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Ionic mobility and electrical transport in 45ZrF4 · 35BiF3 · 20MF (M - Li, Na, K) glasses studied by NMR and impedance spectroscopy

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Abstract

The ionic mobility and electrical transport in 45ZrF4 · 35BiF3 · 20MF (M - Li, Na, K) glasses have been studied by 7Li, 19F, and 23Na NMR and impedance spectroscopy at temperatures from 200 to 500 K. In the range 400–440 K, the main kinds of ionic mobility in these glasses are local motions of fluorine-containing groups and lithium ion diffusion. The temperature range where the dominant kind of ion motion in the glasses is fluoride ion diffusion depends on the nature of the M+ cation. Above 470 K, the glasses offer rather high ionic conductivity: σ ≥ 10−5 S/cm.

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References

  1. Kahnt, H., Ionic Transport in Glasses, J. Non-Cryst. Solids, 1996, vol. 203, pp. 225–231.

    Article  CAS  Google Scholar 

  2. Trnovcova, V., Zakalyukin, R.M., Sorokin, N.I., et al., Physical Properties of Fluoride Glasses for Ionics, Mater. Sci. Forum, 2005, vols. 480–481, pp. 299–304.

    Article  Google Scholar 

  3. Kavun, V.Ya. and Sergienko, V.I., Diffuzionnaya podvizhnost’ i ionnyi transport v kristallicheskikh i amorfnykh ftoridakh elementov IV gruppy i sur’my(III) (Diffusion and Ionic Transport in Crystalline and Amorphous Group IV and Antimony(III) Fluorides), Vladivostok: Dal’nauka, 2004.

    Google Scholar 

  4. Sorokin, N.I., Anion-Conducting Fluoride and Oxyfluoride Glasses, Usp. Khim., 2001, vol. 70, no. 9, pp. 901–908.

    Google Scholar 

  5. Fedorov, P.P., Glass Formation Criteria for Fluoride Systems, Neorg. Mater., 1997, vol. 33, no. 12, pp. 1415–1424 [Inorg. Mater. (Engl. Transl.), vol. 33, no. 12, pp. 1197–1205].

    Google Scholar 

  6. Stamboulis, A., Hill, R.G., and Law, R.V., Structural Characterization of Fluorine Containing Glasses by 19F, 27Al, 29Si, and 31P MAS-NMR Spectroscopy, J. Non-Cryst. Solids, 2005, vol. 351, nos. 40–42, pp. 3289–3295.

    Article  CAS  Google Scholar 

  7. Merkulov, E.B., Goncharuk, V.K., Logoveev, N.A., et al., New Lead-Fluorozirconate Glasses Containing BiF3, J. Non-Cryst. Solids, 2005, vol. 351, pp. 3607–3609.

    Article  CAS  Google Scholar 

  8. Kavun, V.Ya., Merkulov, E.B., Logoveev, N.A., et al., Ionic Mobility in ZrF4-BiF3-MF (M = Li, Na, K) Glasses Studied by 7Li, 19F, and 23Na NMR, Zh. Neorg. Khim., 2008, vol. 53, no. 3, pp. 467–473.

    CAS  Google Scholar 

  9. Merkulov, E.B., Loginov, N.A., Goncharuk, V.K., and Yaroshenko, R.M., Glass Formation in the ZrF4-BiF3-MF (M = Li, Na, K) Fluoride Systems, Fiz. Khim. Stekla, 2007, vol. 33, no. 2, pp. 149–153.

    Google Scholar 

  10. Kavun, V.Ya., Slobodyuk, A.B., Tararako, E.A., et al., Synthesis, Ion Mobility, and Superionic Conductivity of (1 − x)PbF2 · xMFn (M = Li, Na, K, Rb, Cs, Zr) Solid Solutions, Neorg. Mater., 2005, vol. 41, no. 11, pp. 1388–1396 [Inorg. Mater (Engl. Transl.), vol. 41, no. 11, pp. 1228–1235].

    Google Scholar 

  11. Lundin, A.G. and Fedin, E.I., YaMR-Spektroskopiya (NMR Spectroscopy), Moscow: Nauka, 1986.

    Google Scholar 

  12. Kavun, V.Ya., Slobodyuk, A.B., Tararako, E.A., et al., Ion Mobility and Transport in β-PbF2 Doped with Alkaline-Earth Fluorides, Neorg. Mater., 2007, vol. 43, no. 3, pp. 352–361 [Inorg. Mater. (Engl. Transl.), vol. 43, no. 3, pp. 301–309].

    Article  CAS  Google Scholar 

  13. Haeberlen, U. and Mehring, M., YaMR vysokogo razresheniya v tverdykh telakh (High Resolution NMR in Solids), Moscow: Mir, 1980.

    Google Scholar 

  14. Kawamoto, Y., Fujiwara, J., and Ichimura, C., Ionic Conduction inxMF · (95 − x)ZrF4 · 5LaF3 (M: Alkali Metals) Glasses, J. Non-Cryst. Solids, 1989, vol. 111, nos. 2–3, pp. 245–251.

    Article  CAS  Google Scholar 

  15. Reau, J.M., Senegas, J., Rojo, J.M., et al., Transport Properties of ZrF4-BaF2-LaF3-AF (A = Li, Na) Glasses, J. Non-Cryst. Solids, 1990, vol. 116, nos. 2–3, pp. 175–178.

    Article  CAS  Google Scholar 

  16. Bobe, J.M., Reau, J.M., Senegas, J., and Poulain, M., F− Ion Conductivity and Diffusion Properties in ZrF4-Based Fluoride Glasses with Various NaF Concentrations (0 ≤ x NaF ≤ 0.45), Solid State Ionics, 1995, vol. 82, no. 1, pp. 39–52.

    Article  CAS  Google Scholar 

  17. Sural, M. and Ghosh, A., Ionic Conductivity and Relaxation in ZrF4-BaF2-YF3 Glasses: Effect of Substitution of BaF2 by NaF, J. Non-Cryst. Solids, 2001, vol. 291, no. 1, pp. 127–131.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of Chemistry, Far East Division, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022, Russia

    V. Ya. Kavun, E. B. Merkulov, S. L. Sinebryukhov, S. V. Gnedenkov & V. K. Goncharuk

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  1. V. Ya. Kavun
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  2. E. B. Merkulov
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  3. S. L. Sinebryukhov
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  4. S. V. Gnedenkov
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  5. V. K. Goncharuk
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Correspondence to V. Ya. Kavun.

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Original Russian Text © V.Ya. Kavun, E.B. Merkulov, S.L. Sinebryukhov, S.V. Gnedenkov, V.K. Goncharuk, 2009, published in Neorganicheskie Materialy, 2009, Vol. 45, No. 3, pp. 358–365.

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Kavun, V.Y., Merkulov, E.B., Sinebryukhov, S.L. et al. Ionic mobility and electrical transport in 45ZrF4 · 35BiF3 · 20MF (M - Li, Na, K) glasses studied by NMR and impedance spectroscopy. Inorg Mater 45, 315–321 (2009). https://doi.org/10.1134/S0020168509030170

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  • DOI: https://doi.org/10.1134/S0020168509030170

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