Skip to main content
Log in

Photoactivated nanocrystallization and hardness of Fe78P20Si2 alloy

  • Published:
Inorganic Materials Aims and scope

Abstract

The structural changes induced in an amorphous Fe78P20Si2 alloy by heat treatment and lamp processing have been compared using X-ray diffraction. The results demonstrate that the main effect of the lamp processing is to increase the crystallization rate. Under nanoindentation conditions that do not lead to crystallization under the action of a concentrated load (as verified by transmission electron microscopy), we have determined the hardness (8 ± 0.3 GPa) and Young’s modulus (130 ± 10 GPa) of the amorphous alloy. Lamp processing conditions have been found that lead to the formation of an amorphous-nanocrystalline composite whose hardness is almost twice that of the parent amorphous alloy, without loss of plasticity.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Glezer, A.M. and Permyakova, I.E., Nanokristally, zakalennye iz rasplava (Liquid-Quenched Nanocrystals), Moscow: Fizmatlit, 2012.

    Google Scholar 

  2. Vavilova, V.V., Ievlev, V.M., Isaenko, A.P., et al., Effects of thermal annealing and pulsed photon processing on the relaxation and crystallization of amorphous Fe-P-Si alloys, Inorg. Mater., 2004, vol. 40, no. 2, pp. 152–159.

    Article  CAS  Google Scholar 

  3. Vavilova, V.V., Ievlev, V.M., Kalinin, Yu.E., et al., Effect of pulsed photon irradiation on the formation of a nanocrystalline structure in Fe-P-Nb alloys, Russ. Metall. (Engl. Transl.), 2011, no. 3, pp. 471–478.

    Google Scholar 

  4. Belousov, O.K., Vavilova, V.V., Ievlev, V.M., et al., Effects of heat treatment and flash lamp processing on the mechanical properties of amorphous Al87Ni10Nd3 with a tendency to nanocrystallization, Deform. Razrushenie Mater., 2007, no. 6, pp. 10–17.

    Google Scholar 

  5. Vavilova, V.V., Ievlev, V.M., Isaenko, A.P., et al., Nanoscale crystallization in the amorphous alloy Fe79P14.2Si4.4Mn2.2V0.2 upon pulsed photon annealing, Inorg. Mater., 2003, vol. 39, no. 1, pp. 72–76.

    Article  CAS  Google Scholar 

  6. Ievlev, V.M., Activation of solid-state processes by light from gas-discharge lamps, Usp. Khim., 2013, vol. 82, no. 9, pp. 815–834.

    Article  Google Scholar 

  7. Darinskiy, B.M. and Yudin, L.Yu., Mechanisms of the enhancement of amorphous alloy crystallization under illumination, Bull. Russ. Acad. Sci.: Phys., 2010, vol. 74, no. 9, pp. 1299–1303.

    Article  Google Scholar 

  8. Donovan, P.E. and Stobbs, W.M., The structure of shear bands in metallic glasses, Acta Metall., 1981, vol. 29, pp. 1419–1436.

    Article  CAS  Google Scholar 

  9. Jiang, W.H., Pinkerton, F.E., and Atzmon, M., Effect of strain rate on the formation of nanocrystallites in an Al-based amorphous alloy during nanoindentation, J. Appl. Phys., 2003, vol. 93, no. 11, pp. 9287–9290.

    Article  CAS  Google Scholar 

  10. Kim, J.J., Choi, Y., Suresh, S., et al., Nanocrystallization during nanoindentation of a bulk amorphous metal alloy at room temperature, Science, 2002, vol. 295, no. 5555, pp. 654–657.

    CAS  Google Scholar 

  11. Huang, S., Structure and Structure Analysis of Amorphous Materials, Oxford: Clarendon, 1984, p. 48.

    Google Scholar 

  12. Abrosimova, G.E., Aronin, A.S., and Kholstin, N.N., On the determination of the volume fraction of the crystalline phase in amorphous-crystalline alloys, Phys. Solid State, 2010, vol. 52, no. 3, pp. 445–451.

    Article  CAS  Google Scholar 

  13. Oliver, W.C. and Pharr, G.M., An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments, J. Mater. Res., 1992, vol. 7, no. 6, pp. 1564–1583.

    Article  CAS  Google Scholar 

  14. Okamoto, H., The Fe-P (iron-phosphorus) system, Bull. Alloy Phase Diagrams, 1990, vol. 11, no. 4, pp. 404–412.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to N. A. Palii.

Additional information

Original Russian Text © M.S. Antonova, E.K. Belonogov, A.V. Boryak, V.V. Vavilova, V.M. Ievlev, S.V. Kannykin, N.A. Palii, 2015, published in Neorganicheskie Materialy, 2015, Vol. 51, No. 3, pp. 333–337.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Antonova, M.S., Belonogov, E.K., Boryak, A.V. et al. Photoactivated nanocrystallization and hardness of Fe78P20Si2 alloy. Inorg Mater 51, 283–287 (2015). https://doi.org/10.1134/S0020168515030012

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0020168515030012

Keywords

Navigation