Skip to main content
Log in

Planar multilayer membranes on metallic supports

  • Published:
Inorganic Materials Aims and scope

Abstract

We have tested a number of approaches to producing oxygen-selective planar multilayer membranes with mixed conductivity of functional layers on metallic gauze as a key component of a porous support. The results demonstrate that the shrinkage mismatch can be considerably reduced via pressure sintering. The conditions for firing metallic gauzes and applying ceramic coatings have been established. We describe the optimal structure and processes for applying ceramic layers with the aim of producing planar multilayer membranes of catalytic membrane reactors for methane conversion. Mechanochemical ceramic processing was successfully used to produce ceramic nanopowders and modifying paste.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Handbook of Solid State Electrochemistry, vol. 1: Fundamentals, Materials and Their Applications, Kharton, V.V., Ed., Weinheim: Wiley-VCH, 2009.

    Google Scholar 

  2. Zyryanov, V.V., Uvarov, N.F., Sadykov, V.A., et al., Mechanosynthesis of Complex Oxides and Preparation of Mixed Conducting Nanocomposites for Catalytic Membrane Reactors, Catal. Today, 2005, vol. 104, pp. 114–119.

    Article  CAS  Google Scholar 

  3. Zyryanov, V.V., Sadykov, V.A., and Alikina, G.M., Design of Multilayer Ceramic MIEC Membranes, Separat. Sci. Technol., 2007, vol. 42, no. 13, pp. 2849–2861.

    Article  CAS  Google Scholar 

  4. Zyryanov, V.V. and Sadykov, V.A., Design of Multilayered Ceramic MIEC Membranes, Desalination, 2006, vol. 199, nos. 1–3, pp. 299–301.

    Article  CAS  Google Scholar 

  5. Zyryanov, V.V., Multilayered Selective Ceramic Membranes, Konstr. Kompoz. Mater., 2007, no. 1, pp. 32–49.

  6. Zyryanov, V.V. and Karakchiev, L.G., Porous Supports for Conducting Ceramic Membranes, Inorg. Mater., 2008, vol. 44, no. 4, pp. 429–437.

    Article  CAS  Google Scholar 

  7. Zyryanov, V.V. and Mel’gunov, M.S., High-Shrinkage-Potential Porous Glass-Ceramic Supports for High-Temperature Oxide Ceramic Membranes, Inorg. Mater., 2008, vol. 44, no. 10, pp. 1130–1134.

    Article  CAS  Google Scholar 

  8. Zyryanov, V.V., RF Patent 2349373, Byull. Izobret., 2009, no. 8.

  9. Zyryanov, V.V., Nemudry, A.P., and Sadykov, V.A., Nanostructured Perovskites for the Fabrication of Thin Ceramic Membranes and Related Phenomena, Membranes for Membrane Reactors: Preparation, Optimization and Selection, Basile, A. and Gallucci, F., Eds., New York: Wiley, 2011, pp. 201–226.

    Chapter  Google Scholar 

  10. Zyryanov, V.V., Fabrication of Multilayer Ceramic Membranes, Asia-Pac. J. Chem. Eng, 2009, vol. 4, pp. 285–290.

    Article  CAS  Google Scholar 

  11. Safronov, A.P., Kalinina, E.G., Kotov, Yu.A., et al., Electrophoretic Deposition of Nanopowders on Porous Surfaces, Ross. Nanotekhnol., 2006, vol. 1, nos. 1–2, pp. 162–169.

    Google Scholar 

  12. Zyryanov, V.V., Sadykov, V.A., Uvarov, N.F., et al., Mechanosynthesis of Complex Oxides with Fluorite and Perovskite-Related Structures and Their Sintering into Nanocomposites with Mixed Ionic-Electronic Conductivity, Solid State Ionics, 2005, vol. 176, pp. 2813–2818.

    Article  CAS  Google Scholar 

  13. Usol’tsev, V.V., Sadykov, V.A., Sobyanin, V.A., et al., Engineering of Medium-Temperature Solid Oxide Fuel Cells on Porous Work-Hardened Ni-Al Supports, Vserossiiskaya konferentsiya s mezhdunarodnym uchastiem “TOTE i energoustanovki na ikh osnove” (All-Russia/Int. Conf. SOFCs and Related Power Plants), Chernogolovka, 2010, pp. 42–43.

  14. Zyryanov, V.V., Mechanochemical Synthesis of Mixed Oxides, Usp. Khim., 2008, vol. 77, no. 2, pp. 107–137.

    Google Scholar 

  15. Zyryanov, V.V., Ultrafast Mechanochemical Synthesis of Mixed Oxides, Inorg. Mater., 2005, vol. 41, no. 4, pp. 378–392.

    Article  CAS  Google Scholar 

  16. Zyryanov, V.V., Zyryanov, D.V., and Sadykov, V.A., Coating Production by Charged Aerosol Deposition, Ross. Nanotekhnol., 2008, vol. 3, nos. 5–6, pp. 118–126.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. V. Zyryanov.

Additional information

Original Russian Text © V.V. Zyryanov, A.A. Matvienko, 2011, published in Neorganicheskie Materialy, 2011, Vol. 47, No. 10, pp. 1264–1270.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zyryanov, V.V., Matvienko, A.A. Planar multilayer membranes on metallic supports. Inorg Mater 47, 1153–1159 (2011). https://doi.org/10.1134/S0020168511100256

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0020168511100256

Keywords

Navigation