Abstract
We have studied phase transformations of a 20-μm-thick rolled foil of the Pd–57 at % Cu solid solution in a heating–cooling cycle. The as-prepared foil was two-phase, with a nanocrystalline structure. The mutual orientation of the α- and β-phases corresponded to the Nishiyama–Wassermann orientation relationship. Using X-ray diffraction and resistivity measurements, the β ⇆ α phase transformations were shown to be reversible. The effect of the severely deformed initial structure shows up as a shift in the onset temperature and end point of the α → β phase transformation.
Similar content being viewed by others
References
McKinly, D.L., US Patent 3 350 845, 1967.
Roa, F., Way, J.D., McCormick, R.L., and Paglieri, S.N., Preparation and characterization of Pd–Cu composite membranes for hydrogen separation, Chem. Eng. J., 2003, vol. 93, no. 1, pp. 11–22.
Hoang, H.T., Tong, D., Gielens, F.C., Jansena, H.V., and Elwenspoek, M.C., Fabrication and characterization of dual sputtered Pd–Cu alloy films for hydrogen separation membranes, Mater. Lett., 2004, vol. 58, pp. 525–528.
Subramanian, P.R. and Laughlin, D.E., Cu–Pd (copper–palladium), J. Phase Equilib., 1991, vol. 12, no. 2, pp. 231–243.
Burkhanov, G.S., Gorina, N.B., Kol’chugina, N.B., and Roshan, N.R., Palladium alloys for hydrogen energy generation, Ross. Khim. Zh., 2006, vol. 50, pp. 36–40.
Hydrogen in Metals, Alefeld, G. and Volkl, J., Eds., Heidelberg: Springer, 1978, vol. 1.
Ievlev, V.M., Solntsev, K.A., Dontsov, A.I., Maksimenko, A.A., and Kannykin, S.V., Hydrogen permeability of thin condensed Pd–Cu foil: dependence on temperature and phase composition, Tech. Phys., 2016, vol. 61, no. 3, pp. 467–469.
Ievlev, V.M., Solntsev, K.A., Maksimenko, A.A., Kannykin, S.V., Belonogov, E.K., Dontsov, A.I., and Roshan, N.R., Formation of thin foil of the ordered Pd–Cu solid solution with a CsCl-type lattice during magnetron sputtering, Dokl. Phys. Chem., 2014, vol. 457, no. 2, pp. 127–130.
Volkov, A.Yu. and Kruglikov, N.A., Effect of plastic deformation on the kinetics of phase transformations in the Cu–47Pd alloy, Phys Met. Metallogr., 2008, vol. 105, no. 2, pp. 202–211.
Volkov, A.Yu., Novikova, O.S., and Antonov, B.D., Formation of an ordered structure in the Cu–49 at % Pd alloy, Inorg. Mater., 2013, vol. 49, no. 1, pp. 43–48.
RF Patent 2 579 413.
Ievlev, V.M., Dontsov, A.I., Maksimenko, A.A., and Roshan, N.R., Reversibility of the β ⇆ α phase transformations in a Pd–Cu solid solution, Inorg. Mater., 2017, vol. 53, no. 5, pp. 484–488.
Phase Stability in Metals and Alloys, Rudman, P.S. et al., Eds., New York: McGraw-Hill, 1967.
Basile, A., Gallucci, F., and Tosti, S., Synthesis, characterization, and applications of palladium membranes, Membrane Sci. Technol., 2008, vol. 13, pp. 255–323.
Mishchenko, A.P. and Gryaznov, V.M., Chromatographic assessment of hydrogen permeability of membranes, Zh. Fiz. Khim., 1971, vol. 45, no. 4, pp. 953–955.
Ievlev, V.M., Belonogov, E.K., and Maksimenko, A.A., Oriented crystallization of thin Pd–Cu films, Phys. Met. Metallogr., 2008, vol. 105, no. 6, pp. 574–579.
Nishiyama, Z., X-ray investigation of the mechanism of the transformation from face-centered cubic lattice to body-centered cubic, Sci. Rep. Tohoku Imp. Univ., 1934, vol. 23, pp. 637–664.
Wassermann, G., Influence of the α–γ transformation of an irreversible Ni steel onto crystal orientation and tensile strength, Arch. Eisenhuttenwes., 1933, vol. 16, pp. 647–649.
Van Der Merwe, J.H., Analytical selection of ideal epitaxial configurations and some speculations on the occurrence of epitaxy, Phil. Mag. A, 1982, vol. 45, pp. 145–170.
Van Der Merwe, J.H., Misfit accommodation in epitaxial monolayers on (111) F.C.C. and (110) B.C.C. substrates: I. Analytical approach, Thin Solid Films, 1980, vol. 74, pp. 129–151.
Ievlev, V.M. and Bugakov, A.V., Orientational relations in film metallic systems (111)FCC–(110)BCC, Phys. Met. Metallogr., 1993, vol. 75, no. 1, pp. 119–122.
Taylor, R., Transformation in the copper–palladium alloys, J. Inst. Met., 1934, vol. 54, no. 1, pp. 255–272.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © V.M. Ievlev, A.I. Dontsov, E.K. Belonogov, S.V. Kannykin, K.A. Solntsev, 2017, published in Neorganicheskie Materialy, 2017, Vol. 53, No. 11, pp. 1181–1188.
Rights and permissions
About this article
Cite this article
Ievlev, V.M., Dontsov, A.I., Belonogov, E.K. et al. α ⇆ β phase transformations in rolled foil of the Pd–57 at % Cu solid solution. Inorg Mater 53, 1163–1169 (2017). https://doi.org/10.1134/S0020168517110048
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0020168517110048