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Effect of surface modification with carbon-containing groups on the size, properties, and morphology of silica particles

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Abstract

We report the properties of hydrated silica surface-modified with aminopropyl, 3-(2-imidazolin-1-yl)propyl, or 1H,1H,2H,2H-perfluorodecyl. The modifier groups reside on the surface of the silica nanoparticles, as shown by NMR spectroscopy. We examine the effect of the nature and concentration of the modifier on the particle size and specific surface area of silica. Thermal analysis results demonstrate that the modified materials are stable up to 430°C.

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References

  1. Clearfield, A., Role of Ion Exchange in Solid-State Chemistry, Chem. Rev., 1988, vol. 88, no. 1, pp. 125–148.

    Article  CAS  Google Scholar 

  2. Yaroslavtsev, A.B., Ion Exchange on Inorganic Sorbents, Usp. Khim., 1997, vol. 66, no. 7, pp. 641–660.

    CAS  Google Scholar 

  3. Alberti, G. and Casciola, M., Composite Membranes for Medium Temperature PEM Fuel Cells, Ann. Rev. Mater. Res., 2003, vol. 33, pp. 129–154.

    Article  CAS  Google Scholar 

  4. Yaroslavtsev, A.B., Nikonenko, V.V., and Zabolotskii, V.I., Ion Transport in Membrane and Ion Exchange Materials, Usp. Khim., 2003, vol. 72, no. 5, pp. 438–470.

    Google Scholar 

  5. Voropaeva, E.Yu., Stenina, I.A., and Yaroslavtsev, A.B., Transport Properties of Hydrous-Silica-Modified MF-4SK Membranes, Russ. J. Inorg. Chem., 2008, vol. 53, no. 10, pp. 1531–1535.

    Article  Google Scholar 

  6. Voropaeva, E.Yu., Stenina, I.A., and Yaroslavtsev, A.B., Ion Transport in MF-4SK Membranes Modified with Hydrous Zirconia, Russ. J. Inorg. Chem., 2008, vol. 53, no. 11, pp. 1677–1680.

    Article  Google Scholar 

  7. Tai, Y., Qian, J., Zhang, Y., and Huang, J., Study of Surface Modification of Nano-SiO2 with Macromolecular Coupling Agent (LMPB-g-MAH), Chem. Eng. J., 2008, vol. 141, nos. 1–3, pp. 354–361.

    Article  CAS  Google Scholar 

  8. Yu, Y., Rong, M., and Zhang, M., Grafting of Hyperbranched Aromatic Polyamide onto Silica Nanoparticles, Polymer, 2010, vol. 51, no. 2, pp. 492–499.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    E. Yu. Safronova, A. B. Il’in, A. A. Lysova & A. B. Yaroslavtsev

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  1. E. Yu. Safronova
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  2. A. B. Il’in
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  3. A. A. Lysova
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  4. A. B. Yaroslavtsev
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Correspondence to A. B. Yaroslavtsev.

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Original Russian Text © E.Yu. Safronova, A.B. Il’in, A.A. Lysova, A.B. Yaroslavtsev, 2012, published in Neorganicheskie Materialy, 2012, Vol. 48, No. 4, pp. 437–442.

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Safronova, E.Y., Il’in, A.B., Lysova, A.A. et al. Effect of surface modification with carbon-containing groups on the size, properties, and morphology of silica particles. Inorg Mater 48, 368–373 (2012). https://doi.org/10.1134/S0020168512040115

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  • DOI: https://doi.org/10.1134/S0020168512040115

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