Abstract
The transport and optical properties of (3HgSe)1 − x (Al2Se3) x 〈Mn〉 crystals have been studied, and their energy-band parameters have been determined. The transport measurements were made by a four probe method in the ranges T = 77–300 K and H = 40–400 kA/m; transmission was measured at 300 K. The Hall coefficient of the crystals is temperature-independent, their electrical conductivity shows metallic behavior and is a nearly linear function of temperature, and their thermoelectric power increases with temperature. Optical data attest to direct allowed interband optical transitions and suggest that the electrons in the crystals are scattered predominantly by ionized impurities. The energy-band parameters are determined and are used to construct the energy-band diagram of the crystals.
Similar content being viewed by others
References
Lyapilin, I.I., Ponomarev, A.I., Kharus, G.I., et al., Magnetoresistance Oscillations in Dilute HgMnSe Solid Solutions, Zh. Eksp. Teor. Fiz., 1983, vol. 85, no. 5 (11), pp. 1638–1646.
Gavaleshko, N.P., Lyapilin, I.I., Maryanchuk, P.D., et al., Effect of Exchange Interaction on the g-Factor of Conduction Electrons in HgMnSe, Fiz. Tekh. Poluprovodn. (Leningrad), 1984, vol. 18, no. 6, pp. 990–993.
Brandt, N.B., Ismailov, Zh.T., Kul’bachinskii, V.A., et al., Magnetic Phase Diagram of Hg1−x MnxS, Fiz. Nizk. Temp. (Kiev), 1986, vol. 12, no. 2, pp. 215–217.
Ismailov, Zh.T., Kul’bachinskii, V.A., Chudinov, S.M., et al., Electron Transfer to an Impurity Level in Hg1 − x MnxSe, Fiz. Tekh. Poluprovodn. (Leningrad), 1988, vol. 22, no. 3, pp. 375–380.
Maryanchuk, P., Maistruk, E., Andrushchak, G., et al., Semimagnetic Semiconductors on the Base of Mercury Chalcogenide, 16th Int. Conf. on Solid Compounds of Transition Elements, Dresden, 2008, p. 64.
Maryanchuk, P.D. and Kozyarskii, D.P., Physical Properties and Energy Band Parameters of Manganese-Doped (3HgSe)1 − x (Al2Se3)x Crystals, Sens. Elektron. Mikrosist. Tekhnol., 2007, no. 4, pp. 59–65.
Gavaleshko, N.P., Maryanchuk, P.D., and Antoshchuk, V.G., Reflection Spectra of MnxHg1 − x Se Single Crystals, Izv. Vyssh. Uchebn. Zaved., Fiz., 1992, vol. 35, no. 10, pp. 127–128.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © P.D. Maryanchuk, D.P. Kozyarskii, 2010, published in Neorganicheskie Materialy, 2010, Vol. 46, No. 5, pp. 528–531.
Rights and permissions
About this article
Cite this article
Maryanchuk, P.D., Kozyarskii, D.P. Electrical and optical properties of manganese-doped (3HgSe)1 − x (Al2Se3) x crystals. Inorg Mater 46, 460–463 (2010). https://doi.org/10.1134/S0020168510050043
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0020168510050043