Sol–gel synthesis of 2D and 3D nanostructured YSZ:Yb3+ ceramics
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This paper presents results of a detailed study of fundamental aspects of the formation of 2D and 3D nanostructured YSZ:Yb3+ ceramics with a cubic structure through a key synthesis step in aqueous solutions of zirconium-containing hydroxy nanoparticles (1–2 nm) modified by Y3+ and Yb3+ ions, with the use of a sol–gel method and subsequent calcination of the resultant xerogels at temperatures above 350°C. As starting chemicals for the synthesis of ceramic powders, we used zirconyl, yttrium, and ytterbium nitrates and chlorides and aqueous ammonia. Using mixed solutions of these salts and a procedure developed by us, we synthesized sols, gels, and xerogels. To examine the effect of temperature on solid-state transformations, the xerogels were calcined according to a predetermined program in a muffle furnace at temperatures in the range from 350 to 1350°C (rarely, up to 1650°C). We focused primarily on ceramic powders close in composition to 0.86ZrO2 · 0.10Y2O3 · 0.04Yb2O3. The ceramics were characterized by high-resolution transmission electron microscopy, electron microdiffraction, electronic diffuse reflectance spectroscopy, energy dispersive X-ray microanalysis, and X-ray fluorescence analysis.
Keywordsoptically transparent ceramics sol–gel method 2D and 3D nanostructures
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- 7.Lever, A.B.P., Inorganic Electronic Spectroscopy, Amsterdam: Elsevier, 1987, 2nd ed.Google Scholar
- 12.Rydberg, S., Radiation induced losses in ytterbium doped laser materials, PhD Thesis, Sundsvall, 2013.Google Scholar
- 14.Stryganyuk, G., Trots, D., Berezovskaya, I., Shalapska, T., Voloshinovskii, A., Dotsenko, V., and Zimmerer, G., Luminescence of YbP3O9 upon excitation in the UV–VUV range, J. Phys.: Condens. Matter, 2007, vol. 19, paper 6236–6246.Google Scholar