Abstract
The heat capacity of a strontium tetraborate (SrB4O7) single crystal has been determined in the temperature range 55–300 K by adiabatic calorimetry, and its Debye characteristic temperature, entropy change, enthalpy increment, and phonon mean free path have been calculated as functions of temperature.
Similar content being viewed by others
References
Oseledchik, S.Yu., Prosvirnin, A.L., Pisarevskiy, A.I., et al., New Nonlinear Optical Crystals: Strontium and Lead Tetraborate, Opt. Mater., 1995, vol. 4, no. 3, pp. 669–674.
Petrov, V., Noack, F., Shen, D., et al., Application of the Nonlinear Crystal SrB4O7 for Ultrafast Diagnostics Converting to Wavelengths As Short As 125 nm, Opt. Lett., 2004, vol. 29, no. 4, pp. 373–375.
Zaitsev, A.I., Aleksandrovskii, A.S., Zamkov, A.V., and Sysoev, A.M., Nonlinear Optical, Piezoelectric, and Acoustic Properties of SrB4O7, Inorg. Mater., 2006, vol. 42, no. 12, pp. 1360–1362.
Zaitsev, A.I., Aleksandrovsky, A.S., Vasiliev, A.D., and Zamkov, A.V., Domain Structure in Strontium Tetraborate Single Crystal, J. Cryst. Growth, 2008, vol. 310, no. 1, pp. 1–4.
Aleksandrovsky, A.S., Vyunyshev, A.M., Shakhura, I.E., et al., Random Quasi-Phase-Matching in Nonlinear Photonic Crystal Structure of Strontium Tetraborate, Phys. Rev. A, 2008, vol. 78, paper 031 802.
Aleksandrovsky, A.S., Vyunyshev, A.M., Slabko, V.V., et al., Tunable Femtosecond Frequency Doubling in Random Domain Structure of Strontium Tetraborate, Opt. Commun., 2009, vol. 282, no. 11, pp. 2263–2266.
Aleksandrovsky, A.S., Vyunishev, A.M., Zaitsev, A.I., et al., Nonlinear Photonic Crystals of Strontium Tetraborate: Properties and Conversion of Radiation, Proc. SPIE-Int. Soc. Opt. Eng., 2010, vol. 7728, paper 772 819.
Pei, Z., Zeng, Q., and Su, Q., The Application and a Substitution Defect Model for Eu3+-Eu2+ Reduction in a Non-Reducing Atmospheres in Borates Containing BO4 Anion Groups, J. Phys. Chem. Solids, 2000, vol. 61, pp. 9–12.
Mikhail, P., Hulliger, J., and Ramseyer, K., Cathodoluminescence and Photoluminescence of Smn+ (n = 2, 3) in Oxide Environments, Solid State Commun., 1999, vol. 112, pp. 483–488.
Blasse, G., Dirksen, G.J., and Meijerink, A., The Luminescence of Ytterbium (II) in Strontium Tetraborate, Chem. Phys. Lett., 1990, vol. 167, no. 1, pp. 41–44.
Schipper, W.J., Meijerink, A., and Blasse, G., The Luminescence of Tm2+ in Strontium Tetraborate, J. Lumin., 1994, vol. 62, pp. 55–59.
Xu, W. and Peterson, J.R., Stabilization of Divalent Neodymium (Nd2+) in Strontium Tetraborate, J. Alloys Compd., 1997, vol. 249, nos. 1–2, pp. 213–216.
Machida, K., Adachi, G., and Shiokawa, J., Luminescence Properties of Eu(II)-Borates and Eu2+ Activated Sr-Borates, J. Lumin., 1979, vol. 21, pp. 101–110.
Lacam, A. and Chateau, C., High-Pressure Measurements at Moderate Temperatures in a Diamond Anvil Cell with a New Optical Sensor: SrB4O7:Sm2+, J. Appl. Phys., 1989, vol. 66, no. 1, pp. 366–372.
Lavat, A., Graselli, C., Santiago, M., et al., Influence of the Preparation Route on the Optical Properties of Dosimetric Phosphors Based on Rare-Earth Doped Polycrystalline Strontium Borates, Cryst. Res. Technol., 2004, vol. 39, no. 10, pp. 840–848.
Martynyuk-Lototska, I., Dudok, T., Mys, O., and Vlokh, R., Elastic, Piezooptic and Acoustooptic Properties of SrB4O7 and PbB4O7 Crystals, Opt. Mater., 2009, vol. 31, no. 4, pp. 660–667.
Dolzhenkova, E.F., Baumer, V.N., Tolmachev, A.V., and Oseledchik, Yu.S., On the Nature of Fracture of SrB4O7 and PbB4O7 Crystals, Crystallogr. Rep., 2007, vol. 52, no. 5, pp. 889–893.
Popov, P.A., Solomennik, V.D., Zaitsev, A.I., et al., Thermal Conductivity and Thermal Expansion of Crystalline Strontium Tetraborate, SrB4O7, Dokl. Phys., 2012, vol. 57, no. 2 (in press).
Zaitsev, A.I., Zamkov, A.V., Koroleva, N.S., et al., Phase Formation upon Crystallization of SrO2B2O3 Glasses, Crystallogr. Rep., 2011, vol. 56, no. 1, pp. 44–51.
Berman, R., Thermal Conduction in Solids, Oxford: Clarendon, 1976.
Sirota, N.N., Antyukhov, A.M., Novikov, V.V., and Fedorov, V.A., Heat Capacity of (InP)x(InAs)1 − x Solid Solutions from 5 to 160 K, Dokl. Akad. Nauk SSSR, 1981, vol. 259, no. 2, pp. 362–365.
Debye, P., Zur Theorie der spezifischen Wärmen, Ann. Phys., 1912, vol. 39, pp. 789–839.
Grechin, S.G., Zuev, A.V., Kokh, A.E., et al., Thermophysical Parameters of the LBO Crystal, Kvantovaya Elektron. (Moscow), 2010, vol. 40, no. 6, pp. 509–512.
Popov, P.A., Moiseev, N.V., Kokh, A.E., and Kokh, K.A., Thermal Conductivity and Heat Capacity of α- and β-BaB2O4 Single Crystals, Inorg. Mater., 2011, vol. 47, no. 2, pp. 163–166.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © N.V. Moiseev, P.A. Popov, V.D. Solomennik, A.I. Zaitsev, A.V. Cherepakhin, 2012, published in Neorganicheskie Materialy, 2012, Vol. 48, No. 5, pp. 588–591.
Rights and permissions
About this article
Cite this article
Moiseev, N.V., Popov, P.A., Solomennik, V.D. et al. Heat capacity and thermodynamic properties of crystalline SrB4O7 . Inorg Mater 48, 504–507 (2012). https://doi.org/10.1134/S0020168512050123
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0020168512050123