Abstract
We have studied the optical absorption edge of TlIn1 − x Ga x Se2 (x = 1.0, 0.9, 0.7, 0.6, 0.5) solid solutions, identified the types of the observed optical transitions, and evaluated the band gap of the solid solutions and the energy of phonons involved in the transitions.
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Hahn, H. and Wellman, B., Uber ternare Chalkokogenide des Thalliums mit Gallium und Indium, Naturwissenschaften, 1967, vol. 54, no. 2, pp. 42–48.
Guseynov, G.D., Abdullayev, G.B., and Gojayev, E.M., Constitutional Diagram and Physical Properties of TlSe-InSe Pseudobinary System, Mater. Res. Bull., 1972, vol. 7, pp. 1497–1504.
Guseinov, G.D., Seidov, F.M., Khalilov, Kh.S., and Ismailov, M.Z., TlSe-GaSe Pseudobinary System, Zh. Fiz. Khim., 1972, vol. 16, no. 3, pp. 803–804.
Guseinov, G.D. and Abdullaev, G.B., Piezoresistive Effect in TlInSe2 Single Crystals, Dokl. Akad. Nauk SSSR, 1973, vol. 203, no. 5, pp. 1052–1054.
Karpovich, I.A., Chervova, A.A., Leonov, E.N., and Orlov, V.M., Electrical and Photoelectric Properties of TlInSe2 Single Crystals and Films, Izv. Vyssh. Uchebn. Zaved., Fiz., 1972, no. 5, pp. 157–161.
Gojaev, E.M., Orudzhev, G.S., Mamedov, E.M., et al., Transport Properties of TlIn1−x GaxSe2 (0 ⩽ x ⩽ 0.3) Crystals, Inorg. Mater., 2007, vol. 43, no. 10, pp. 1054–1058.
Urbulak, G., Yildirim, M., Ates, A., et al., The Absorption Properties of p-TypeTlInxGa1−xSe2 and TlGaSe2, Turk. J. Phys, 2000, vol. 49, pp. 49–61.
Ukhanov, Yu.I., Opticheskie svoistva poluprovodnikov (Optical Properties of Semiconductors), Moscow: Nauka, 1977.
Kurik, M.V., Urbach Rule, Phys. Status Solidi A, 1971, vol. 8, no. 1, pp. 9–45.
Mahan, G.D., Phonon Broadened Optical Spectra: Urbach Rule, Phys. Rev., 1966, vol. 145, no. 2, pp. 602–608.
Dunn, D., Exciton-Phonon Interaction in Polar Media, Can. J. Phys., 1975, vol. 53, no. 4, pp. 321–336.
Burtsev, E.V., Polarization Fluctuations and Optical Absorption Edge in Ferroelectrics, in Poluprovodnikisegnetoelnktriki (Ferroelectric Semiconductors), Rostov-on-Don, 1973, pp. 48–59.
Borovoi, N.A., Gololobov, Yu.P., Isaenko, G.L., and Stepanishchev, N.B., Influence of Polytypism on Structural Phase Transformations in TlGaSe2 Crystals, Fiz. Tverd. Tela, 2009, vol. 51, no. 11, pp. 2367–2370.
Orudzev, G., Shim, Y., Wakita, K., et al., Linearized Augmented Plane Wave Band Structure Calculations and Dielectric Function of Layered TlGaSe2, Jpn. J. Appl. Phys., 2008, vol. 47, no. 10, pp. 8182–8187.
Orudzev, G., Mamedov, N., Uchiki, H., et al., Band Structure and Optical Functions of Ternary Chain TlInSe2, J. Phys. Chem. Solids, 2003, vol. 64, pp. 1703–1706.
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Original Russian Text © E.M. Gojaev, Sh.M. Efendiev, Kh.S. Khalilova, E.A. Allakhyarov, 2013, published in Neorganicheskie Materialy, 2013, Vol. 49, No. 3, pp. 230–235.
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Gojaev, E.M., Efendiev, S.M., Khalilova, K.S. et al. Optical absorption edge of TlIn1 − x Ga x Se2 solid solutions. Inorg Mater 49, 230–234 (2013). https://doi.org/10.1134/S002016851302009X
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DOI: https://doi.org/10.1134/S002016851302009X