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Composition range and thermodynamic properties of Tl5Se2Br-based solid solutions

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Abstract

The equilibrium subsolidus phase diagram of the TlBr-Tl2Se-TlSe system has been mapped out using X-ray diffraction analysis and emf measurements on thallium concentration cells. Tl5Se2Br has been shown to have a broad homogeneity region. The emf results are used to evaluate the relative partial thermodynamic functions of the thallium in the alloys studied and the standard integral thermodynamic functions (ΔG 0(298 K), ΔH 0(298 K), S 0(298 K)) of the Tl5Se2Br-based solid solutions.

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Authors and Affiliations

  1. Institute of Chemical Problems, Academy of Sciences of Azerbaijan, pr. Javida 29, Baku, AZ1143, Azerbaijan

    D. M. Babanly

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  1. D. M. Babanly
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Correspondence to D. M. Babanly.

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Original Russian Text © D.M. Babanly, 2011, published in Neorganicheskie Materialy, 2011, Vol. 47, No. 6, pp. 658–661.

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Babanly, D.M. Composition range and thermodynamic properties of Tl5Se2Br-based solid solutions. Inorg Mater 47, 583–587 (2011). https://doi.org/10.1134/S002016851106001X

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