Abstract
The composition and molecular structure of preceramic nanozirconooligocarbosilanes have been determined using a variety of physicochemical characterization techniques: nuclear magnetic resonance (1H, 29Si, 13C), IR spectroscopy, transmission electron microscopy, gel-permeation chromatography, scanning electron microscopy, thermogravimetry, X-ray photoelectron spectroscopy, and elemental analysis.
Similar content being viewed by others
References
Storozhenko, P.A., Shcherbakova, G.I., Tsirlin, A.M., et al., Synthesis of Nanozirconooligocarbosilanes, Neorg. Mater., 2006, vol. 42, no. 10, pp. 1269–1277 [Inorg. Mater. (Engl. Transl.), vol. 42, no. 10, pp. 1159–1167].
Tsirlin, A.M., Shcherbakova, G.I., Florina, E.K., et al., RF Patent 2258715, Byull. Izobret., 2005, no. 23.
Yajima, S., Hasegawa, Y., Hayashi, J., and Hmura, M., Synthesis of Continuous Silicon Carbide Fibre with High Tensile Strength and High Young’s Modulus: Part 1. Synthesis of Polycarbosilane As Precursor, J. Mater. Sci., 1978, vol. 13, pp. 2569–2576.
Tsirlin, A.M., Fedorova, T.V., Florina, E.K., et al., RF Patent 2108348, Byull. Izobret., 1998, no. 10.
Storozhenko, P.A., Shcherbakova, G.I., Muzafarov, A.M., et al., Preceramic Carbosilanes: Physicochemical Properties and Molecular Structure, Nanotekhnika, 2009, no. 4 (20), pp. 7–13.
Bürger, H. and Neese, H.-J., Titan-Stickstoff-Verbindungen VIII* Thermolyse von Tris(dialkylamino)titanalkylen, J. Organomet. Chem., 1970, vol. 21, pp. 381–388.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © G.I. Shcherbakova, P.A. Storozhenko, D.V. Sidorov, M.Kh. Blokhina, M.G. Kuznetsova, M.V. Polyakova, A.E. Chernyshev, G.Yu. Yurkov, 2011, published in Neorganicheskie Materialy, 2011, Vol. 47, No. 5, pp. 605–613.
Rights and permissions
About this article
Cite this article
Shcherbakova, G.I., Storozhenko, P.A., Sidorov, D.V. et al. Molecular structure of preceramic nanozirconooligocarbosilanes. Inorg Mater 47, 535–543 (2011). https://doi.org/10.1134/S0020168511040182
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0020168511040182