Skip to main content
SpringerLink
Log in

Synthesis and thermal expansion of some lanthanide-containing apatites

  • Published:
Inorganic Materials Aims and scope

Abstract

Compounds with the general formula CaLn4(SiO4)3O (Ln = Pr, Sm, Eu), belonging to the apatite class, have been prepared by solid-state reactions and have been studied at high temperatures by high-temperature X-ray diffraction and differential scanning calorimetry. The results demonstrate that the volume expansivity of these apatites and its temperature coefficient are determined by the ionic radius of the lanthanides.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Jothinathan, E., Vammeesel, K., Vleugels, J., et al., Apatite type lanthanum silicate and composite anode half cells, Solid State Ionics, 2011, vol. 192, pp. 419–423.

    Article  CAS  Google Scholar 

  2. Fukuda, K., Asaka, T., and Uchida, T., Thermal expansion of lanthanum silicate oxyapatite (La9.33 + 2x (SiO4)6O2 + 3x), lanthanum oxyorthosilicate (La2SiO5) and lanthanum sorosilicate (La2Si2O7), J. Solid State Chem., http://dx.doi.org/10.1016/j.jssc.2012.04.043

  3. Nakayama, S., Kageyama, T., Aono, H., and Sadaoka, Y., Ionic conductivity of lanthanoid silicates, Ln10(SiO4)6O3 (Ln = La, Nd, Sm, Gd, Dy, Y, Ho, Er and Yb), J. Mater. Chem., 1995, vol. 5, pp. 1801–1805.

    Article  CAS  Google Scholar 

  4. Nakayama, S. and Sakamoto, M., Electrical properties of new type high oxide ionic conductor RE10Si6O27 (RE = La, Pr, Nd, Sm, Gd, Dy), J. Eur. Ceram. Soc., 1998, vol. 18, pp. 1413–1418.

    Article  CAS  Google Scholar 

  5. Pasero, M., Kampf, A.R., Ferraris, C., et al., Nomenclature of the apatite supergroup minerals, Eur. J. Mineral., 2010, vol. 22, pp. 163–179.

    Article  CAS  Google Scholar 

  6. Skakle, J.M.S., Dickson, C.L., and Glasser, F.P., The crystal structures of CeSiO4 and Ca2Ce8(SiO4)6O2, Powder Diffraction, 2000, vol. 15, pp. 234–238.

    Article  CAS  Google Scholar 

  7. White, T.J. and Dong, Z.-L., Structural derivation and crystal chemistry of apatites, Acta Crystallogr., Sect. B: Struct. Sci., 2003, vol. 59, pp. 1–16.

    Article  CAS  Google Scholar 

  8. Chernorukov, N.G., Knyazev, A.V., and Bulanov, E.N., Isomorphism and phase diagram of the Pb5(PO4)3Cl-Pb5(VO4)3Cl system, Russ. J. Inorg. Chem., 2010, vol. 55, no. 9, pp. 1463–1470.

    Article  CAS  Google Scholar 

  9. Belousov, R.I. and Filatov, S.K., Algorithm for calculating the thermal expansion tensor and constructing the thermal expansion diagram for crystals, Glass Phys. Chem., 2007, vol. 33, no. 3, pp. 271–275.

    Article  CAS  Google Scholar 

  10. Filatov, S.K., Vysokotemperaturnaya kristallokhimiya. Teoriya, metody i rezul’taty issledovanii (High-Temperature Crystal Chemistry: Theory, Methods, and Results), Leningrad: Nedra, 1990.

    Google Scholar 

  11. Chernorukov, N.G., Knyazev, A.V., and Bulanov, E.N., Phase Transitions and Thermal Expansion of Apatite-Structured Compounds, Inorg. Mater., 2011, vol. 47, no. 2, pp. 172–177.

    Article  CAS  Google Scholar 

  12. Knyazev, A.V., Chernorukov, N.G., and Bulanov, E.N., Apatite-structured compounds: Synthesis and high-temperature investigation, Mater. Chem. Phys., 2012, vol. 132, pp. 773–781.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Lobachevski State University, pr. Gagarina 23, Nizhni Novgorod, 603950, Russia

    A. V. Knyazev, E. N. Bulanov, A. O. Korshunov & O. V. Krasheninnikova

Authors
  1. A. V. Knyazev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. N. Bulanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. O. Korshunov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. O. V. Krasheninnikova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. V. Knyazev.

Additional information

Original Russian Text © A.V. Knyazev, E.N. Bulanov, A.O. Korshunov, O.V. Krasheninnikova, 2013, published in Neorganicheskie Materialy, 2013, Vol. 49, No. 11, pp. 1222–1227.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Knyazev, A.V., Bulanov, E.N., Korshunov, A.O. et al. Synthesis and thermal expansion of some lanthanide-containing apatites. Inorg Mater 49, 1133–1137 (2013). https://doi.org/10.1134/S0020168513110095

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0020168513110095

Keywords

Search

Navigation