Skip to main content
SpringerLink
Log in

Phase equilibria in the reciprocal system 3Tl2S + Bi2Te3 ↔ 3Tl2Te + Bi2S3

  • Published:
Inorganic Materials Aims and scope

Abstract

Phase equilibria in the reciprocal system 3Tl2S + Bi2Te3 ↔ 3Tl2Te + Bi2S3 (A) have been studied by differential thermal analysis, X-ray diffraction, microhardness tests, and emf measurements using thallium concentration cells, and a number of vertical sections, the 300-K isothermal section of its phase diagram, and the liquidus projection have been mapped out. The system is shown to be reversibly reciprocal, with broad solid solution regions in the Tl2S-Tl2Te-Tl9BiTe6 subsystem and along the TlBiS2-TlBiTe2 join. We have determined the homogeneity ranges and primary crystallization fields of the phases and identified the nature and coordinates of invariant equilibria in system A.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Shevel’kov, A.V., Chemical aspects of thermoelectric materials engineering, Usp. Khim., 2008, vol. 77, no. 1, pp. 3–21.

    Google Scholar 

  2. Yamanaka, Sh., Kosuka, A., and Korosaki, K., Thermoelectric properties of Tl9BiTe6, J. Alloys. Compd., 2003, vol. 352, pp. 275–278.

    Article  CAS  Google Scholar 

  3. Tao, X., Jund, P., Viennois, R., and Tédenac, J.-C., Physical properties of thallium-tellurium based thermoelectric compounds using first-principles simulations, J. Phys. Chem. A, 2011, vol. 115, no. 31, pp. 8761–8766.

    Article  CAS  Google Scholar 

  4. Eremeev, S.V., Koroteev, Yu.M., and Chulkov, E.V., Ternary thallium-based semimetal chalcogenides Tl-V-VI2 as a new class of three-dimensional topological insulators, JETP Lett., 2010, vol. 91, no. 11, pp. 594–598.

    Article  CAS  Google Scholar 

  5. Jafarov, Y.I., Mirzoeva, A.M., and Babanly, M.B., Reciprocal system 3Tl2S+ Sb2Se3 ↔ 3Tl2Se + Sb2S3, Russ. J. Inorg. Chem., 2008, vol. 53, no. 1, pp. 146–152.

    Article  Google Scholar 

  6. Jafarov, Y.I., Babanly, M.B., Shevelkov, A.V., and Aliev, Z.S., Experimental investigation of the 3Tl2Se + Sb2Te3 ↔ 3Tl2Te + Sb2Se3 phase diagram, J. Alloys. Compd., 2013, vol. 555, pp. 184–192.

    Article  CAS  Google Scholar 

  7. Dzhafarov, Y.I., Mirzoeva, A.M., and Babanly, M.B., Reciprocal system 3Tl2S + Bi2Se3 ↔ 3Tl2Se + Bi2S3, Russ. J. Inorg. Chem., 2006, vol. 51, no. 5, pp. 805–809.

    Article  Google Scholar 

  8. Jafarov, Ya.I., Rzaeva, N.A., and Babanly, M.B., Phase equilibria in the system, Inorg. Mater., 2008, vol. 44, no. 11, pp. 1183–1186.

    Article  CAS  Google Scholar 

  9. Veisova, S.M., Guseinov, Z.A., Yusibov, Yu.A., and Babanly, M.B., Reciprocal system 3Tl2Se + Bi2Te3 ↔ ↔3Tl2Te + Bi2Se3, Russ. J. Inorg. Chem., 2003, vol. 48, no. 9, pp. 1425–1430.

    Google Scholar 

  10. Binary Alloy Phase Diagrams, Massalski, T.B., Ed., Materials Park: ASM International, 1990, 2nd ed.

    Google Scholar 

  11. Diagrammy sostoyaniya dvoinykh metallicheskikh sistem. Spravochnik (Phase Diagrams of Binary Metallic Systems), Lyakishev, N.P., Ed., Moscow: Mashinostroenie, 1996, vol. 1; 1997, vol. 2.

    Google Scholar 

  12. Abrikosov, N.Kh., et al., Poluprovodnikovye khal’kogenidy i splavy na ikh osnove (Semiconducting Chalcogenides and Their Alloys), Moscow: Nauka, 1968.

    Google Scholar 

  13. Cerny, R., Joubert, J., Filinchuk, Y., and Feutelais, Y., Tl2Te and its relationship with Tl5Te3, Acta. Crystallogr, Sect. C: Cryst. Struct. Commun., 2002, vol. 58, no. 5, pp. 163–165.

    Article  Google Scholar 

  14. Asadov, M.M., Babanly, M.B., and Kuliev, A.A., Phase equilibria in the Tl2S-Tl2Te system, Azerb. Khim. Zh., 1977, no. 2, pp. 94–95.

    Google Scholar 

  15. Julien-Pouzol, M. and Guittard, M., Sur le compose Tl4Bi2S5 et diagramme de phase Tl2S-Bi2S3, Bull. Soc. Chim. Fr., 1975, nos. 5–6, pp. 1037–1039.

    Google Scholar 

  16. Babanly, M.B., Kesamanly, M.F., and Kuliev, A.A., System Tl-Tl2S-Bi2S3-Bi, Zh. Neorg. Khim., 1988, vol. 33, no. 9, pp. 2371–2375.

    CAS  Google Scholar 

  17. Voroshilov, Yu.V., Evstigneeva, T.L., and Nekrasov, I.Ya., Kristallokhimicheskie tablitsy troinykh khal’kogenidov (Crystal-Chemical Tables for Ternary Chalcogenides), Moscow: Nauka, 1989.

    Google Scholar 

  18. Babanly, M.B., Akhmad’yar, A., and Kuliev, A.A., System Tl2Te-Bi2Te3-Te, Zh. Neorg. Khim., 1985, vol. 30, no. 9, pp. 2356–2361.

    CAS  Google Scholar 

  19. Doert, T. and Böttcher, P., Crystal structure of bismuthnonathallium hexatelluride BiTl9Te6, Z. Kristallogr., 1994, vol. 209, pp. 95–100.

    Article  CAS  Google Scholar 

  20. Pradel, A., Tedenac, J.C., Brun, G., and Maurin, M., Mise au point dans le ternaire Tl-Bi-Te. Existence de deux phases nonstoechiometriques de type TlBiTe2, J. Solid State Chem., 1982, vol. 5, no. 1, pp. 99–111.

    Article  Google Scholar 

  21. Beglaryan, M.L. and Abrikosov, N.Kh., System Bi2Te3-Bi2S3, Dokl. Akad. Nauk SSSR, 1959, vol. 129, no. 1, pp. 135–137.

    CAS  Google Scholar 

  22. Babanly, M.B. and Yusibov, Yu.A., Elektrokhimicheskie metody v termodinamike neorganicheskikh sistem (Electrochemical Methods in the Thermodynamics of Inorganic Systems), Baku: ELM, 2011.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Baku State University, ul. Khalilova 23, Baku, AZ1148, Azerbaijan

    Ya. I. Jafarov, S. Z. Imamalieva & M. B. Babanly

  2. Moscow State University, Moscow, 119992, Russia

    V. P. Zlomanov

Authors
  1. Ya. I. Jafarov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. Z. Imamalieva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. P. Zlomanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. B. Babanly
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. B. Babanly.

Additional information

Original Russian Text © Ya.I. Jafarov, S.Z. Imamalieva, V.P. Zlomanov, M.B. Babanly, 2014, published in Neorganicheskie Materialy, 2014, Vol. 50, No. 6, pp. 597–604.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Jafarov, Y.I., Imamalieva, S.Z., Zlomanov, V.P. et al. Phase equilibria in the reciprocal system 3Tl2S + Bi2Te3 ↔ 3Tl2Te + Bi2S3 . Inorg Mater 50, 551–558 (2014). https://doi.org/10.1134/S0020168514060065

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0020168514060065

Keywords

Search

Navigation