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X-ray photoelectron spectra of magnetite nanopowders after chromium(VI) sorption from aqueous solutions

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Abstract

Fe3O4 nanopowders prepared by three different procedures (vapor-phase synthesis, chemical precipitation from aqueous solutions, and laser evaporation) have been characterized by X-ray photoelectron spectroscopy before and after chromium(VI) sorption from aqueous solutions. The results demonstrate that, during sorption, the chromium is concentrated in the magnetite at a level of several atomic percent, and its oxidation state is 3+. The mechanism of chromium sorption on magnetite particles is discussed.

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References

  1. Topkin, Yu.V., Roda, I.G., Anfinogenov, N.V., and Prishchep, N.N., Removal of Heavy Metal Ions from Solutions by a Ferrite Method, Khim. Tekhnol. Vody, 1990, vol. 12, no. 12, pp. 895–897.

    CAS  Google Scholar 

  2. Lesnikovich, A.I., Vorob’eva, S.A., and Karpenko, N.V., Cr(VI) Adsorption from Aqueous Solutions by Cobalt, Manganese, and Iron Ferrites, Zh. Prikl. Khim. (S.-Peterburg), 1994, vol. 67, no. 3, pp. 500–502.

    CAS  Google Scholar 

  3. Banerjee, S.S., Joshi, M.V., and Jayaram, R.V., Removal of Cr(VI) and Hg(II) from Aqueous Solutions Using Fly Ash and Impregnated Fly Ash, Sep. Sci. Technol., 2004, vol. 39, no. 7, pp. 1611–1629.

    Article  CAS  Google Scholar 

  4. Zhao, J., Guan, X., and Unuma, H., Preparation of Fe3O4 Nanoparticles and Their Application to Composite Biosorbent, J. Ceram. Soc. Jpn., 2007, vol. 115, no. 8, pp. 475–478.

    Article  CAS  Google Scholar 

  5. Sheha, R.R. and Ei-Zahhar, A.A., Synthesis of Some Ferromagnetic Composite Resins and Their Metal Removal Characteristics in Aqueous Solutions, J. Hazard. Mater., 2008, vol. 150, nos. 2–3, pp. 795–803.

    Article  CAS  Google Scholar 

  6. Yuan, P., Montmorillonite-Supported Magnetite Nanoparticles for the Removal of Hexavalent Chromium [Cr(VI)] from Aqueous Solutions, J. Hazard. Mater, 2009, vol. 166, nos. 2–3, pp. 821–829.

    Article  CAS  Google Scholar 

  7. Linnikov, O.D., Rodina, I.V., Ermakov, A.E., et al., Sorption of Hexavalent Chromium Ions from Aqueous Solutions by Magnetite, III Vserossiiskaya konferentsiya po nanomaterialam “NANO-2009” (III All-Russia Conf. on Nanomaterials, NANO-2009), Yekaterinburg, 2009, pp. 571–572.

  8. Linnikov, O.D., Rodina, I.V., Shevchenko, V.G., et al., Sorption of Hexavalent Chromium from Aqueous Solutions by Magnetite Nanoparticles, in Fizikokhimicheskie aspekty izucheniya klasterov, nanostruktur i nanomaterialov (Physicochemical Aspects of Clusters, Nanostructures, and Nanomaterials), Tver: Tversk. Gos. Univ., 2009, issue 1, pp. 74–79.

    Google Scholar 

  9. Linnikov, O.D., Rodina, I.V., Shevchenko, V.G., et al., Sorption of Hexavalent Chromium from Aqueous Solutions by Nanoparticulate Magnetite, Voda: Khim. Ekol., 2011, no. 5, pp. 68–75.

  10. Kortov, V.S. et al., Specific Features of Luminescence Properties of Nanostructured Aluminum Oxide, Phys. Solid State, 2008, vol. 50, pp. 957–961.

    Article  CAS  Google Scholar 

  11. Vainshtein, I.A., Ochistka i ispol’zovanie stochnykh vod travil’nykh otdelenii (Purification and Recycling of Wastewater Solutions from Pickling Plants), Moscow: Metallurgiya, 1986.

    Google Scholar 

  12. Kotov, Yu.A., Characteristics of Oxide Nanopowders Produced by Evaporating a Target with Repetitive CO2 Laser Pulses, Zh. Tekh. Fiz., 2002, vol. 72, no. 1, pp. 76–82.

    Google Scholar 

  13. Welsh, I.D. and Sherwood, M.A., Photoemission and Electronic Structure of FeOOH: Distinguishing between Oxide and Oxyhydroxide, Phys. Rev. B: Condens. Matter Mater. Phys., 1989, vol. 40, no. 9, p. 6386.

    Article  CAS  Google Scholar 

  14. Fujii, T., de Groot, F.M.F., Sawatzky, G.A., et al., In Situ XPS Analysis of Various Iron Oxide Films Grown by NO2-Assisted Molecular-Beam Epitaxy, Phys. Rev. B: Condens. Matter Mater. Phys., 1999, vol. 59, no. 4, p. 3195.

  15. Practical Surface Analysis by Auger and X-ray Photoelectron Spectroscopy, Briggs, D. and Seah, M., Eds., New York: Wiley, 1983.

    Google Scholar 

  16. Galakhov, V.R., Application of 3s X-Ray Photoelectron Spectra for Determination of Charge States and Magnetic Moments of 3d Ions in Oxides, Solid State Phenom., 2011, vols. 168–169, p. 453.

    Google Scholar 

  17. Handbook of X-ray Photoelectron Spectroscopy, Mullenberg, G.E., Ed., Minnesota: Perkin-Elmer.

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Correspondence to M. V. Kuznetsov.

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Original Russian Text © M.V. Kuznetsov, O.D. Linnikov, I.V. Rodina, 2012, published in Neorganicheskie Materialy, 2012, Vol. 48, No. 2, pp. 213–219.

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Kuznetsov, M.V., Linnikov, O.D. & Rodina, I.V. X-ray photoelectron spectra of magnetite nanopowders after chromium(VI) sorption from aqueous solutions. Inorg Mater 48, 169–175 (2012). https://doi.org/10.1134/S0020168512020148

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  • DOI: https://doi.org/10.1134/S0020168512020148

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