Abstract
We have studied the effect of Li+, Na+, K+, and Ag+ for proton ion exchange on the structural characteristics of crystalline tungstoantimonic acid with the composition H3OWSbO6 · nH2O. The metal ion substitutions for protons have been shown to result in the formation of a continuous series of solid solutions existing in a limited composition range. The dependence of the unit-cell parameter on the ionic radius of the substituents has been analyzed.
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Original Russian Text © O.A. Mezhenina, V.A. Burmistrov, A.A. Biryukova, 2015, published in Neorganicheskie Materialy, 2015, Vol. 51, No. 2, pp. 208–212.
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Mezhenina, O.A., Burmistrov, V.A. & Biryukova, A.A. Structure and ion-exchange properties of crystalline tungstoantimonic acid. Inorg Mater 51, 167–171 (2015). https://doi.org/10.1134/S0020168515010136
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DOI: https://doi.org/10.1134/S0020168515010136