Abstract
We have examined the effect of metal compounds on α-Si3N4 formation as a result of silicon combustion in nitrogen in the presence of organic compounds. The results demonstrate that the iron and copper chlorides FeCl3 · 6Н2О and CuCl2 · 2Н2О have the strongest effect on α-Si3N4 formation. The contributions of the metal chlorides and organic compounds to α-Si3N4 formation have been shown to be nonadditive.
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Original Russian Text © T.V. Barinova, I.P. Borovinskaya, 2017, published in Neorganicheskie Materialy, 2017, Vol. 53, No. 4, pp. 375–379.
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Barinova, T.V., Borovinskaya, I.P. Effect of metal compounds on α-Si3N4 formation during silicon combustion in nitrogen in the presence of organic additives. Inorg Mater 53, 381–385 (2017). https://doi.org/10.1134/S0020168517040021
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DOI: https://doi.org/10.1134/S0020168517040021