Abstract
Alumina- and titania-based composite coatings containing ferromagnetic nanoparticles have been produced on UKN-5000P carbon fibers by an in situ organo-inorganic hybrid sol-gel process using appropriate aqueous metal chloride solutions containing Fe(III) and Co(II). The morphology, phase composition, and elemental composition of the coatings have been studied by high-resolution electron microscopy, X-ray diffraction, and energy-dispersive X-ray microanalysis. The results demonstrate that the oxide coatings containing ferromagnetic nanoparticles are uniform in thickness along and across the fibers and adhere well to the fiber surface. The coatings range in thickness from 100 to 500 nm. In all of the systems studied, the coatings produced on carbon fibers differ in phase composition from powders prepared from identical hydrosols.
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Giannakopoulou, T. et al., Microwave Behavior of Ferrites Prepared via Sol-Gel Method, J. Magn. Magn. Mater., 2002, vol. 246, no. 3, pp. 360–365.
Yusoffa, A.N. et al., Microwave Electromagnetic and Absorption Properties of Some LiZn Ferrites, J. Magn. Magn. Mater., 2004, vol. 269, no. 2, pp. 271–280.
Lee, W.Y., Lara-Curzio, E., et al., Multilayered Oxide Interphase Concept for Ceramic-Matrix Composites, J. Am. Ceram. Soc., 1998, vol. 81, no. 3, pp. 717–720.
Kerans, R.J., Hay, R.S., et al., Interface Design for Oxidation-Resistant Ceramic Composites, J. Am. Ceram. Soc., 2002, vol. 85, no. 11, pp. 2599–2632.
Baklanova, N.I., Zima, T.M., et al., Protective Ceramic Multilayer Coating for Carbon Fibers, Surf. Coat. Technol., 2006, vol. 201, pp. 2313–2319.
Baklanova, N.I. and Zima, T.M., Barrier Coatings on Carbon and Silicon Carbide Fibers for Ceramic-Matrix Composites, Khim. Interesakh Ustoich. Razvit., 2006, vol. 14, no. 3, pp. 243–246.
Yang, Y., Zhang, B.S., et al., Preparation and Properties of a Novel Iron-Coated Carbon Fiber, J. Magn. Magn. Mater., 2003, vol. 256, nos. 1–3, pp. 129–132.
Yang, Y., Zhang, B.S., et al., Preparation and Electromagnetic Characteristics of a Novel Iron-Coated Carbon Fiber, J. Alloys Compd., 2004, vol. 365, pp. 300–302.
Xu, J., Yang, H., Fu, W., et al., Preparation and Characterization of Carbon Fibers Coated by Fe3O4 Nano-particles, Mater. Sci. Eng., B, 2006, vol. 132, pp. 307–310.
Shen, G., Xu, M., and Xu, Z., Double-Layer Micro-wave Absorber Based on Ferrite and Short Carbon Fiber Composites, Mater. Chem. Phys., 2007, vol. 105, p. 268.
Karakchiev, L.G., Zima, T.M., and Lyakhov, N.Z., Heat Treatment of Alumina-Titania Gels, Neorg. Mater., 2000, vol. 36, no. 7, pp. 852–857 [Inorg. Mater. (Engl. Transl.), vol. 36, no. 7, pp. 709–713].
Reidy, D.J. et al., The critical Size Mechanism for the Anatase to Rutile Transformation in TiO2 and Doped-TiO2, J. Eur. Ceram. Soc., 2006, vol. 26, no. 9, pp. 1527–1534.
Zenkovets, G.A., Gavrilov, V.A., Shutilov, A.A., and Tsybulya, S.V., Effect of Silica Additions on the Phase Composition and Pore Structure of Anatase, Kinet. Katal., 2009, vol. 50, no. 5, pp. 790–797.
Emily, A.A. et al., Exploiting Covalency to Enhance Metal-Oxide and Oxide-Oxide Adhesion at Heterogeneous Interfaces, J. Eur. Ceram. Soc., 2003, vol. 86, no. 3, pp. 373–386.
Zima, T.M., Baklanova, N.I., and Titov, A.T., The Behavior of the Oxide-Coated Nicalon™ Fibers Exposed to Air at 1000°C, J. Eur. Ceram. Soc., 2005, vol. 25, no. 11, pp. 1943–1952.
Zima, T.M., Baklanova, N.I., and Lyakhov, N.Z., Composites of Mesoporous Al2O3 and Fe- or Co-Containing Nanoparticles, Neorg. Mater., 2010, vol. 46, no. 8, pp. 949–954 [Inorg. Mater. (Engl. Transl.), vol. 46, no. 8, pp. 852–857].
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Original Russian Text © T.M. Zima, N.I. Baklanova, A.T. Titov, 2011, published in Neorganicheskie Materialy, 2011, vol. 47, no. 4, pp. 439–444.
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Zima, T.M., Baklanova, N.I. & Titov, A.T. Ferromagnetic composite coatings on carbon fibers. Inorg Mater 47, 385–389 (2011). https://doi.org/10.1134/S0020168511040236
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DOI: https://doi.org/10.1134/S0020168511040236