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Synthesis and physicochemical properties of titanium(IV)- and cobalt(II)-Based photocatalytic oxide composites

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Abstract

We have studied the phase transitions, morphology, and photocatalytic activity of composites based on titanium(IV) and cobalt(II) oxides at Co doping levels from 0.5 to 60 wt % and heat-treatment temperatures from 80 to 1150°C. The highest photocatalytic activity under illumination in the spectral range λ ≥ 670 nm is offered by mesoporous X-ray amorphous and multiphase (X-ray amorphous phase, anatase, rutile, and CoTiO3) nanomaterials containing 5–20 wt % Co, whereas two-phase materials (rutile + CoTiO3) have the lowest photocatalytic activity.

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References

  1. Fenezonov, V.B. and Parmon, V.N., Introduction to the physical chemistry of texturing of heterogeneous photocatalysts, in Promyshlennyi kataliz v lektsiyakh (Lectures on Industrial Catalysis), Moscow: Kalvis, 2005, part 1.

    Google Scholar 

  2. Jin, Q., Fujishima, M., and Tada, H., Visible-lightactive iron oxide-modified anatase titanium(IV) dioxide, J. Phys. Chem. C, 2011, vol. 115, no. 14, pp. 6478–6483.

    Article  CAS  Google Scholar 

  3. Sedneva, T.A., Lokshin, E.P., Kalinnikov, V.T., and Belikov, M.L., Photocatalytic activity of tungstenmodified titanium oxide, Dokl. Phys. Chem., 2012, vol. 443, no. 1, pp. 57–59.

    Article  CAS  Google Scholar 

  4. Sedneva, T.A., Lokshin, E.P., Belikov, M.L., and Belyaevskii, A.T., TiO2and Nb2O5-based photocatalytic composites, Inorg. Mater., 2013, vol. 49, no. 4, pp. 382–389.

    Article  CAS  Google Scholar 

  5. Samsonov, G.V., Bulankova, T.G., and Burykina, A.L., Fiziko-khimicheskie svoistva okislov. Spravochnik (Physicochemical Properties of Oxides: A Handbook), Moscow: Metallurgiya, 1969.

    Google Scholar 

  6. Lapidus, A.L., Krylova, A.Yu., Kozlova, G.V., and Kondrat’ev, L.T., Effect of oxide additives on the activity of cobalt carbonyl catalysts for the synthesis of hydrocarbons from CO and H2, Izv. Akad. Nauk SSSR, Neorg. Mater., 1989, vol. 25, no. 11, pp. 2425–2428.

    Google Scholar 

  7. Zhang Guoge, Huang Haitao, Li Wenfang, Yu Fei, Wu Huijun, and Zhou Limin, Enhanced photocatalytic activity of CoO/TiO2 nanotube composite, Electrochim. Acta, 2012, vol. 81, pp. 117–122.

    Article  CAS  Google Scholar 

  8. Xu Rui, Li Jia, Wang Jun, Wang Xiaofang, Liu Bin, Wang Baoxin, Luan Xiaoyu, and Zhang Xiangdong, Photocatalytic degradation of Er3+ organic dyes under solar light irradiation combined with Er3+:YAlO3/Feand Co-doped TiO2 coated composites, Sol. Energy Mater. Sol. Cells, 2010, vol. 94, no. 6, pp. 1157–1165.

    Article  CAS  Google Scholar 

  9. Carvalho Hudson, W.P., Batista Ana, P.L., Bertholdo, R., Santilli Celso, V., Pulcinelli Sandra, H., and Ramalho Teodorico, C., Photocatalyst TiO2–Co: the effect of doping depth profile on methylene blue degradation, J. Mater. Sci., 2010, vol. 45, no. 20, pp. 5698–5703.

    Article  Google Scholar 

  10. Surkin, R.R., Zhimalov, A.B., Bondareva, L.N., Gorina, I.N., Gerancheva, O.E., and Polkan, G.A., RF Patent 2434819, Byull. Izobret., 2011, no. 33.

  11. Yu-Fen Wang, Meng-Chun Hsieh, Jyh-Fu Lee, and Chia-Min Yan, Nonaqueous synthesis of CoOx/TiO2 nanocomposites showing high photocatalytic activity of hydrogen generation, Appl. Catal., B, 2013, vols. 142–143, pp. 626–632.

    Google Scholar 

  12. Ivanova, V.P., Kasatov, B.K., Krasavina, T.N., and Rozinova, E.L., Termicheskii analiz mineralov i gornykh porod (Thermal Analysis of Minerals and Rocks), Leningrad: Nedra, 1974.

    Google Scholar 

  13. Gregg, S.J. and Sing, K.S.W., Adsorption, Surface Area, and Porosity, New York: Academic, 1982.

    Google Scholar 

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Correspondence to T. A. Sedneva.

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Original Russian Text © T.A. Sedneva, M.L. Belikov, E.P. Lokshin, A.T. Belyaevskii, 2016, published in Neorganicheskie Materialy, 2016, Vol. 52, No. 2, pp. 187–196.

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Sedneva, T.A., Belikov, M.L., Lokshin, E.P. et al. Synthesis and physicochemical properties of titanium(IV)- and cobalt(II)-Based photocatalytic oxide composites. Inorg Mater 52, 153–162 (2016). https://doi.org/10.1134/S0020168516010143

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  • DOI: https://doi.org/10.1134/S0020168516010143

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