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Synthesis and properties of structural analogs of the mineral bournonite

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Abstract

Rare-earth analogs of the mineral bournonite, PbCuSbS3, have been synthesized for the first time and their physicochemical properties have been studied. PbCuSbS3, EuCuSbS3, YbCuSbS3, PbCuLaS3, and PbCuNdS3 are isostructural with each other and crystallize in orthorhombic symmetry with the following unit-cell parameters: a = 8.176, b = 8.660, c = 7.796 Å (PbCuSbS3); a = 8.156, b = 8.68, c = 7.786 Å (EuCuSbS3); a = 8.15, b = 8.64, c = 7.76 Å (YbCuSbS3); a = 8.26, b = 8.84, c = 7.96 Å (PbCuLaS3); a = 8.20, b = 8.80, c = 7.92 Å (PbCuNdS3) (Z = 4, sp. gr. Pmn21).

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Authors and Affiliations

  1. Institute of Chemical Problems, Academy of Sciences of Azerbaijan, pr. Javida 29, Baku, AZ1143, Azerbaijan

    S. T. Bairamova, M. R. Bagieva, S. M. Agapashaeva & O. M. Aliev

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  1. S. T. Bairamova
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  2. M. R. Bagieva
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  3. S. M. Agapashaeva
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  4. O. M. Aliev
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Correspondence to S. T. Bairamova.

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Original Russian Text © S.T. Bairamova, M.R. Bagieva, S.M. Agapashaeva, O.M. Aliev, 2011, published in Neorganicheskie Materialy, 2011, Vol. 47, No. 4, pp. 399–402.

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Bairamova, S.T., Bagieva, M.R., Agapashaeva, S.M. et al. Synthesis and properties of structural analogs of the mineral bournonite. Inorg Mater 47, 345–348 (2011). https://doi.org/10.1134/S0020168511040054

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  • DOI: https://doi.org/10.1134/S0020168511040054

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