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Crystal structure and phase transitions of Sr2Ni1–yMg y MoO6 solid solutions

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Abstract

Sr2Ni1–yMg y MoO6 mixed oxides with a double perovskite structure have been synthesized via the pyrolysis of glycerol–salt mixtures. The phase composition and structure of the samples have been determined using X-ray diffraction and Raman spectroscopy. The temperatures of phase transitions in Sr2Ni1–yMg y MoO6 with y = 0.25, 0.5, and 0.75 have been determined by high-temperature X-ray diffraction and dilatometry.

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Correspondence to L. S. Skutina.

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Original Russian Text © L.S. Skutina, A.I. Vylkov, K.V. Grzhegorzhevskii, A.Yu. Chuikin, A.A. Ostroushko, E.A. Filonova, 2017, published in Neorganicheskie Materialy, 2017, Vol. 53, No. 12, pp. 1325–1330.

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Skutina, L.S., Vylkov, A.I., Grzhegorzhevskii, K.V. et al. Crystal structure and phase transitions of Sr2Ni1–yMg y MoO6 solid solutions. Inorg Mater 53, 1293–1299 (2017). https://doi.org/10.1134/S0020168517120147

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  • DOI: https://doi.org/10.1134/S0020168517120147

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