Skip to main content
SpringerLink
Log in

Preparation and properties of electrets based on iodine-intercalated InSe and GaSe

  • Published:
Inorganic Materials Aims and scope

Abstract

We have studied the properties of iodine-intercalated GaSe and InSe layered crystals and showed that the intercalated materials can be used to prepare electrets. Thermally stimulated discharge spectra of electrochemically intercalated GaSe and InSe have been measured. The spectra and a model with a single relaxation frequency of dipoles have been used to determine their activation energy. The composition dependence of the electret voltage has been explained. The photoresponse of GaSeI x and InSeI x electrets has been measured using a monochromatic beam propagating along their crystallographic axis C.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Kovalyuk, Z.D., Pyrlya, M.N., Seredyuk, A.I., and Tovstyuk, K.D., Intercalation Complexes of III–VI Layered Compounds, Izv. Akad. Nauk SSSR, Neorg. Mater., 1985, vol. 29, no. 10, pp. 1652–1655.

    Google Scholar 

  2. Dragomeretskii, V.V., Kovalyuk, Z.D., Pyrlya, M.N., et al., Electronic Spectrum and Dynamics of Impurity States in Barium-Intercalated InSe, Dokl. Akad. Nauk Ukr. SSR, 1987, no. 9, pp. 77–80.

  3. Kovalyuk, Z.D., Prokipchuk, T.P., Seredyuk, A.I., and Tovstyuk, K.D., NMR Study of Impurity States in Hydrogen-Intercalated Gallium Selenide, Fiz. Tverd. Tela (Leningrad), 1987, vol. 29, no. 7, pp. 2191–2193.

    CAS  Google Scholar 

  4. Kaminskii, V.M., Kovalyuk, Z.D., Netyaga, V.V., et al., Dielectric and Electrical Properties of Hydrogen Containing Nanopowders of GaSe and InSe, Phys. Chem. Solid State, 2010, vol. 11, no. 2, pp. 367–372.

    CAS  Google Scholar 

  5. Kovalyuk, Z.D. and Mintyanskii, I.V., Electrical Properties of InSe Intercalated with Anthracene Molecules, Ukr. Fiz. Zh. (Russ. Ed.), 1982, vol. 27, no. 4, pp. 616–617.

    CAS  Google Scholar 

  6. Ichimura, Sh., Tatsuyama, Ch., and Ueno, O., Electrical and Optical Properties of Intercalated GaSe Compound, Phys. B (Amsterdam, Neth.), 1981, vol. 105, pp. 238–242.

    Article  CAS  Google Scholar 

  7. Bakhmatyuk, B.P. and Netyaga, V.V., Electrochemical Intercalation of Indium and Gallium Monoselenides with Halogens, in Materialovedenie uzkoshchelevykh i sloistykh poluprovodnikov (Narrow-Gap and Layered Semiconductor Materials Research), Kiev: Nauchnaya Mysl’, 1989, pp. 61–65.

    Google Scholar 

  8. Kovalyuk, Z.D., Boledzyuk, V.B., and Pyrlya, M.M., Optical, Electrical, and Electrochemical Properties of Indium Monoselenide Intercalated with Iodine, Ukr. J. Phys., 2009, vol. 54, no. 6, pp. 582–586.

    Google Scholar 

  9. Kovalyuk, Z.D., Duplavyy, V.Y., Pyrlja, M.M., et al., Studies of InSe and GaSe Layered Crystals Intercalated in Iodine Vapor, Ukr. J. Phys., 2010, vol. 55, no. 11, pp. 1210–1216.

    CAS  Google Scholar 

  10. Mintyanskii, I.V., Grigorchak, I.I., Kovalyuk, Z.D., and Gavrilyuk, S.V., Electret Effect in GaSe Layered Crystals, Fiz. Tverd. Tela (Leningrad), 1986, vol. 28, no. 4, pp. 1263–1265.

    CAS  Google Scholar 

  11. Electrets, Sessler, G.M., Ed., Heidelberg: Springer, 1980.

    Google Scholar 

  12. Kovalyuk, Z.D., Seredyuk, A.I., and Tovstyuk, K.D., Photoelectric Properties of Intercalated InSe, Ukr. Fiz. Zh. (Russ. Ed.), 1984, vol. 29, no. 7, pp. 1096–1097.

    CAS  Google Scholar 

  13. Tovstyuk, K.D., Poluprovodnikovoe materialovedenie (Semiconductor Materials Research), Kiev: Naukova Dumka, 1984.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Frantsevich Institute of Materials Science Problems (Chernivtsi Branch), National Academy of Sciences of Ukraine, ul. Vilde 5, Chernivtsi, 58001, Ukraine

    Z. D. Kovalyuk & V. Y. Duplavyy

Authors
  1. Z. D. Kovalyuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. Y. Duplavyy
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Z. D. Kovalyuk.

Additional information

Original Russian Text © Z.D. Kovalyuk, V.Y. Duplavyy, 2012, published in Neorganicheskie Materialy, 2012, Vol. 48, No. 8 pp. 887–891.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kovalyuk, Z.D., Duplavyy, V.Y. Preparation and properties of electrets based on iodine-intercalated InSe and GaSe. Inorg Mater 48, 776–780 (2012). https://doi.org/10.1134/S0020168512080092

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0020168512080092

Keywords

Search

Navigation