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Frequency-dependent electrical conductivity of nanocrystalline SnO2

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Abstract

Nanocrystalline SnO2 with a crystallite size of 3–4 and 5–6 nm has been prepared by a sol-gel process in aqueous solution. Its ac electrical conductivity has been measured in dry air at a temperature of 200°C. The observed frequency dependence of its conductivity has been interpreted in terms of the random potential barrier model. The data obtained indicate that the transport properties of the material are dominated by hopping conduction through disordered crystallite boundaries.

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References

  1. Madelung, O., Festkörpertheorie, Heidelberg: Springer, 1978.

    Google Scholar 

  2. Serin, N., Yildiz, A., Alsac, A.A., and Serin, T., Estimation of compensation ratio by identifying the presence of different hopping conduction mechanisms in SnO2 thin films, Thin Solid Films, 2011, vol. 519, pp. 2302–2307.

    Article  CAS  Google Scholar 

  3. Yong-Jun, M., Feng, Z., Li, L., and Zhang, Z., Low-temperature transport properties of individual SnO2 nanowires, Solid State Commun., 2004, vol. 130, pp. 313–316.

    Article  Google Scholar 

  4. Babar, A.R., Shinde, S.S., Moholkar, A.V., and Rajpure, K.Y., Electrical and dielectric properties of coprecipitated nanocrystalline tin oxide, J. Alloys Compd., 2010, vol. 505, pp. 743–749.

    Article  CAS  Google Scholar 

  5. Sahay, P.P., Pandey, S.N., Mishra, R.K., et al., AC transport properties of nanocrystalline SnO2 semiconductor, Ceram. Int., 2012, vol. 38, pp. 1281–1286.

    Article  CAS  Google Scholar 

  6. Chandra Bose, A., Balaya, P., Thangadurai, P., and Ramasamy, S., Grain size effect on the universality of ac conductivity in SnO2, J. Phys. Chem. Solids, 2003, vol. 64, pp. 659–663.

    Article  Google Scholar 

  7. Dyre, J.C. and Schrøder, T.B., Computer simulations of the random barrier model, Phys. Chem. Chem. Phys., 2002, vol. 4, pp. 3173–3178.

    Article  Google Scholar 

  8. Dyre, J.C. and Schrøder, T.B., AC hopping conduction at extreme disorder takes place on the percolating cluster, Phys. Rev. Lett., 2008, vol. 101, paper 025 901.

  9. Dyre, J.C., Maass, P., Rolling, B., and Sidebottom, L.D., Fundamental questions relating to ion conduction in disordered solids, Rep. Prog. Phys., 2009, vol. 72, paper 046 501.

  10. Vasiliev, R.B., Rumyantseva, M.N., Dorofeev, S.G., et al., Crystallite size effect on the conductivity of the ultradisperse ceramics of SnO2 and In2O3, Mendeleev Commun., 2004, pp. 167–169.

    Google Scholar 

  11. Liu, S.H., Fractal model for the ac response of a rough interface, Phys. Rev. B: Condens. Matter Mater. Phys., 1985, vol. 55, no. 5, pp. 529–532.

    CAS  Google Scholar 

  12. Staresinic, D., Biljakovic, K., Baklanov, N.I., and Zaitsev-Zotov, S.V., Low-frequency dielectric spectroscopy of low-energy excitations of the charge-density wave ground state, Ferroelectrics, 1996, vol. 176, p. 335.

    Article  CAS  Google Scholar 

  13. Reedijk, J.A., Adriaanse, L.J., Brom, H.B., et al., Crossover from phonon- to photon-mediated charge transport observed in metal-cluster compounds, Phys. Rev. B: Condens. Matter Mater. Phys., 1998, vol. 57, no. 24, pp. R15 116–R15 119.

    Article  CAS  Google Scholar 

  14. Kudryashov, M.A., Mashin, A.I., Logunov, A.A., et al. Frequency dependence of the electrical conductivity in Ag/PAN nanocomposites, Tech. Phys., 2012, vol. 57, no. 7, pp. 965–970.

    Article  CAS  Google Scholar 

  15. Vasil’ev, R.B., Dorofeev, S.G., Rumyantseva, M.N., et al., Impedance spectroscopy of ultrafine-grain SnO2 ceramics with a variable grain size, Semiconductors, 2006, vol. 40, no. 1, pp. 104–107.

    Article  Google Scholar 

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Correspondence to A. S. Chizhov.

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Original Russian Text © A.S. Chizhov, M.N. Rumyantseva, A.M. Gaskov, 2013, published in Neorganicheskie Materialy, 2013, Vol. 49, No. 10, pp. 1078–1082.

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Chizhov, A.S., Rumyantseva, M.N. & Gaskov, A.M. Frequency-dependent electrical conductivity of nanocrystalline SnO2 . Inorg Mater 49, 1000–1004 (2013). https://doi.org/10.1134/S0020168513100014

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  • DOI: https://doi.org/10.1134/S0020168513100014

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