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Synthesis and IR spectroscopic characterization of fluorinated graphite intercalation compounds with chlorinated derivatives of methane and ethane

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Abstract

We have synthesized (C2F x Br0.01 · yG) n intercalation compounds with (C2F x Br0.01) n as a host and G (dichloromethane, chloroform, carbon tetrachloride, and dichloroethane) as a guest (x and y are stoichiometric coefficients). The behavior of the functional groups in the guest and host subsystems has been studied by IR spectroscopy. We have examined the influence of the degree of fluorination of the polymer host (0.5 < x < 1.0) and the nature of the guest on the vibrational frequencies of the C-F and C-Cl bonds.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    D. V. Pinakov, N. I. Alferova & G. N. Chekhova

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  1. D. V. Pinakov
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  2. N. I. Alferova
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  3. G. N. Chekhova
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Correspondence to D. V. Pinakov.

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Original Russian Text © D.V. Pinakov, N.I. Alferova, G.N. Chekhova, 2012, published in Neorganicheskie Materialy, 2012, Vol. 48, No. 11, pp. 1286–1290.

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Pinakov, D.V., Alferova, N.I. & Chekhova, G.N. Synthesis and IR spectroscopic characterization of fluorinated graphite intercalation compounds with chlorinated derivatives of methane and ethane. Inorg Mater 48, 1153–1157 (2012). https://doi.org/10.1134/S002016851211009X

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  • DOI: https://doi.org/10.1134/S002016851211009X

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