Skip to main content
Log in

Methods for studying anthropogenic environmental pollution with platinum group metals (Review)

  • Analysis of Substances
  • Published:
Inorganic Materials Aims and scope

Abstract

A review of the published works on the use of different methods of analysis for studying anthropogenic pollution of environmental objects with platinum group metals (PGMs) for 2011–2013 is presented. The results of the recent studies on the content of PGMs in environmental objects of big cities are provided.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Prichard, H.M. and Fisher, P.C., Identification of platinum and palladium particles emitted from vehicles and dispersed into the surface environment, Environ. Sci. Technol., 2012, vol. 46, no. 6, pp. 3149–3154.

    Article  CAS  Google Scholar 

  2. Sen, I.S., Peucker-Ehrenbrink, B., and Geboy, N., Complex anthropogenic sources of platinum group elements in aerosols on Cape Cod, USA, Environ. Sci. Technol., 2013, vol. 47, no. 18, pp. 10188–10196.

    CAS  Google Scholar 

  3. Urban Airborne Particulate Matter. Origin, Chemistry, Fate, and Health Impacts, Zereini, F. and Wiseman, C.L.S., Eds., Berlin: Springer Verlag, 2010.

  4. Mapping Chemical Environment of Urban Areas, Johnson, C.C., Demetriades, A., Locutura, J., and Ottesen, R.T., Eds., New York: Wiley, 2011.

  5. Bencs, L., Ravindra, K., and van Grieken, R., Platinum: Environmental Pollution and Health Effects, in Encyclopedia of Environmental Health, Nriagu, J., Ed., Amsterdam: Elsevier, 2011, pp. 580–595.

    Chapter  Google Scholar 

  6. Iavicoli, I., Fontana, L., and Bergamaschi, A., Palladium: Exposure, Uses, and Human Health Effects, in Encyclopedia of Environmental Health, Nriagu, J., Ed., Amsterdam: Elsevier, 2011, pp. 307–314.

    Chapter  Google Scholar 

  7. Puls, C., Limbeck, A., and Hann, S., Bioaccessibility of palladium and platinum in urban aerosol particulates, Atmos. Environ, 2012, vol. 55, pp. 213–219.

    Article  CAS  Google Scholar 

  8. Asharani, P.V., Lianwu, Y., Gong, Z., and Valiyaveettil, S., Comparison of the toxicity of silver, gold and platinum nanoparticles in developing zebrafish embryos, Nanotoxicology, 2011, vol. 5, no. 1, pp. 43–54.

    Article  CAS  Google Scholar 

  9. Soyol-Erdene, T.-O., Huh, Y., Hong, S., and Do Hur, S., A 50-year record of platinum, iridium, and rhodium in Antarctic snow: volcanic and anthropogenic sources, Environ., Sci. Technol., 2011, vol. 45, no. 14, pp. 5929–5935.

    Article  CAS  Google Scholar 

  10. Zereini, F., Alsenz, H., Wiseman, C.L.S., et al., Platinum group elements (Pt, Pd, Rh) in airborne particulate matter in rural vs. urban areas of Germany: Concentrations and spatial patterns of distribution, Sci. Total Environ., 2012, vol. 416, pp. 261–268.

    Article  CAS  Google Scholar 

  11. Zereini, F., Wiseman, C.L., and Puttmann, W., In vitro investigations of platinum, palladium, and rhodium mobility in urban airborne particulate matter (PM10, PM2.5, and PM1) using simulated lung fluids, Environ. Sci. Technol., 2012, vol. 46, no. 18, pp. 10326–10333.

    CAS  Google Scholar 

  12. Ramavati Mathur V., Balaram, M., Satyanarayanan, S.S., and Sawant S.L. Ramesh, Anthropogenic platinum, palladium and rhodium concentrations in road dusts from Hyderabad city, India, Environ. Earth Sci., 2011, vol. 62, no. 5, pp. 1085–1098.

    Article  Google Scholar 

  13. Lifeng Zhong, Jie Li, Wen Yan, et al. Platinum-group and other traffic-related heavy metal contamination in road sediment, Guangzhou, China, J. Soils Sediments, 2012, vol. 12, no. 6, pp. 942–951.

    Article  CAS  Google Scholar 

  14. Spada, N., Bozlaker, A., and Chellam, S., Multi-elemental characterization of tunnel and road dusts in Houston, Texas using dynamic reaction cell-quadrupole- inductively coupled plasma-mass spectrometry: Evidence for the release of platinum group and anthropogenic metals from motor vehicles, Anal. Chim. Acta, 2012, vol. 735, pp. 1–8.

    Article  CAS  Google Scholar 

  15. Mahmood, Q., Rashid, A., Ahmad, S.S., et al., Current status of toxic metals addition to environment and its consequences, in Environmental Pollution, Vol. 21: Plant Family Brassicaceae, Anjum, N.A., Ahmad, I., Pereira, M.E., Duarte, A.C., Umar, S., and Khan, N.A., Eds., Dordrecht: Springer-Verlag, 2012, pp. 35–69.

    Google Scholar 

  16. Liang, Q., Zhou, M.-F., Zheng, Z., et al., The characteristics of automobile catalyst-derived platinum group elements in road dusts and roadside soils: a case study in the Pearl River Delta Region, South China, Earth Sci., 2011, vol. 64, no. 6, pp. 1683–1692.

    Article  Google Scholar 

  17. Wang, Y. and Li, X., Health risk of platinum group elements from automobile catalyst, Procedia Eng., 2012, vol. 45, pp. 1004–1009.

    Article  CAS  Google Scholar 

  18. Sobrova, P., Zehnalek, J., Adam, V., et al., The effects on soil/water/plant/animal systems by platinum group elements, Central Eur. J. Chem., 2012, vol. 10, no. 5, pp. 1369–1382.

    CAS  Google Scholar 

  19. Petrenko, D.B., Platinum-group elements in the environment and their ecological hazards, Vestn. Mosk. Gos. Obl. Univ., Ser.: Estestv. Nauki, 2011, no. 5, pp. 49–53.

    Google Scholar 

  20. Ribeiro, A.P., Figueiredo, A.M.G., Sarkis, J.E.S., et al., First study on anthropogenic Pt, Pd, and Rh levels in soils from major avenues of Sao Paulo City, Brazil, Environ. Monit. Assess., 2012, vol. 184, no. 12, pp. 7373–7382.

    Article  CAS  Google Scholar 

  21. Gao, B., Yu, Y., Zhou, H., and Lu, J., Accumulation and distribution characteristics of platinum group elements in roadside dusts in Beijing, Environ. Toxicol. Chem., 2012, vol. 31, no. 6, pp. 1231–1238.

    Article  CAS  Google Scholar 

  22. Lee, H.-Y., Chon, H.-T., Sager, M., and Marton, L., Platinum pollution in road dusts, roadside soils, and tree barks in Seoul, Korea, Environ. Geochem. Health, 2012, vol. 34, no. 1, suppl., pp. 5–12.

    Article  CAS  Google Scholar 

  23. Sikorová, L., Ličbinský, R., and Adamec, V., Platinové kovy z automobilovych katalyzáor v životnim prostředí, Chem. Listy, 2011, vol. 105, no. 5, pp. 361–366.

    Google Scholar 

  24. Dean, J.R., Environmental Trace Analysis: Techniques and Applications, New York: Wiley, 2013.

    Book  Google Scholar 

  25. Balcerzak, M., Methods for the determination of platinum group elements in environmental and biological materials: a review, Crit. Rev. Anal. Chem., 2011, vol. 41, no. 3, pp. 214–235.

    Article  CAS  Google Scholar 

  26. Kubrakova, I.V., Nikulin, A.V., Koshcheeva, I.Ya., and Tyutyunnik, O.A., Platinum metals in the environment: content, determination, behavior in natural systems, Khim. Interesakh Ustoich. Razvit., 2012, vol. 20, no. 6, pp. 645–656.

    CAS  Google Scholar 

  27. Butler, O.T., Cairns, W.R.L., Cook, J.M., and Davidson, C.M., Atomic spectrometry update. Environmental analysis, J. Anal. At. Spectrom., 2010, vol. 25, no. 2, pp. 103–141.

    Article  CAS  Google Scholar 

  28. Butler, O.T., Cairns, W.R.L., Cook, J.M., and Davidson, C.M., Atomic spectrometry update. Environmental analysis, J. Anal. Atom. Spectrom., 2012, vol. 27, no. 2, pp. 187–221.

    Article  CAS  Google Scholar 

  29. Puls, C., Limbeck, A., and Hann, S., Ultra-trace analysis of palladium: state-of-the-art and future challenges, in Urban Airborne Particulate Matter, Zereini, F. and Wiseman, C., Eds., Berlin: Springer-Verlag, 2010.

    Google Scholar 

  30. Fumagalli, A., Faggion, B., Ronchini, M., Terzaghi, G., et al., Platinum, palladium, and rhodium deposition to the Prunus laurus cerasus leaf surface as an indicator of the vehicular traffic pollution in the city of Varese area: an easy and reliable method to detect PGEs released from automobile catalytic converters, Environ. Sci. Pollut. Res. Int., 2010, vol. 17, no. 3, pp. 665–673.

    Article  CAS  Google Scholar 

  31. Paraskevas, M.S., Papoutsi, K., and Ochsenkuhn-Petropoulou, M., A novel way of sampling particles containing platinum group elements from automobile catalyst, Anal. Lett., 2012, vol. 45, nos 5–6, pp. 539–550.

    Article  CAS  Google Scholar 

  32. Qi, L., Gao, J., Huang, X., et al., An improved digestion technique for determination of platinum group elements in geological samples, J. Anal. At. Spectrom., 2011, vol. 26, no. 9, pp. 1900–1904.

    Article  CAS  Google Scholar 

  33. Li, D., Chang, X., Hu, Z., et al., Selective solid-phase extraction of trace Au (III), Pd (II) and Pt (IV) using activated carbon modified with 2,6-diaminopyridine, Microchim. Acta, 2011, vol. 174, nos. 1–2, pp. 131–136.

    Article  CAS  Google Scholar 

  34. Bujdos, M., Hagarova, I., Matus, P., et al., Optimisation of determination of platinum group elements in airborne particulate matter by inductively coupled plasma mass spectrometry, Acta Chim. Slov., 2012, vol. 59, no. 1, pp. 124–128.

    CAS  Google Scholar 

  35. Cairns, A., Warrwn, R.L., De Boni, A., et al., The use of cation exchange matrix separation coupled with ICP-MS to directly determine platinum group element (PGE) and other trace element emissions from passenger cars equipped with diesel particulate filters (DPF), Anal. Bioanal. Chem., 2011, vol. 399, no. 8, pp. 2731–2740.

    Article  CAS  Google Scholar 

  36. Alsenz, H., Zereini, F., Wiseman, C.L.S., and Puttmann, W., Analysis of palladium concentrations in airborne particulate matter with reductive co-precipitation, He collision gas and ID-ICPQ-MS, in Urban Airborne Particulate Matter, Zereini, F. and Wiseman, C., Eds., Berlin: Springer-Verlag, 2010.

    Google Scholar 

  37. Goulle, J.-P., Lacroix, C., Saussereau, E., et al., Interet du dosage de quatre elements mineraux dans les eaux usees pour le suivi des activites medicales, Ann. Toxicol. Anal., 2011, vol. 23, no. 2, pp. 53–59.

    Article  CAS  Google Scholar 

  38. Goulle, J.-P., Saussereau, E., Mahieu, L., et al., Importance of anthropogenic metals in hospital and urban wastewater: its significance for the environment, Bull. Environ. Contam. Toxicol., 2012, vol. 89, no. 6, pp. 1220–1224.

    Article  CAS  Google Scholar 

  39. Krejcova, A., Cernohorsky, T., and Pouzar, M., O-TOFICP- MS analysis of rare earth elements, noble elements, uranium and thorium in river-relating species, Int. J. Environ. Anal. Chem., 2012, vol. 92, no. 5, pp. 620–635.

    Article  CAS  Google Scholar 

  40. Zhong Li-Feng, Yan Wen, Li Jie, et al. Pt and Pd in sediments from the Pearl River estuary, South China: background levels, distribution, and source, Environ. Sci. Pollut. Res., 2012, vol. 19, no 4, pp. 1305–1314.

    Article  CAS  Google Scholar 

  41. Puls, C., Limbeck, A., and Hann, S., Bioaccessibility of palladium and platinum in urban aerosol particulates, Atmos. Environ., 2012, vol. 55, pp. 213–219.

    Article  CAS  Google Scholar 

  42. Castillo, M.L., Garcia de Torres A., Vereda Alonso E., et al. Multi-element determination of Pt, Pd and Ir traces in environmental samples by ICP-MS after preconcentration, Talanta, 2012, vol. 99, pp. 853–858.

    Article  Google Scholar 

  43. Akrivi, A.A., Tsogas, G.Z., Giokas, D.L., and Vlessidis, A.G., Analytical determination and bio-monitoring of platinum group elements in roadside grass using microwave assisted digestion and electrothermal atomic absorption spectrometry, Anal. Lett., 2012, vol. 45, nos. 5–6, pp. 526–538.

    Article  CAS  Google Scholar 

  44. Woinska, S. and Godlewska-Zylkiewicz, B., Determination of platinum and palladium in road dust after their separation on immobilized fungus by electrothermal atomic absorption spectrometry, Spectrochim. Acta, 2011, vol. 66, no. 7, pp. 522–528.

    Article  CAS  Google Scholar 

  45. Yuanpei Lian, Wei Zhen, Zhigang Tai, et al. Cloud point extraction and flame atomic absorption spectrometry analysis of palladium, platinum, and gold ions from industrial polluted soil, Rare Met., 2012, vol. 31, no. 5, pp. 512–516.

    Article  CAS  Google Scholar 

  46. Mladenova, E., Dakova, I., Karadjova, I., and Karadjov, M., Column solid phase extraction and determination of ultra-trace Au, Pd and Pt in environmental and geological samples, Microchem. J, 2012, vol. 101, pp. 59–64.

    Article  CAS  Google Scholar 

  47. Sid, KalalH., Hoveidi, H., Thagiof, M., et al., Preconcentration and determination of platinum (IV) in water samples using chelating resin by inductively coupled plasma atomic emission spectroscopy (ICP-AES), Int. J. Environ. Res, 2012, vol. 6, no. 3, pp. 739–750.

    Google Scholar 

  48. Mokhodoeva, O.B., Nikulin, A.V., Myasoedova, G.V., and Kubrakova, I.V., A new combined ETAAS method for the determination of platinum, palladium, and gold traces in natural samples, J. Anal. Chem., 2012, vol. 67, no. 6, pp. 531–536.

    Article  CAS  Google Scholar 

  49. Herincs, E., Puschenreiter, M., Wencel, W., and Limbeck, A., A novel flow-injection method for simultaneous measurement of platinum (Pt), palladium (Pd) and rhodium (Rh) in aqueous soil extracts of contaminated soil by ICP-OES, J. Anal. Atom. Spectrom., 2013, vol. 28, no. 3, pp. 354–363.

    Article  CAS  Google Scholar 

  50. van der Horst, C., Silwana, B., Iwuoha, E., and Somerset, V., Stripping voltammetric determination of palladium, platinum and rhodium in freshwater and sediment samples from South African water resources, J. Environ. Sci. Health, 2012, vol. 47, no. 13, pp. 2084–2093.

    Article  Google Scholar 

  51. Locatelli, C., Sequential voltammetric determination of ultratrace osmium, ruthenium and iridium. application to superficial water, Electroanalysis, 2011, vol. 26, no. 6, pp. 1329–1336.

    Article  Google Scholar 

  52. Locatelli, C., Catalytic-adsorptive stripping voltammetric determination of ultra-trace iridium (III). Application to fresh- and sea-water, Talanta, 2011, vol. 85, no. 1, pp. 546–550.

    Article  CAS  Google Scholar 

  53. Locatelli, C., Ultratrace osmium, ruthenium and lead in airborne particulate matter: peak area as instrumental datum to improve their simultaneous voltammetric determination, Electroanalysis, 2012, vol. 24, no. 12, pp. 2273–2282.

    Article  CAS  Google Scholar 

  54. Kawamura, K., Ikoma, K., Igarashi, S., et al., Flow injection analysis combined with a hydrothermal flow reactor: application to kinetic determination of trace amounts of iridium using a water-soluble porphyrin, Talanta, 2011, vol. 84, no. 5, pp. 1318–1322.

    Article  CAS  Google Scholar 

  55. Khomutova, E.G., Ostanina, O.I., Zagorodnikova, V.A., and Zagorodnikova, S.A., Determination of rhodium microconcentrations by the catalytic method in the flow-injection system, Izv. Vyssh. Uchebn. Zaved., Chern. Metall., 2011, vol. 54, no. 11, pp. 50–53.

    CAS  Google Scholar 

  56. Malejko, J., Szygalowicz, M., Godlewska-Zylkiewicz, B., and Kojlo, A., Sorption of platinum on immobilized microorganisms for its on-line preconcentration and chemiluminescent determination in water samples, Microchim. Acta, 2012, vol. 176, nos 3–4, pp. 429–435.

    Article  CAS  Google Scholar 

  57. Pushpa, Ratre and Devendra, Kumar, Spectrophotometric determination of Pt (II) and Pd (II) in environmental samples collected from highly polluted areas of Delhi region of India, Int. J. Emerging Comput. Technol. Appl. Sci., 2013, vol. 5, no. 4, pp. 421–429.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to L. P. Zhitenko.

Additional information

Original Russian Text © L.P. Zhitenko, I.N. Kiseleva, E.G. Khomutova, 2015, published in Zavodskaya Laboratoriya, Diagnostika Materialov, 2015, Vol. 81, No. 3, pp. 5–11.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zhitenko, L.P., Kiseleva, I.N. & Khomutova, E.G. Methods for studying anthropogenic environmental pollution with platinum group metals (Review). Inorg Mater 52, 1370–1376 (2016). https://doi.org/10.1134/S0020168516140156

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0020168516140156

Keywords

Navigation