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Phase separation of Mn2Sb at high pressures and temperatures

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Abstract

The intermetallic compound Mn2Sb (tetragonal structure, Cu2Sb type) was exposed to high pressures (4 to 8 GPa) and temperatures (up to 2300 K) for 10 min and was shown to phase-separate to Mn3Sb and Mn1.5Sb at certain processing temperatures, pressures, and durations.

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References

  1. Ryzhkovskii, V.M., Nekrashevich, E.M., Dymont, V.P., and Starchenko, I.M., High-Pressure Crystal Structure of Mn2Sb and Mn2(Fe)Sb Compounds, Cryst. Res. Technol., 1996, vol. 31, no. 8, pp. A96–A99.

    Article  Google Scholar 

  2. Goncharov, V.S. and Ryzhkovskii, V.M., Effect of High-Pressure High-Temperature Processing on the Structure and Magnetic Properties of Manganese Antimonide, Pis’ma Zh. Tekh. Fiz., 2001, vol. 27, no. 13, pp. 39–43.

    Google Scholar 

  3. Goncharov, V.S. and Ryzhkovskii, V.M., High-Pressure Synthesis and Crystal Structure of the New Compound Mn3Sb, Inorg. Mater., 2005, vol. 41, no. 6, pp. 557–559.

    Article  CAS  Google Scholar 

  4. Yamashita, T., Takizawa, H., Sasaki, T., et al. Mn3Sb: A New L12-Type Intermetallic Compound Synthesized under High-Pressure, J. Alloys Compd., 2003, vol. 348, nos. 1–2, pp. 220–223.

    Article  CAS  Google Scholar 

  5. Ryzhkovskii, V.M. and Goncharov, V.S., Effect of High-Pressure High-Temperature Processing on the Phase Composition and Magnetic State of Mn1 + x Sb (1 ≤ x ≤ 1.0) Alloys, Inorg. Mater., 2010, vol. 46, no. 3, pp. 226–231.

    Article  CAS  Google Scholar 

  6. Rodriguez-Cravajal, J., Recent Advances in Magnetic Structure Determination by Neutron Powder Diffraction, Phys. B: Condens. Matter, 1993, vol. 192, nos. 1–2, pp. 55–69.

    Article  Google Scholar 

  7. Chernyshev, V.V., Powder Diffraction Analysis of Crystal Structures, Izv. Akad. Nauk, Ser. Khim., 2001, no. 12, pp. 2171–2190.

  8. Aksenov, V.L., Balagurov, A.M., Glazkov, V.P., et al., DN-12 Time-Of-Flight High-Pressure Neutron Spectrometer for Investigation of Microsamples, Phys. B: Condens. Matter, 1999, vol. 265, nos. 1–4, pp. 258–262.

    Article  CAS  Google Scholar 

  9. Rietveld, H.M., A Profile Refinement Method for Nuclear and Magnetic Structures, J. Appl. Crystallogr., 1969, vol. 2, no. 2, pp. 65–71.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Scientific-Practical Materials Research Centre, Belarussian Academy of Sciences, ul. Brovki 19, Minsk, 220072, Belarus

    V. S. Goncharov & V. M. Ryzhkovskii

Authors
  1. V. S. Goncharov
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  2. V. M. Ryzhkovskii
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Correspondence to V. S. Goncharov.

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Original Russian Text © V.S. Goncharov, V.M. Ryzhkovskii, 2011, published in Neorganicheskie Materialy, 2011, Vol. 47, No. 12, pp. 1425–1428.

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Goncharov, V.S., Ryzhkovskii, V.M. Phase separation of Mn2Sb at high pressures and temperatures. Inorg Mater 47, 1298–1301 (2011). https://doi.org/10.1134/S0020168511120065

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  • DOI: https://doi.org/10.1134/S0020168511120065

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