Abstract
This paper describes a sequential, two-step process for the synthesis of a composite based on graphene and CeO2 nanoparticles using supercritical fluid. The process includes the reduction of a prepre-pared graphene oxide/CeO2 nanocomposite with supercritical propanol-2. The nanocomposites thus obtained have been characterized by transmission electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy.
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Johns, J.E., Alaboson, J.M., Patwardhan, S.P., Ryder, C.R., Schatz, G.C., and Hersam, M.C., Metal oxide nanoparticle growth on graphene via chemical activation with atomic oxygen, J. Am. Chem. Soc., 2013, vol. 135, pp. 18 121–18 125.
Gotoh, K., Kinumoto, T., Fujii, E., Yamamoto, A., Hashimoto, H., Ohkubo, T., Itadani, A., Kuroda, Y., and Ishida, H., Exfoliated graphene sheets decorated with metal/metal oxide nanoparticles: simple preparation from cation exchanged graphite oxide, Carbon, 2011, vol. 49, pp. 1118–1125.
Huajie, Y., Zhao, S., Wan, J., Tang, H., Chang, L., He, L., Zhao, H., Gao, Y., and Tang, Z., Three-dimensional graphene/metal oxide nanoparticle hybrids for high-performance capacitive deionization of saline water, Adv. Mater., 2013, vol. 25, no. 43, pp. 6270–6276.
Lee, C., Wei, X.D., Kysar, J.W., and Hone, J., Measurement of the elastic properties and intrinsic strength of monolayer graphene, Science, 2008, vol. 321, pp. 385–388.
Geim, A.K., Graphene: status and prospects, Science, 2009, vol. 324, pp. 1530–1534.
Geim, A.K. and Novoselov, K.S., The rise of graphene, Nat. Mater., 2007, vol. 6, pp. 183–191.
Zhu, Y., Murali, S., Cai, W., Li, X., Suk, J.W., Potts, J.R., and Ruoff, R.S., Graphene and graphene oxide: synthesis, properties, and applications, Adv. Mater., 2010, vol. 22, no. 35, pp. 3906–3924.
Akhavan, O., Photocatalytic reduction of graphene oxides hybridized by ZnO nanoparticles in ethanol, Carbon, 2011, vol. 49, pp. 11–18.
Zhang, X.Y., Li, H.P., Cui, X.L., and Lin, Y., Graphene/TiO2 nanocomposites: synthesis, characterization and application in hydrogen evolution from water photocatalytic splitting, J. Mater. Chem., 2010, vol. 20, no. 14, pp. 2801–2806.
Wang, B., Su, D., Park, J., Ahn, H., and Wang, G., Graphene-supported SnO2 nanoparticles prepared by a solvothermal approach for an enhanced electrochemical performance in lithium-ion batteries, Nanoscale Res. Lett., 2012, vol. 7, pp. 215–218.
Jasinski, P., Suzuki, T., and Anderson, H.U., Nanocrystalline undoped ceria oxygen sensor, Sens. Actuators, B, 2003, vol. 95, pp. 73–77.
Corma, A., Atienzar, P., García, H., and Chane-Ching, J.-Y., Hierarchically mesostructured doped CeO2 with potential for solar-cell use, Nat. Mater., 2004, vol. 6, pp. 394–397.
Liu, X.W., Zhou, K.B., Wang, L., Wang, B.Y., and Li, Y.D., Oxygen vacancy clusters promoting reducibility and activity of ceria nanorods, J. Am. Chem. Soc., 2009, vol. 131, no. 9, pp. 3140–3141.
Shekunova, T.O., Gil’, D.O., Ivanova, O.S., Ivanov, V.K., and Tret’yakov, Yu.D., Synthesis, bioactivity, and photocatalytic activity of citrate ion-stabilized ceria sols, Nanosist.: Fiz., Khim., Mat., 2013, vol. 4, no. 1, pp. 83–89.
Zhou, X., Qiao, J., Yang, L., and Zhang, J., A review of graphene-based nanostructural materials for both catalyst supports and metal-free catalysts in PEM fuel cell oxygen reduction reactions, Adv. Energy Mater., 2014, vol. 4, no. 3, pp. 1–25.
An, K., Alayoglu, S., Musselwhite, N., Na, K., and Somorjai, G.A., Designed catalysts from Pt nanoparticles supported on macroporous oxides for selective isomerization of n-hexane, J. Am. Chem. Soc., 2014, vol. 136, no. 19, pp. 6830–6833.
Hummers, W.S., Jr. and Offeman, R.E., Preparation of graphitic oxide, J. Am. Chem. Soc., 1958, vol. 80, pp. 1339–1339.
Shalyapina, A.Ya., Solov’eva, A.Yu., Zaporozhets, M.A., Khokhlov, E.M., Plotnichenko, V.G., Savilov, S.V., Egorov, A.V., Nikolaichik, V.I., Buslaeva, E.Yu., Rustamova, E.G., Avilov, A.S., and Gubin, S.P., Zinc oxide nanoparticles immobilized on graphene flake, Russ. J. Inorg. Chem., 2013, vol. 58, no. 3, pp. 354–360.
Tkachev, S.V., Buslaeva, E.Yu., Naumkin, A.V., Kotova, S.L., Laure, I.V., and Gubin, S.P., Reduced graphene oxide, Inorg. Mater., 2012, vol. 48, no. 8, pp. 796–802.
Gubin, S.P. and Buslaeva, E.Yu., Supercritical isopropanol as a reductant of inorganic oxides, Sverkhkrit. Flyuidy: Teor. Prakt., 2009, vol. 4, no. 4, pp. 73–96.
Yan, M., Wei, W., and Zuoren, N., Influence of pH on morphology and formation mechanism of CeO2 nanocrystalline, J. Rare Earths, 2007, vol. 25, pp. 53–57.
Pouretedal, H.R. and Kadkhodaie, A., Synthetic CeO2 nanoparticle catalysis of methylene blue photodegradation: kinetics and mechanism, Chin. J. Catal., 2010, vol. 31, no. 11, pp. 1328–1334.
Naumkin, V., Kraut-Vass, A., Gaarenstroom, S.W., and Powell, C.J., NIST Photoelectron Spectroscopy Database, Version 4.1, Gaithersburg: National Inst. of Standards and Technology, 2012. http://srdata.nist.gov/xps/.
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Original Russian Text © A.Yu. Soloveva, Yu.V. Ioni, E.Yu. Buslaeva, M.A. Zaporozhets, S.V. Savilov, A.V. Naumkin, S.P. Gubin, 2015, published in Neorganicheskie Materialy, 2015, Vol. 51, No. 8, pp. 923–928.
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Soloveva, A.Y., Ioni, Y.V., Buslaeva, E.Y. et al. Fabrication and characterization of composites based on CeO2 nanoparticles and graphene. Inorg Mater 51, 848–853 (2015). https://doi.org/10.1134/S0020168515080178
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DOI: https://doi.org/10.1134/S0020168515080178