Abstract
Mn(VO3) powders was successfully synthesized by an effective and simple route-rheological phase reaction method and investigated as a cathode material for lithium-ion batteries. The structures, morphologies, phase purity of the prepared powder were characterized by X-ray diffraction, transmission electron microscope and X-ray photo-electron spectrometry, respectively. The results showed that the different heat temperatures could influence the particle size and crystallinity of the product. The charge-discharge experiments were performed to investigate the electrochemical properties of Mn(VO3)2 powder at a constant current density of 1.0 mA/cm2 in a potential range of 0.0 and 3.5 V. The discharge capacity (441.1 mAh/g) showed only 31.7% losses of the initial discharge capacity (645.9 mAh/g) after 40 cycles.
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References
Croguennec, L., Deniard, P., and Brec, R., Electrochemical Cyclability of Orthorhombic LiMnO2, J. Electrochem. Soc., 1997, vol. 144, no. 10, pp. 3323–3330.
Chung, S.Y., Bliking, J.T., and Chiang, Y.M., Electronically Conductive Phospho-Olivines as Lithium Storage Electrodes, J. Nature, 2002, no. 1, pp. 123–128.
Yi, S.B., Chung, H.T., and Kim, H.G., A Novel Preparation Method of Active Materials for the Lithium Secondary Battery, J. Electrochem. Commun., 2007, vol. 9, no. 4, pp. 591–595.
Liu, H.W., Cheng, C.X., Hu, Z.Q., and Zhang, K.L., The Effect of ZnO Coating on LiMn2O4 Cycle Life in High Temperature for Lithium Secondary Batteries, J. Mater. Chem. Phys., 2007, vol. 101, nos. 2, 3, pp. 276–279.
Wang, G.J., Zhang, H.P., Fu, L.J., et al., Aqueous Rechargeable Lithium Battery (ARLB) Based on LiV3O8 and LiMn2O4 with Good Cycling Performance, J. Electrochem. Commun., 2007, vol. 9, no. 28, pp. 1873–1876.
Cho, T.H. and Chung, H.T., Synthesis of Olivine-Type LiFePO4 by Emulsion-Drying Method, J. Power Sources, 2004, vol. 133, no. 2, pp. 272–276.
Morishita, T., Nomura, K., Inamasu, T., and Inagaki, M., Synthesis of Anhydrous Manganese Vanadate Powder by Coprecipitation and Its Anodic Performance for Lithium Secondary Battery, J. Solid State Ionics, 2005, vol. 176, nos. 29–30, pp. 2235–2241.
Piffard, Y., Leroux, F., Guyomard, D., et al., The Amorphous Oxides MnV2O6 + δ (0 < δ < 1) as High Capacity Negative Electrode Materials for Lithium Batteries, J. Power Sources, 1997, vol. 68, no. 2, pp. 698–703.
Kim, S.S., Ikuta, H., Wakihara, M., Synthesis and Characterization of MnV2O6 as a High Capacity Anode Material for a Lithium Secondary Battery, J. Solid State Ionics, 2001, vol. 139, nos. 1, 2, pp. 57–65.
Leyzerovich, N.N., Bramnik, K.G., Buhrmester, T., et al. Electrochemical Intercalation of Lithium in Ternary Metal Molybdates MMoO4 (M: Cu, Zn, Ni and Fe), J. Power Sources, 2004, vol. 127, nos. 1, 2, pp. 76–84.
Liu, Y., Zhang Y.G., Du, J., et al., Synthesis and Characterization of Single-Crystal MnV2O6 Nanobelts, J. Cryst. Growth, 2006, vol. 29, no. 2, pp. 320–324.
Foord, J.S., Jackman, R.B., and Allen, G.C., An X-Ray Photoelectron Spectroscopic Investigation of the Oxidation of Manganese, J. Philos. Mag., 1984, vol. 49, no. 5, pp. 657–663.
Guyomard, D., Sigala, C., Le Gal La Salle, A., and Pifard, Y., New Amorphous Oxides as High Capacity Negative Electrodes for Lithium Batteries: the LixMVO4 (M = Ni, Co, Cd, Zn; 1 < x ≤ 8) Series, J. Power Sources, 1997, vol. 68, no. 2, pp. 692–697.
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Tan, L., Liu, H. Novel synthesis and electrochemical properties of Mn(VO3)2 as a high capacity electrode material in lithium-ions batteries. Inorg Mater 46, 201–205 (2010). https://doi.org/10.1134/S0020168510020202
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DOI: https://doi.org/10.1134/S0020168510020202