Skip to main content
Log in

Effect of titanium on the rheological properties of MoSi2-based materials prepared by SHS

  • Published:
Inorganic Materials Aims and scope

Abstract

We have studied the moldability of molybdenum disilicide-based materials using free self-propagating high-temperature synthesis (SHS) compression, a method that combines combustion and high-temperature deformation processes. As a moldability criterion, we used strain. The strain of the synthesized materials has been determined experimentally as a function of the time delay before high-temperature deformation, compaction pressure, heating temperature, and metallic binder content of the starting mixture. To improve the plasticity of the synthesized material, 1–2 wt % titanium was added to the starting mixture as a metallic binder.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Zaki, Z.I., Mostafa Nasser, Y., and Ahmed, Y.M., Synthesis of dense mullite MoSi2 composite for high temperature applications, Int. J. Refract. Met. Hard Mater., 2014, vol. 45, pp. 23–30.

    Article  CAS  Google Scholar 

  2. Sharif, A.A., Misra, A., and Mitchell, T.E., Strength of MoSi2-based crystals at ultra-high temperature, Scr. Mater., 2005, vol. 52, pp. 399–402.

    Article  CAS  Google Scholar 

  3. Kislyi, P.S., Badyan, A.Kh., Kindysheva, V.S., and Garibyan, F.S., Vysokotemperaturnye nemetallicheskie nagrevateli (High-Temperature Nonmetallic Heaters), Kiev: Naukova Dumka, 1981.

    Google Scholar 

  4. Tkachev, L.G. and Pogrebisskii, M.Ya., Computer simulation of resistance furnace heaters for metallurgical applications, Elektrometallurgiya, 2000, no. 9, pp. 42–46.

    Google Scholar 

  5. Lin, W.Y., Hsu, J.Y., and Speyer, R.F., Stability of molybdenum disilicide in combustion gas environments, J. Am. Ceram. Soc., 1994, vol. 77, no. 5, pp. 1162–1168.

    Article  CAS  Google Scholar 

  6. Vasudeva, A.K. and Petrovic, J.J., A Comparative Overview of Molybdenum Disilicide Composites, 1992.

    Google Scholar 

  7. Yue Chen, Hammerschmidt, T., Pettifor, D.G., JiaXiang Shang, and Yue Zhang, Influence of vibrational entropy on structural stability of Nb–Si and Mo–Si systems at elevated temperatures, Acta Mater., 2009, vol. 57, pp. 2657–2664.

    Article  Google Scholar 

  8. Rioult, F.A., Imhoff, S.D., Sakidja, R., and Perepezko, J.H., Transient oxidation of Mo–Si–B alloys: effect of the microstructure size scale, Acta Mater., 2009, vol. 57, pp. 4600–4613.

    Article  CAS  Google Scholar 

  9. Mileiko, S.T., High-temperature metal matrix composites, J. Appl. Mech. Tech. Phys., 2014, vol. 55, no. 1, pp. 136–146.

    Article  CAS  Google Scholar 

  10. Grammenos, I. and Tsakiropoulos, P., Study of the role of Hf, Mo and W additions in the microstructure of Nb–20Si silicide based alloys, Intermetallics, 2011, vol. 19, pp. 1612–1621.

    Article  CAS  Google Scholar 

  11. Stolin, A.M. and Bazhin, P.M., Manufacture of multipurpose composite and ceramic materials in the combustion regime and high-temperature deformation (SHS extrusion), Theor. Found. Chem. Eng., 2014, vol. 48, no. 6, pp. 751–763.

    Article  CAS  Google Scholar 

  12. Stolin, A.M. and Bazhin, P.M., SHS extrusion: an overview, Int. J. Self-Propag. High-Temp. Synth., 2014, vol. 23, no. 2, pp. 65–73.

    Article  Google Scholar 

  13. Stolin, A.M., Bazhin, P.M., and Alymov, M.I., Preparation of nanostructured composite ceramic materials and products under conditions of a combination of combustion and high-temperature deformation (SHS extrusion), Nanotechnol. Russ., 2014, vol. 9, nos. 11–12, pp. 583–600.

    Google Scholar 

  14. Galyshev, S.N., Stolin, A.M., and Bazhin, P.M., Ti–Al intermetallics by free SHS compression, Inzh. Fiz., 2009, no. 9, pp. 25–28.

    Google Scholar 

  15. Galyshev, S.N., Stolin, A.M., and Bazhin, P.M., Preparation of nickel aluminide-based intermetallic materials by free SHS compression by free SHS compression, Inzh. Fiz., 2009, no. 9, pp. 25–28.

    Google Scholar 

  16. Stolin, A.M., Vrel, D., Galyshev, S.N., Hendaoui, A., Bazhin, P.M., and Sytschev, A.E., Hot forging of MAX compounds SHS-produced in the Ti–Al–C system, Int. J. Self-Propag. High-Temp. Synth., 2009, vol. 18, no. 3, pp. 194–199.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. V. Mikheev.

Additional information

Original Russian Text © M.V. Mikheev, P.M. Bazhin, A.M. Stolin, M.I. Alymov, 2016, published in Neorganicheskie Materialy, 2016, Vol. 52, No. 2, pp. 173–179.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Mikheev, M.V., Bazhin, P.M., Stolin, A.M. et al. Effect of titanium on the rheological properties of MoSi2-based materials prepared by SHS. Inorg Mater 52, 141–146 (2016). https://doi.org/10.1134/S0020168516020102

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0020168516020102

Keywords

Navigation