Abstract
Carbon-ceramic composites have been prepared by mechanical ball-milling and ultrasonic treatment of mixtures of titania with carbon nanomaterials, and the optimal preparation conditions have been determined. The dependence of electrical conductivity of the composites on the mass fraction of carbon nanomaterials (1–5 mass. %) has been ascertained, and it has been found that a carbon nanotubes mass fraction of 3% gives rise to a sharp increase in the electrical conductivity up to 2.2 × 10−3 S/cm. It has been shown that the carbon-ceramic composites are promising electrocatalyst supports for electrochemical applications.
Similar content being viewed by others
References
Miracle, D.B. and Donaldson, S.L., ASM Handbook: Composites, 2001, vol. 21.
Karabasov, Yu.S., Novye materialy (New Materials), Moscow: MISIS, 2002.
Arsecularatne, J.A. and Zhang, L.C., Carbon nanotube reinforced ceramic composites and their performance, Recent Pat. Nanotechnol., 2007, vol. 1, no. 3, pp. 176–185.
Eder, D., Carbon nanotube—inorganic hybrids, Chem. Rev., 2010, vol. 110, pp. 1348–1385.
Blagoveshchenskii, Yu.V., Van, K.V., Volodin, A.A., et al., Preparation and structure of ceramic-matrix composites containing carbon nanotubes, Kompoz. Nanostrukt., 2010, no. 1, pp. 30–39.
Yuchi Fan and Lianjun Wang, Preparation and electrical properties of graphene nanosheet/Al2O3 composites, Carbon, 2010, vol. 48, pp. 1743–1749.
Bondar, A.M. and Iordache, I., Carbon/ceramic composites designed for electrical application, J. Opt. Adv. Mater., 2006, vol. 8, no. 2, pp. 631–637.
Su, F.-H., Zhang, Zh.-Zh., and Wang, K., Friction and wear properties of carbon fabric composites filled with nano-Al2O3 and nano-Si3N4, Composites, 2006, vol. 37, pp. 1351–1357.
Fényi, B., Hegman, N., and Wéber, F., DC conductivity of silicon nitride based carbon-ceramic composites, Proc. Appl. Ceram., 2007, vol. 1, nos. 1–2, pp. 57–61.
Zheng, G.-B., Sano, H., and Uchiyama, Y., A Carbon nanotube-enhanced SiC coating for the oxidation protection of C/C composite materials, Composites, 2011, vol. 42, pp. 2158–2162.
Guo, S.Q., Sivakumar, R., Kitazawa, H., and Kagawa, Y., Electrical properties of silica-based nanocomposites with multiwall carbon nanotubes, J. Am. Ceram. Soc., 2007, vol. 90, no. 5, pp. 1667–70.
Yu, J., Fan, J., and Cheng, B., Dye-sensitized solar cells based on anatase TiO2 hollow spheres/carbon nanotubes composite films, J. Power Sources, 2011, vol. 196, pp. 7891–7898.
Ivanshina, O.Yu., Tamm, M.E., Gerasimova, E.V., et al., Synthesis and electrocatalytic activity of platinum nanoparticle/carbon nanotube composites, Inorg. Mater., 2011, vol. 47, no. 6, pp. 618–625.
Martínez, C., Canle, M., and Fernández, M.I., Kinetics and mechanism of aqueous degradation of carbamazepine by heterogeneous photocatalysis using nanocrystalline TiO2, ZnO and multi-walled carbon nanotubes-anatase composites, Appl. Catal., B, 2011, vol. 102, pp. 563–571.
Li, X.L., Li, C., and Zhang, Y., Atomic layer deposition of ZnO on multi-walled carbon nanotubes and its use for synthesis of CNT-ZnO heterostructures, Nanoscale Res. Lett., 2010, vol. 5, pp. 1836–1840.
Jiang, L.Q. and Gao, L., Carbon nanotubes-metal nitride composites: A new class of nanocomposites with enhanced electrical properties, J. Mater. Chem., 2005, vol. 15, no. 2, pp. 260–266.
Shi, S.L. and Liang, J., Electronic transport properties of multiwall carbon nanotubes/yttria-stabilized zirconia composites, J. Appl. Phys., 2007, vol. 101, no. 2, paper 023 708.
Wu, Zh.-Sh., Zhou, G., and Yina, Li-Ch., Graphene/metal oxide composite electrode materials for energy storage, Nano Energy, 2012, no. 1, pp. 107–131.
Tarasov, B.P., Muradyan, V.E., and Volodin, A.A., Synthesis, properties, and some applications of carbon nanomaterials, Izv. Akad. Nauk, Ser. Khim., 2011, no. 7, pp. 1237–1249.
Volodin, A.A., Chikhirev, D.V., Zolotarenko, A.D., et al., Fabrication and properties of composites of metal oxides and carbon nanotubes, in Nanostruktury v kondensirovannykh sredakh (Nanostructures in Condensed Media), Minsk: BGU, 2011, pp. 286–291.
Volodin, A.A., Fursikov, P.V., Kasumov, Yu.A., et al., Synthesis of carbon nanofibers through catalytic pyrolysis of ethylene and methane on lanthanum nickel hydrides, Izv. Akad. Nauk, Ser. Khim., 2005, no. 10, pp. 2210–2214.
Volodin, A.A., Fursikov, P.V., Kasumov, Yu.A., et al., Synthesis of carbon nanostructures on Fe-Mo catalysts supported on modified SiO2, Izv. Akad. Nauk, Ser. Khim., 2006, no. 8, pp. 1372–1376.
Volodin, A.A., Gerasimova, E.V., and Tarasov, B.P., Synthesis of carbon nanofibers through catalytic ethylene pyrolysis in the presence of vapors of volatile components, Izv. Akad. Nauk, Ser. Khim., 2011, no. 3, pp. 398–403.
Streletskii, A.N., Leonov, A.V., and Butyagin, P.Yu., Amorphization of silicon during mechanical treatment of its powders: 1. Process kinetics, Colloid J., 2001, vol. 63, no. 5, pp. 630–634.
Butyagin, P.Yu. and Streletskii, A.N., The kinetics and energy balance of mechanochemical transformations, Phys. Solid State, 2005, vol. 47, no. 5, pp. 856–863.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.A. Volodin, A.A. Belmesov, V.B. Murzin, P.V. Fursikov, A.D. Zolotarenko, B.P. Tarasov, 2013, published in Neorganicheskie Materialy, 2013, Vol. 49, No. 7, pp. 702–708.
The article was translated by the authors.
Rights and permissions
About this article
Cite this article
Volodin, A.A., Belmesov, A.A., Murzin, V.B. et al. Electro-conductive composites based on titania and carbon nanotubes. Inorg Mater 49, 656–662 (2013). https://doi.org/10.1134/S0020168513060174
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0020168513060174