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Adhesion mechanism of destruction of silica-glass surface during the preparation and treatment of optical glassy arsenic Chalcogenides

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Abstract

Adhesion of As–S and As–Se glasses to silica glass is studied by means of the steady detachment method. The results demonstrate that the adhesion strength of the boundary of solid phases increases with the content of chalcogens in the composition of glass. It is found that adhesion of arsenic sulfide glasses with sulfur content over 65% to silica glass exceeds the tensile strength of the silica glass during the process of solidification and annealing of chalcogenide preforms. The adhesion of arsenic chalcogenides to silica glass is determined to be the reason of chalcogenide glass contamination by heterophase inclusions.

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References

  1. Standler, R.R. and Henderson, R.E., Infrared fiber optics technique, Infrared Phys., 1963, vol. 3, pp. 223–227.

    Article  Google Scholar 

  2. Kapany, N.S. and Simms, R.S., Recent developments in infrared fiber optics, Infrared Phys., 1965, vol. 5, pp. 69–80.

    Article  CAS  Google Scholar 

  3. Snopatin, G.E., Shiryaev, V.S., Plotnichenko, V.G., Dianov, E.M., and Churbanov, M.F., High-purity chalcogenide glasses for fiber optics, Inorg. Mater., 2009, vol. 45, no. 13, pp. 1439–1460.

    Article  CAS  Google Scholar 

  4. Aio, L.G., Efimov, A.M., and Kokorina, V.F., Refractive index of chalcogenide glasses over a wide range of compositions, J. Non-Cryst. Solids, 1978, vol. 27, pp. 299–307.

    Article  CAS  Google Scholar 

  5. Tsuchihashi Shoji and Kawamoto Yoji, Properties and structure of glasses in the system As–S, J. Non-Cryst. Solids, 1971, vol. 5, pp. 286–305.

    Article  Google Scholar 

  6. Borisova, Z.U., Khal’kogenidnye poluprovodnikovye stekla (Semiconducting Chalcogenide Glasses), Leningrad: Leninigradsk. Univ., 1983.

    Google Scholar 

  7. Mel’nichenko, T.D., Fedelesh, V.I., Mel’nichenko, T.N., Sanditov, D.S., Badmaev, S.S., and Damdinov, D.G., On the approximate estimation of the surface tension of chalcogenide glass melts, Glass Phys. Chem., 2009, vol. 35, no. 1, pp. 40–54.

    Google Scholar 

  8. Shiryaev, V.S., Kosolapov, A.F., Pryamikov, A.D., Snopatin, G.E., Churbanov, M.F., Biriukov, A.S., Kotereva, T.V., Mishinov, S.V., Alagashev, G.K., and Kolyadin, A.N., Development of technique for preparation of As2S3 glass preforms for hollow core microstructured optical fibers, J. Optoelectron. Adv. Mater., 2014, vol. 16, nos. 9–10, pp. 1020–1025.

    CAS  Google Scholar 

  9. Churbanov, M.F., Snopatin, G.E., Shiryaev, V.S., Plotnichenko, V.G., and Dianov, E.M., Recent advances in preparation of high-purity glasses based on arsenic chalcogenides for fiber optics, J. Non-Cryst. Solids, 2011, vol. 357, pp. 2352–2357.

    Article  CAS  Google Scholar 

  10. Mittal, K.L., Adhesion measurement of thin films, Electrocompon. Sci. Technol., 1976, vol. 3, pp. 21–42.

    Article  CAS  Google Scholar 

  11. Shiryaev, V.S., Mishinov, S.V., and Churbanov, M.F., Investigation of adhesion of chalcogenide glasses to silica glass, J. Non-Cryst. Solids, 2015, vol. 408, pp. 71–75.

    Article  CAS  Google Scholar 

  12. Nemilov, S.V., Viscosity, elastic properties, and valence structure of melts and glasses in the As–S system, Fiz. Khim. Stekla, 1979, vol. 5, no. 4, pp. 398–409.

    CAS  Google Scholar 

  13. Bureau, B., Troles, J., le Floch, M., Smektala, F., Silly, G., and Lucas, J., Solid state 77Se NMR investigations on arsenic–selenium glasses and crystals, Solid State Sci., 2003, vol. 5, pp. 219–224.

    Article  CAS  Google Scholar 

  14. Silin’, A.R. and Trukhin, A.N., Tochechnye defekty i elementarnye vozbuzhdeniya v kristallicheskom i stekloobraznom SiO 2 (Point Defects and Elementary Excitations in Crystalline and Glassy SiO2), Riga: Zinatne, 1985, p. 244.

    Google Scholar 

  15. Lunin, B.S. and Torbin, S.N., Heat treatment induced defect formation on the surface of quartz glass, Vestn. Mosk. Univ., Ser. 2: Khim., 2005, vol. 46, no. 6, pp. 378–381.

    CAS  Google Scholar 

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Authors and Affiliations

  1. Devyatykh Institute of Chemistry of High-Purity Substances of the Russian Academy of Sciences, 49 Tropinin str., 603950, Nizhny Novgorod, Russia

    S. V. Mishinov, M. F. Churbanov, V. S. Shiryaev, A. I. Suchkov & G. E. Snopatin

  2. Lobachevski Nizhny Novgorod State University, 23 Gagarin av., Nizhny Novgorod, 603950, Russia

    M. F. Churbanov, A. N. Gorokhov, D. A. Kazakov, V. S. Shiryaev & L. A. Igumnov

Authors
  1. S. V. Mishinov
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  2. M. F. Churbanov
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  3. A. N. Gorokhov
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  4. D. A. Kazakov
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  5. V. S. Shiryaev
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  6. A. I. Suchkov
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  7. L. A. Igumnov
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  8. G. E. Snopatin
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Correspondence to S. V. Mishinov.

Additional information

Original Russian Text © S.V. Mishinov, M.F. Churbanov, A.N. Gorokhov, D.A. Kazakov, V.S. Shiryaev, A.I. Suchkov, L.A. Igumnov, G.E. Snopatin, 2016, published in Neorganicheskie Materialy, 2016, Vol. 52, No. 7, pp. 773–777.

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Mishinov, S.V., Churbanov, M.F., Gorokhov, A.N. et al. Adhesion mechanism of destruction of silica-glass surface during the preparation and treatment of optical glassy arsenic Chalcogenides. Inorg Mater 52, 716–720 (2016). https://doi.org/10.1134/S0020168516070104

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  • DOI: https://doi.org/10.1134/S0020168516070104

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