Abstract
Submicron grain size Ba1 − x La x TiO3 (x = 0.025–0.05) barium titanate ceramics have been prepared by two-step heat treatment. The grain size of the ceramics was 200–400 nm at x = 0.025 and 300–700 nm at x = 0.05, and the ceramics had increased dielectric permittivity (ɛmax ≃23 000 at x = 0.025 and ɛmax ≃ 46 000 at x = 0.05) compared to large-grained (>1 μm) materials.
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Buscaglia, M.T., Buscaglia, V., Viviani, M., et al., Influence of foreign ions on the crystal structure of BaTiO3, J. Eur. Ceram. Soc., 2000, vol. 20, no. 12, pp. 1997–2007.
Niesz, K., Ould-Ely, T., Tsukamoto, H., and Morse, D.E., Engineering grain size and electrical properties of donor-doped barium titanate ceramics, Ceram. Int., 2011, vol. 37, no. 1, pp. 303–311.
Shut, V.N., Syrtsov, S.R., and Trublovsky, V.L., Ferroelectric properties of compositionally graded BST ceramics, Phase Transitions, 2010, vol. 83, no. 5, pp. 368–377.
Vijatović, M.M., Stojanović, B.D., Bobić, J.D., et al., Properties of lanthanum doped BaTiO3 produced from nanopowders, Ceram. Int., 2010, vol. 36, no. 6, pp. 1817–1824.
Morrison, F.D., Sinclair, D.C., and West, A.R., Doping mechanisms and electrical properties of La-doped BaTiO3 ceramics, Int. J. Inorg. Mater., 2001, vol. 3, no. 8, pp. 1205–1210.
Shihua, D., Ping, Z., Tianxiu, S., and Xiaojing, Y., The dielectric behavior of BaTiO3 based ceramics doped with La/Mn, Ferroelectrics, 2012, vol. 426, no. 1, pp. 66–71.
Fujii, I., Trolier-McKinstry, S., and Nies, C., Effect of grain size on dielectric nonlinearity in model BaTiO3-based multilayer ceramic capacitors, J. Am. Ceram. Soc., 2011, vol. 94, no. 1, pp. 194–199.
Buscaglia, M.T., Viviani, M., Buscaglia, V., et al., High dielectric constant and frozen macroscopic polarization in dense nanocrystalline BaTiO3 ceramics, Phys. Rev. B: Condens. Matter Mater. Phys., 2006, vol. 73, no. 6, paper 064 114.
Fujii, I., Ugorek, M., and Trolier-McKinstry, S., Grain size effect on the dielectric nonlinearity of BaTiO3 ceramics, J. Appl. Phys., 2010, vol. 107, no. 10, paper 104 116.
Lunkenheimer, P., Krohns, S., Riegg, S., et al., Colossal dielectric constants in transition-metal oxides, Eur. Phys. J. Spec. Top., 2010, vol. 180, no. 1, pp. 61–89.
Valdez-Nava, Z., Guillemet-Fritsch, S., Tenailleau, Ch., et al., Colossal dielectric permittivity of BaTiO3-based nanocrystalline ceramics sintered by spark plasma sintering, J. Electroceram., 2009, vol. 22, nos. 1–3, pp. 238–244.
Chen, I.-W. and Wang, X.-H., Sintering dense nanocrystalline ceramics without final-stage grain growth, Nature, 2000, vol. 404, no. 6774, pp. 168–171.
Tian, Z., Wang, X., Lee, S., et al., Microstructure evolution and dielectric properties of ultrafine grained BaTiO3-based ceramics by two-step sintering, J. Am. Ceram. Soc., 2011, vol. 94, no. 4, pp. 1119–1124.
Maca, K., Pouchly, V., and Shen, Z., Two-step sintering and spark plasma sintering of Al2O3, ZrO2 and SrTiO3 ceramics, Integr. Ferroelectr., 2008, vol. 99, no. 1, pp. 114–124.
Shut, V.N., Kostomarov, S.V., and Gavrilov, A.V., PTCR ceramics produced from oxalate-derived barium titanate, Inorg. Mater., 2008, vol. 44, no. 8, pp. 905–910.
Bhaskar Reddy, S., Prasad Rao, K., and Ramachandra Rao, M.S., Effect of La substitution on the structural and dielectric properties of BaZr0.1Ti0.9O3 ceramics, J. Alloys Compd., 2009, vol. 481, nos. 1–2, pp. 692–696.
Lin, M.-H. and Lu, H.-Y., Densification retardation in the sintering of La2O3-doped barium titanate ceramic, Mater. Sci. Eng., A, 2002, vol. 323, nos. 1–2, pp. 167–176.
Wang, X.-H., Deng, X.-Y., Bai, H.-L., et al., Two-step sintering of ceramics with constant grain-size: II. BaTiO3 and Ni-Cu-Zn ferrite, J. Am. Ceram. Soc., 2006, vol. 89, no. 2, pp. 438–443.
Han, H., Voisin, C., Guillemet-Fritsch, S., et al., Origin of colossal permittivity in BaTiO3 via broadband dielectric spectroscopy, J. Appl. Phys., 2013, vol. 113, no. 2, 024 102.
Raevski, I.P., Kuropatkina, S.A., Kubrin, S.P., et al., Dielectric and Mössbauer studies of high-permittivity BaFe1/2Nb1/2O3 ceramics with cubic and monoclinic perovskite structures, Ferroelectrics, 2009, vol. 379, no. 1, pp. 48–54.
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Original Russian Text © V.N. Shut, S.R. Syrtsov, V.L. Trublovsky, D.A. Il’yushchenko, I.O. Troyanchuk, 2014, published in Neorganicheskie Materialy, 2014, Vol. 50, No. 7, pp. 801–805.
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Shut, V.N., Syrtsov, S.R., Trublovsky, V.L. et al. Microstructure and properties of Ba1 − x La x TiO3 ceramics with submicron grain size. Inorg Mater 50, 745–749 (2014). https://doi.org/10.1134/S0020168514070139
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DOI: https://doi.org/10.1134/S0020168514070139