Abstract
This paper reports a comparative study of the homogeneity of LiNbO3〈Mg〉 (≥5 mol % Mg) crystals grown from a charge synthesized using Nb2O5〈Mg〉 prepared through homogeneous magnesium doping of a reextract in the Nb2O5 extraction step, and LiNbO3〈Mg〉 crystals prepared through direct doping of a growth charge. The LiNbO3〈Mg〉 crystals were characterized by optical microscopy and Raman spectroscopy. The results demonstrate that the LiNbO3〈Mg〉 crystals prepared using homogeneous doping are more structurally uniform.
Similar content being viewed by others
References
Sidorov, N.V., Volk, T.R., Mavrin, B.N., et al., Niobat litiya: defekty, fotorefraktsiya, kolebatel’nyi spektr, polyaritony (Lithium Niobate: Defects, Photorefractive Properties, Vibrational Spectrum, and Polaritons), Moscow: Nauka, 2003.
Rosenman, G., Skliar, A., and Arie, A., Ferroelectric domain engineering for quasi-phase-matched nonlinear optical devices, Ferroelectr. Rev., 1999, vol. 1, pp. 263–326.
Qi-Ren Zhang and Xi-Qi Feng, Defect structures and the MgO-doping-level-threshold affect on the optical absorption of reduced MgO-doped lithium niobate, Phys. Rev. B: Condens. Matter Mater. Phys., 1991, vol. 43, no. 14, pp. 12 019–12 024.
Furukawa, Y., Sato, M., Nitanda, F., and Ito, K., Growth and characterization of MgO-doped LiNbO3 for electro-optic devices, J. Cryst. Growth, 1990, vol. 99, pp. 832–836.
Choubey, R.K., Sen, P., Sen, P.K., et al., Optical properties of MgO doped LiNbO3 single crystals, Opt. Mater., 2006, vol. 28, pp. 467–472.
Hu, L.J., Chang, Y.H., Yen, F.S., et al., Crystal growth and characterization of heavily MgO doped LiNbO3, J. Appl. Phys., 1991, vol. 69, p. 7635.
Chen, Y.I., Guo, J., Lou, C.B., et al., Crystal growth and characteristics of 6.5 mol. % MgO-doped LiNbO3, J. Cryst. Growth, 2004, vol. 263, pp. 427–430.
Palatnikov, M.N., Sidorov, N.V., and Kalinnikov, V.T., Controlled synthesis of single-crystal and ceramic materials based on alkali metal niobate tantalates, Tsvetn. Met., 2000, no. 10, pp. 54–60.
Palatnikov, M.N., Sidorov, N.V., and Kalinnikov, V.T., Segnetoelektricheskie tverdye rastvory na osnove oksidnykh soedinenii niobiya i tantala (Ferroelectric Solid Solutions Based on Niobium and Tantalum Oxide Compounds), St. Petersburg: Nauka, 2001.
Voron’ko, Yu.K., Kudryavtsev, A.B., Osiko, V.V., et al., Phase transformations of lithium niobate and lithium tantalate studied by Raman spectroscopy, Fiz. Tverd. Tela (Leningrad), 1987, vol. 29, no. 5, pp. 1348–1355.
Voron’ko, Yu.K., Kudryavtsev, A.B., Sobol’, A.A., and Sorokin, E.V., High-temperature Raman spectroscopy as an effective probe of phase transformations in laser crystals, Tr. Inst. Obshch. Fiz., Ross. Akad. Nauk, 1991, vol. 29, pp. 50–100.
Voron’ko, Yu.K., Kudryavtsev, A.B., Osiko, V.V., Sobol’, A.A., and Sorokin, E.V., Raman spectroscopy study of Li2O-Nb2O5 Melts, Kratk. Soobshch. Fiz., 1987, no. 2, pp. 34–36.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © M.N. Palatnikov, I.V. Biryukova, S.M. Masloboeva, O.V. Makarova, O.E. Kravchenko, A.A. Yanichev, N.V. Sidorov, 2013, published in Neorganicheskie Materialy, 2013, Vol. 49, No. 7, pp. 765–770.
Rights and permissions
About this article
Cite this article
Palatnikov, M.N., Biryukova, I.V., Masloboeva, S.M. et al. Structure and optical homogeneity of LiNbO3〈Mg〉 crystals grown from different charges. Inorg Mater 49, 715–720 (2013). https://doi.org/10.1134/S0020168513060083
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0020168513060083