Abstract
Dense SiC-based ceramic materials containing yttrium aluminum garnet (YAG) as an oxide sintering aid have been prepared by hot pressing in the temperature range 1750–1850°C. As a result of melting, the oxides fill spaces between the SiC particles, contributing to the densification of the material and mass transport during the hot pressing process. The present results demonstrate that relatively small amounts of the oxides (≤5 wt %) are needed to ensure a high degree of densification of the SiC–YAG materials. The best physicomechanical properties are offered by the SiC + 3 wt % YAG material sintered at a temperature of 1850°C: ρ = 3.24 ± 0.01 g/cm3, П = 1.1 ± 0.1%, σb = 640 ± 10 MPa; KIc = 6.4 ± 0.2 MPa m1/2, Еel = 410 ± 20 GPa, and HV = 26.0 ± 0.2 GPa. This material experiences predominantly intercrystalline fracture.
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References
Garshin, A.P., Gropyanov, V.M., Zaitsev, G.P., et al., Keramika dlya mashinostroeniya (Engineering Ceramics), Moscow: Nauchtekhlitizdat, 2003.
Gnesin, G.G., Karbidokremnievye materialy (Silicon Carbide Materials), Moscow: Metallurgiya, 1977.
Lenk, R., Kriwoschepov, A.F., and Grosse, K., Heissgiessen von drucklos gesintertem Siliziumcarbid: Herstellung der heissgiess Schlicker. Hot-casting of pressureless-sintered silicon carbide: preparation of the casting slip, Sprechsaal: Ceram. Mater., 1995, vol. 128, no. 1, pp. 17–20.
Chou, Y.S. and Green, D.J., Silicon carbide platelet/ alumina composites (I): effect of forming technique on platelet orientation, J. Am. Ceram. Soc., 1992, vol. 75, no. 12, pp. 3346–3352.
Chou, Y.S. and Green, D.J., Silicon carbide platelet/ alumina composites (II): mechanical properties, J. Am. Ceram. Soc., 1993, vol. 76, no. 6, pp. 1452–1458.
Chou, Y.S. and Green, D.J., Silicon carbide platelet/ alumina composites (III): toughening mechanisms, J. Am. Ceram. Soc., 1993, vol. 76, no. 8, pp. 1985–1992.
Kim, Y.-W. and Lee, J.-G., Pressureless sintering of Al2O3–SiC whisker composites, J. Mater. Sci., 1991, vol. 26, pp. 1316–1320.
Ko, Y.-M., Kwon, W.T., and Kim, Y.-W., Cutting performance of Al2O3–SiC nanocomposite tools, J. Mater. Sci., 2005, vol. 40, pp. 785–787.
Kim, Y.-W., Mitomo, M., and Zhan, G.-D., Microstructure control of liquid-phase sintered β-SiC by seeding, J. Mater. Sci. Lett., 2001, vol. 20, pp. 2217–2220.
Kim, Sh.-H., Kim, Y.-W., and Mitomo, M., Microstructure and fracture toughness of liquid-phase-sintered β-SiC containing β-SiC whiskers as seeds, J. Mater. Sci., 2003, vol. 38, pp. 1117–1121.
Perevislov, S.N., Chupov, V.D., and Tomkovich, M.V., Influence of yttrium aluminum garnet and magnesium spinel additions on the compactibility and mechanical properties of SiC ceramics, Vopr. Materialoved., 2011, no. 1, pp. 123–129.
Jin, Y.-J., Kim, Y.-W., and Mitomo, M., Effect of large seeds addition on microstructural development of SiC sintered with oxynitride glass, J. Mater. Sci. Lett., 2002, vol. 21, pp. 1015–1017.
Cho, D.-H., Kim, Y.-W., and Kim, W., Strength and fracture toughness of in situ-toughened silicon carbide, J. Mater. Sci., 1997, vol. 32, pp. 4777–4782.
Ko, S.-I., Lee, S.-J., Roh, M.-H., et al., Effect of annealing on mechanical properties of silicon carbide sintered with aluminum nitride and scandium oxide, Met. Mater. Int., 2009, vol. 15, no. 1, pp. 149–153.
Manoj Kumar, B.V., Roh, M.-H., Kim, Y.-W., et al., Mechanical properties of SiC ceramics sintered with Re2O3 (Re: Sc, Lu, Y) and AlN additives, Met. Mater. Int., 2010, vol. 16, no. 2, pp. 229–233.
Roh, M.-H., Kim, W., Kim, Y.-W., et al., Effect of hotforging on mechanical properties of silicon carbide sintered with Al2O3–Y2O3–MgO, Met. Mater. Int., 2010, vol. 16, no. 6, pp. 891–894.
Perevislov, S.N., Nesmelov, D.D., and Tomkovich, M.V., Preparation of SiC- and Si3N4-based materials by spark plasma sintering, Vestn. NNGU im. N. I. Lobachevskogo, 2013, no. 2-2, pp. 107–114.
Pujari, V.K., Collins, W.T., and Scalabrino, M., US Patent 6 762 140, 2001.
Sciti, D. and Bellosy, A., Effects of additives on densification, microstructure and properties of liquid-phase sintered silicon carbide, J. Mater. Sci., 2000, vol. 35, pp. 3849–3855.
Kim, J.-Y., An, H.-G., Kim, Y.-W. et al., R-curve behaviour and microstructure of liquid-phase sintered α-SiC, J. Mater. Sci., 2000, vol. 35, pp. 3693–3697.
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Original Russian Text © S.N. Perevislov, A.S. Lysenkov, D.D. Titov, M.V. Tomkovich, 2017, published in Neorganicheskie Materialy, 2017, Vol. 53, No. 2, pp. 206–211.
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Perevislov, S.N., Lysenkov, A.S., Titov, D.D. et al. Hot-pressed ceramic SiC–YAG materials. Inorg Mater 53, 220–225 (2017). https://doi.org/10.1134/S0020168517020091
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DOI: https://doi.org/10.1134/S0020168517020091