Abstract
Using in situ X-ray diffraction in conjunction with the Rietveld method, we have studied the dynamics of phase formation in the early stages of hardening of mechanically activated blended binders based on Portland cement and mineral admixtures: granulated magnesia-ferriferous slag and nepheline concentrate. The results demonstrate accelerated clinker hydration in the composition of the blended cements compared to admixture-free Portland cement, which correlates with the compressive strength of the samples.
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Bikbau, M.Ya., Development of the cement industry in Russia: where to go?, Tekhnol. Betonov, 2013, no. 1, pp. 20–25.
Georgichny, Z., New cements and technologies of alternative binders, Tsement Ego Primen., 2013, no. 2, pp. 40–45.
Whittaker, M., Zajac, M., Ben Haha, M., Bullerjahn, F., and Black, L., The role of the alumina content of slag, plus the presence of additional sulfate on the hydration and microstructure of Portland cement-slag blends, Cem. Concr. Res, 2014, vol. 66, pp. 91–101.
Usherov-Marshak, A.V., Zlatkovskii, O.A., and Tsiak, M., Assessing the efficiency of chemical and mineral admixtures in early cement hydration, Inorg. Mater., 2004, vol. 40, no. 8, pp. 886–890.
Wu, H.C., Inorganic binders: a new look at the hydration/hardening process, Alitinform, 2014, vol. 33, no. 1, pp. 26–43.
Le Xu, G. and Ben Haha, M., Effect of the filler on early Portland cement hydration, Tsement Ego Primen., 2012, no. 4, pp. 46–51.
Heinicke, G., Tribochemistry, Berlin: Akademie, 1984.
Avvakumov, E.G. and Gusev, A.A., Mekhanicheskie metody aktivatsii v pererabotke prirodnogo i tekhnogennogo syr’ya (Mechanical Activation Methods in the Processing of Natural and Anthropogenic Raw Materials), Novosibirsk: Geo, 2009.
Lomovskii, O.I. and Boldyrev, V.V., Mekhanokhimiya v reshenie ekologicheskikh zadach (Mechanochemistry and Solutions to Environmental Problems), Novosibirsk: GPNTB Sib. Otd. Ross. Akad. Nauk, 2006.
Molchanov, V.I., Selezneva, O.G., and Zhirnov, E.N., Aktivatsiya mineralov pri izmel’chenii (Grinding-Assisted Activation of Minerals), Moscow: Nedra, 1988.
Juhasz, A.Z. and Opoczky, L., Mechanical Activation of Minerals by Grinding. Pulverizing and Morphology of Particles, Chichester: Ellis Horwood, 1990.
Kuz’mina, V.P., Mechanical activation of cements, Stroit. Mater., 2006, no. 7, pp. 7–9.
Khripacheva, I.S., Garkavi, M.S., Artamonova, A.V., Voronin, K.M., and Artamonov, A.V., Cements ground by centrifugal impact processing, Tsement Ego Primen., 2013, no. 4, pp. 106–109.
Kumar, S., Bandopadhyay, A., Rajinikanth, V., Alex, T.C., and Kumar, R., Improved processing of blended slag cement through mechanical activation, J. Mater. Sci., 2004, vol. 39, no. 10, pp. 3449–3452.
Kalinkin, A.M., Gurevich, B.I., Pakhomovskii, Ya.A., Kalinkina, E.V., and Tyukavkina, V.V., Effect of mechanical activation of magnesia-ferriferous slags in carbon dioxide on their properties, Russ. J. Appl. Chem., 2009, vol. 82, no. 8, pp. 1346–1350.
Hesse, C., Goetz-Neunhoeffer, F., Neubauer, J., Braeu, M., and Gaeberlein, P., Quantitative in situ x-ray diffraction analysis of early hydration of Portland cement at defined temperatures, Powder Diffr., 2009, vol. 24, no. 2, pp. 112–115.
Gurevich, B.I., Kalinkin, A.M., Kalinkina, E.V., and Tyukavkina, V.V., Effect of mechanical activation of nepheline concentrate on its binding properties in mixed cements, Russ. J. Appl. Chem., 2013, vol. 86, no. 7, pp. 965–970.
Kalinkina, E.V., Kalinkin, A.M., Forsling, W., and Makarov, V.N., Sorption of atmospheric carbon dioxide and structural changes of Ca and Mg silicate minerals during grinding. I. Diopside, Int. J. Miner. Process., 2001, vol. 61, no. 4, pp. 273–288.
Bikbau, M.Ya., Molchanov, V.N., and Chen Lung, Production of mechanochemically activated cements (binders) of low water requirement, Tsement Ego Primen., 2008, no. 3, pp. 80–87.
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Original Russian Text © A.M. Kalinkin, M.G. Krzhizhanovskaya, B.I. Gurevich, E.V. Kalinkina, V.V. Tyukavkina, 2015, published in Neorganicheskie Materialy, 2015, Vol. 51, No. 8, pp. 901–907.
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Kalinkin, A.M., Krzhizhanovskaya, M.G., Gurevich, B.I. et al. Hydration of mechanically activated blended cements studied by in situ X-ray diffraction. Inorg Mater 51, 828–833 (2015). https://doi.org/10.1134/S0020168515080099
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DOI: https://doi.org/10.1134/S0020168515080099