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Local crystal structure of multiferroic BiMnO3 studied by 57Fe probe Mössbauer spectroscopy

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Abstract

This paper presents a 57Fe probe Mössbauer spectroscopy study of a BiMn0.96 57Fe0.04O3 manganite synthesized at high pressure (6 GPa). The BiMnO3 manganite possesses multiferroic properties and exhibits cooperative orbital ordering due to Jahn–Teller active Mn3+ ions. 57Fe Mössbauer spectra have been measured and analyzed in a wide temperature range, which includes the orbital ordering temperature of BiMnO3.

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Moscow, 119899, Russia

    Ya. S. Glazkova, A. V. Sobolev & I. A. Presniakov

  2. National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki, 305-0047, Japan

    A. A. Belik

Authors
  1. Ya. S. Glazkova
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  2. A. A. Belik
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  3. A. V. Sobolev
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  4. I. A. Presniakov
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Correspondence to Ya. S. Glazkova.

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Original Russian Text © Ya.S. Glazkova, A.A. Belik, A.V. Sobolev, I.A. Presniakov, 2016, published in Neorganicheskie Materialy, 2016, Vol. 52, No. 5, pp. 546–550.

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Glazkova, Y.S., Belik, A.A., Sobolev, A.V. et al. Local crystal structure of multiferroic BiMnO3 studied by 57Fe probe Mössbauer spectroscopy. Inorg Mater 52, 499–503 (2016). https://doi.org/10.1134/S0020168516050058

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  • DOI: https://doi.org/10.1134/S0020168516050058

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