Abstract
The behavior of polydisperse second-phase inclusions in molten selenium during settling is modeled using solid carbon particles as an example. A theoretical limit of the particle concentration in the surface layer of the melt is evaluated as a function of particle size, and the particle concentration is determined as a function of time, melt viscosity, and surface layer thickness. The calculated histograms of the particle size distribution in the surface and bottom layers of molten selenium are in satisfactory agreement with experimental data.
Similar content being viewed by others
References
Devyatykh, G.G. and Churbanov, M.F., Vysokochistye khal’kogeny (High-Purity Chalcogens), Nizhni Novgorod: NNGU, 1997.
Shiryaev, V.S., Skripachev, I.V., Suchkov, A.I., and Churbanov, M.F., Heterophase Impurity Inclusions in Extrapure Selenium, Vysokochist. Veshchestva, 1995, no. 4, pp. 41–45.
Churbanov, M.F. and Shiryaev, V.S., Behavior of Submicron Carbon Impurity Particles during Vacuum Distillation of Selenium, Vysokochist. Veshchestva, 1996, no. 2, pp. 5–13.
Devyatykh, G.G., Churbanov, M.F., Shiryaev, V.S., et al., Impurity Inclusions in Extra-Pure Arsenic and Chalcogens Neorg. Mater., 1998, vol. 34, no. 9, pp. 1081–1085 [Inorg. Mater. (Engl. Transl.), vol. 34, no. 9, pp. 902–906]].
Shchukin, E.D., Pertsov, A.V., and Amelina, E.A., Kolloidnaya khimiya (Colloid Chemistry), Moscow: Vysshaya Shkola, 2007.
Johnson, C.P., Li, X., and Logan, B.E., Settling Velocities of Fractal Aggregates, Environ. Sci. Technol., 1996, vol. 30, p. 1911.
Ketkova, L.A., Kurilin, A.V., and Churbanov, M.F., Characterization of Heterophase Inclusions in Glasses Opaque in the Visible Range, Neorg. Mater., 2008, vol. 44, no. 7, pp. 878–882 [Inorg. Mater. (Engl. Transl.), vol. 44, no. 7, pp. 773–777].
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © Yu.P. Kirillov, G.A. Voronin, V.S. Shiryaev, L.A. Ketkova, A.V. Kurilin, M.F. Churbanov, 2011, published in Neorganicheskie Materialy, 2011, Vol. 47, No. 4, pp. 506–512.
Rights and permissions
About this article
Cite this article
Kirillov, Y.P., Voronin, G.A., Shiryaev, V.S. et al. Sedimentation kinetics of polydisperse second-phase inclusions in molten selenium. Inorg Mater 47, 449–454 (2011). https://doi.org/10.1134/S0020168511030149
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0020168511030149