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Catalytic properties of composite materials based on mesoporous silica and zirconium hydrogen phosphate

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Abstract

We have synthesized composite materials based on SBA-15 mesoporous silica and zirconium phosphate. The materials have been characterized by scanning electron microscopy, transmission electron microscopy, inductively coupled plasma mass spectrometry, X-ray diffraction, BET measurements, 31P NMR spectroscopy, and thermogravimetry, and have been employed as catalysts for ethanol dehydration. Even though their catalytic activity is somewhat lower than that of fine-particle zirconium phosphates with layered and framework structures, they offer an increased ethylene yield at low temperatures.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    I. A. Stenina & A. B. Yaroslavtsev

  2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninskii pr. 29, Moscow, 119991, Russia

    A. B. Il’in, N. A. Zhilyaeva & A. B. Yaroslavtsev

  3. Siberian Federal University, Svobodnyi pr. 79/10, Krasnoyarsk, 660041, Russia

    S. D. Kirik

  4. Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences, Leninskii pr. 49, Moscow, 119991, Russia

    G. Yu. Yurkov

Authors
  1. I. A. Stenina
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  2. A. B. Il’in
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  3. S. D. Kirik
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  4. N. A. Zhilyaeva
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  5. G. Yu. Yurkov
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  6. A. B. Yaroslavtsev
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Correspondence to I. A. Stenina.

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Original Russian Text © I.A. Stenina, A.B. Il’in, S.D. Kirik, N.A. Zhilyaeva, G.Yu. Yurkov, A.B. Yaroslavtsev, 2014, published in Neorganicheskie Materialy, 2014, Vol. 50, No. 6, pp. 635–640.

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Stenina, I.A., Il’in, A.B., Kirik, S.D. et al. Catalytic properties of composite materials based on mesoporous silica and zirconium hydrogen phosphate. Inorg Mater 50, 586–591 (2014). https://doi.org/10.1134/S0020168514060181

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  • DOI: https://doi.org/10.1134/S0020168514060181

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