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Carbon phases resulting from Pt x Pd y (CO) z decomposition

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Abstract

It has been found that spontaneous decomposition of carbonyl clusters with the general formula Pt x Pd y (CO) z at t ≥ 120°C leads to the formation of platinum-palladium sponge containing carbon phases—graphite, diamond, fullerenes, and carbon nanotubes resulting from the decomposition of CO molecules via the Boudoir reaction. The diamond has the form of grains up to 1 mm in size and filamentary crystals up to 2 cm in length and up to 30 μm in diameter, whose photographs are presented in the paper.

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Authors and Affiliations

  1. Bauman State Technical University, Vtoraya Baumanskaya ul. 5, Moscow, 107005, Russia

    I. V. Fedoseev, N. S. Gerasimova & K. V. Maramygin

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  1. I. V. Fedoseev
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  2. N. S. Gerasimova
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  3. K. V. Maramygin
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Correspondence to I. V. Fedoseev.

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Original Russian Text © I.V. Fedoseev, N.S. Gerasimova, K.V. Maramygin, 2013, published in Neorganicheskie Materialy, 2013, Vol. 49, No. 12, pp. 1289–1293.

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Fedoseev, I.V., Gerasimova, N.S. & Maramygin, K.V. Carbon phases resulting from Pt x Pd y (CO) z decomposition. Inorg Mater 49, 1190–1193 (2013). https://doi.org/10.1134/S0020168513120054

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  • DOI: https://doi.org/10.1134/S0020168513120054

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