Abstract
We have studied amorphous silica samples prepared by a thermal method and precipitation from rice processing waste: straw and grain shells (husk and peelings). We have determined their true and bulk densities, silica content, and sorbed water vapor content. The porosity of the samples has been evaluated by different techniques: nitrogen desorption (Barrett-Joyner-Halenda method) and adsorption (BET analysis), water vapor adsorption, sorption of organic dyes (methylene blue and brilliant green), and positron annihilation spectroscopy. The effect of the nature of raw materials and processing procedure on the physicochemical properties of amorphous silica is examined.
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Govindarao Venneti, M.N., Utilization of rice huska preliminary analysis, J. Sci. Ind. Res., 1980, vol. 39, no. 9, p. 495.
Sergienko, V.I., Zemnukhova, L.A., Egorov, A.G., et al., Sustainable sources of chemical raw materials: Combined processing of rice and buckwheat production waste, Ross. Khim. Zh., 2004, vol. 48, no. 3, p. 116.
Zemnukhova, L.A., Babushkina, T.A., Ziatdinov, A.M., et al., Impurity paramagnetic Fe(III) and Mn(II) centers in samples of amorphous silica of different origin, Russ. J. Appl. Chem., 2012, vol. 85, no. 7, p. 1011.
Zemnukhova, L.A., Babushkina, T.A., Klimova, T.P., et al., Structural features of amorphous silica from plants, Appl. Magn. Reson., 2012, vol. 42, no. 4, p. 557.
Zemnukhova, L.A., Fedorishcheva, G.A., Shkorina, E.D., et al., Amorphous silicon dioxide from waste of ferroalloy production, Russ. J. Appl. Chem., 2011, vol. 84, no. 4, pp. 565.
Zemnukhova, L.A., Egorov, A.G., Fedorishcheva, G.A., et al., Properties of amorphous silica produced from rice and oat processing waste, Inorg. Mater., 2006, vol. 42, no. 1, p. 24.
Gregg, S.J. and Sing, K.S.W., Adsorption, Surface Area, and Porosity, New York: Academic, 1982.
Dubinin, M.M., Water vapor adsorption and microporous structures of carbon adsorbents, Izv. Akad. Nauk SSS, Ser. Khim., 1981, no. 1, p. 9.
Zakharchenko, V.N., Kolloidnaya khimiya (Colloid Chemistry), Moscow: Vysshaya Shkola, 1974.
Grafutin, V.I. and Prokop’ev, E.P., Application of positron annihilation spectroscopy in structural studies, Usp. Fiz. Nauk, 2002, vol. 172, no. 1, p. 67.
Belyaev, V.N., Kovalen’, V.Yu., Razov, V.I., et al., System for positron and positronium lifetime measurements in condensed media, Prib. Tekh. Eksp., 1980, no. 6, p. 47.
Infrakrasnye spektry neorganicheskikh stekol i kristallov (Inorganic Spectra of Inorganic Glasses and Crystals), Vlasov, A.G. and Florinskaya, V.A., Eds., Leningrad: Khimiya, 1972.
Ahmaruzzaman, M. and Gupta, V.K., Rice husk and its ash as low-cost adsorbents in water and wastewater treatment, Ind. Eng. Chem. Res., 2011, vol. 50, p. 13589.
Ovchinnikov, O.V., Chernykh, S.V., Smirnov, M.S., et al., Interaction of methylene blue with the surface of AgCl(I) microcrystals, Zh. Prikl. Spektrosk., 2007, vol. 74, no. 6, p. 731.
Mashkova, S.A., Razov, V.I., Tonkikh, I.V., et al., Preparation and adsorption properties of modified natural sorbents, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2005, vol. 48, no. 5, p. 112.
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Original Russian Text © L.A. Zemnukhova, A.E. Panasenko, E.A. Tsoi, G.A. Fedorishcheva, N.P. Shapkin, A.P. Artem’yanov, V.Yu. Maiorov, 2014, published in Neorganicheskie Materialy, 2014, Vol. 50, No. 1, pp. 82–89.
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Zemnukhova, L.A., Panasenko, A.E., Tsoi, E.A. et al. Composition and structure of amorphous silica produced from rice husk and straw. Inorg Mater 50, 75–81 (2014). https://doi.org/10.1134/S0020168514010208
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DOI: https://doi.org/10.1134/S0020168514010208