Skip to main content
Log in

Glass formation in the ZrF4-MF2-LaF3-NaF (M - Ba, Pb) systems

  • Published:
Inorganic Materials Aims and scope

Abstract

Glass formation in the ZrF4-MF2-LaF3-NaF (M - Ba, Pb) systems has been studied by differential thermal analysis, and the thermal parameters of the glasses have been determined. Using glass stability criteria, the most stable ZMLN glass compositions have been identified.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Mitachi, S., Shibata, S., Kanamori, T., et al., US Patent 4 308 066, 1981.

  2. Almeida, R.M. and Mackenzie, Y.D., Vibrational Spectra and Structure of Fluorozirconate Glasses, J. Chem. Phys., 1981, vol. 74, pp. 5954–5961.

    Article  CAS  Google Scholar 

  3. Lucas, J., Rare Earths in Fluoride Glasses, J. Less-Common Met., 1985, vol. 112, pp. 27–40.

    Article  CAS  Google Scholar 

  4. Poulain, M., Poulain, M., and Lucas, J., Etude compareée de verres fluorés dans les diagrammes ternaires ZrF4-BaF2-MFn(M = Na, Ca, Ln, Th; n = 1, 2, 3, 4), Rev. Chim. Miner., 1979, vol. 16, pp. 267–276.

    CAS  Google Scholar 

  5. Cheng Ji-Jian and Bao Shan-Zhi, Synthesis, Properties, and Crystallization Behavior of PbF2-AlF3-LaF3-ZrF4 System Glasses, Mater. Sci. Forum, 1985, vol. 5, pp. 91–94.

    Article  CAS  Google Scholar 

  6. Babitsyna, A.A., Emel’yanova, T.A., and Fedorov, V.A., Phase Relations in the System BaF2-LaF3-ZrF4, Zh. Neorg. Khim., 1994, vol. 39, no. 11, pp. 1883–1886.

    CAS  Google Scholar 

  7. Babitsyna, A.A., Emel’yanova, T.A., and Fedorov, V.A., Phase Relations in the PbF2-LaF3-ZrF4 System, Neorg. Mater., 2004, vol. 40, no. 5, pp. 625–627 [Inorg. Mater. (Engl. Transl.), vol. 40, no. 5, pp. 540–542].

    Article  Google Scholar 

  8. Babitsyna, A.A., Emel’yanova, T.A., and Fedorov, V.A., Glass-Forming Regions in the NaF-BaF2-LaF3-ZrF4 System, Neorg. Mater., 1997, vol. 33, no. 1, pp. 87–92 [Inorg. Mater. (Engl. Transl.), vol. 33, no. 1, pp. 78–83].

    Google Scholar 

  9. Babitsyna, A.A., Emel’yanova, T.A., and Fedorov, V.A., Glass Formation in the ZrF4-PbF2-LaF3-NaF System, Neorg. Mater., 2006, vol. 42, no. 1, pp. 91–93 [Inorg. Mater. (Engl. Transl.), vol. 42, no. 1, pp. 89–91].

    Google Scholar 

  10. Shishkin, Yu.L., The Instrument Constant in DTA. Theory of Sensing Units in DTA Instruments, J. Therm. Anal., 1987, vol. 32, pp. 17–34.

    Article  CAS  Google Scholar 

  11. Shishkin, Yu.L., Enhanced Heat Exchange DTA Cell and a New (Two-Point) Procedure for Recording DTA Curves, Zh. Fiz. Khim., 1986, vol. 60, no. 5, pp. 1319–1323.

    CAS  Google Scholar 

  12. Shishkin, Yu.L., A New Quick Method of Determining the Group Hydrocarbon Composition of Crude Oils and Oil Heavy Residues Based on Their Oxidative Distillation (Cracking) As Monitored by Differential Scanning Calorimetry and Thermogravimetry, Thermochim. Acta, 2006, vol. 440, pp. 156–165.

    Article  CAS  Google Scholar 

  13. Hruby, A., Evaluation of Glass-Forming Tendency by Means of DTA, Czech. J. Phys., 1972, vol. 22, pp. 1187–1193.

    Article  CAS  Google Scholar 

  14. Saad, M. and Poulain, M., Glass-Forming Criterion, Mater. Sci. Forum, 1987, vols. 19–20, pp. 11–18.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. A. Fedorov.

Additional information

Original Russian Text © A.A. Babitsyna, T.A. Emel’yanova, V.A. Fedorov, 2009, published in Neorganicheskie Materialy, 2009, Vol. 45, No. 3, pp. 351–357.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Babitsyna, A.A., Emel’yanova, T.A. & Fedorov, V.A. Glass formation in the ZrF4-MF2-LaF3-NaF (M - Ba, Pb) systems. Inorg Mater 45, 308–314 (2009). https://doi.org/10.1134/S0020168509030169

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0020168509030169

Keywords

Navigation