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Reactions of manganese oxides with sulfuric acid solutions studied by kinetic and electrochemical methods

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Abstract

Reactions of manganese oxides of various compositions with sulfuric acid solutions have been studied by kinetic and electrochemical methods. The surface composition of the manganese oxides has been shown to vary during the dissolution process. We present mathematical dependences of the dissolution rate on kinetic parameters of the electrolyte solution for the oxides of various compositions and interpret the behavior of the manganese oxide with various compositions during dissolution in sulfuric acid solutions of various concentrations.

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References

  1. Izotov, A.D., Gorichev, I.G., and Pankratov, D.V., Probabilistic and fractal approaches to deriving rate equations for heterogeneous oxide dissolution processes, Inorg. Mater., 2010, vol. 46, no. 6, pp. 660–667.

    Article  CAS  Google Scholar 

  2. Sobolev, A.E., Lutsik, V.I., and Potashnikov, Yu.M., The kinetics of hydrochemical oxidation of iron(II) persulfide (pyrite) by nitric acid, Russ. J. Phys. Chem. A, 2001, vol. 75, no. 5, pp. 757–759.

    Google Scholar 

  3. Gorichev, I.G., Kutepov, A.M., Gorichev, A.I., Izotov, A.D., and Zaitsev, B.E., Kinetika i mekhanizm rastvoreniya oksidov i gidroksidov zheleza v kislykh sredakh (Kinetics and Mechanisms of the Dissolution of Iron Oxides and Hydroxides in Acid Media), Moscow: Ross. Univ. Druzhby Narodov, 1999.

    Google Scholar 

  4. Medvedev, A.S., Vyshchelachivanie i sposoby ego intensifikatsii (Leaching and Ways of Activating It), Moscow: Mosk. Inst. Stali i Splavov, 2005.

    Google Scholar 

  5. Yaroslavtsev, A.B., Kulova, T.L., and Skundin, A.M., Electrode nanomaterials for lithium-ion batteries, Russ. Chem. Rev., 2015, vol. 84, no. 8, pp. 826–852.

    Article  CAS  Google Scholar 

  6. Rode, E.Ya., Kislorodnye soedineniya margantsa (Manganese Oxide Compounds), Moscow: Akad. Nauk SSSR, 1952.

    Google Scholar 

  7. Vetter, K.J., Elektrochemische Kinetik, Berlin: Springer, 1961.

    Book  Google Scholar 

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    E. B. Godunov & A. D. Izotov

  2. Moscow Polytechnic University, Bol’shaya Semenovskaya ul. 38, Moscow, 107023, Russia

    E. B. Godunov & I. G. Gorichev

Authors
  1. E. B. Godunov
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  2. A. D. Izotov
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  3. I. G. Gorichev
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Correspondence to E. B. Godunov.

Additional information

Original Russian Text © E.B. Godunov, A.D. Izotov, I.G. Gorichev, 2017, published in Neorganicheskie Materialy, 2017, Vol. 53, No. 8, pp. 845–850.

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Godunov, E.B., Izotov, A.D. & Gorichev, I.G. Reactions of manganese oxides with sulfuric acid solutions studied by kinetic and electrochemical methods. Inorg Mater 53, 831–837 (2017). https://doi.org/10.1134/S0020168517080052

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  • DOI: https://doi.org/10.1134/S0020168517080052

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