Skip to main content
SpringerLink
Log in

Effect of selenium or tellurium substitution for half of the sulfur atoms in AgCuS on its structure and the temperatures of its polymorphic transformations

  • Published:
Inorganic Materials Aims and scope

Abstract

The polymorphic transformations of AgCuS in which half of the S atoms were replaced by Se and Te have been studied by high-temperature x-ray diffraction. The substitutions are shown to have a significant effect on the temperatures of the polymorphic transformations.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Frueh, A.J., The Crystallography of Silver Sulfide Ag2S, Z. Kristallogr., 1958, vol. 110, pp. 136–144.

    Article  CAS  Google Scholar 

  2. Jabrailova, G.A. and Asadov, Yu.G., Structural Transformations of Ag2S, Izv. Akad. Nauk SSSR, Neorg. Mater., 1977, vol. 13, no. 3, pp. 423–425.

    Google Scholar 

  3. Howard, T. and Evans, H., The Crystal Structures of Low Chalcocite and Djurleite, Z. Kristallogr., 1979, vol. 150, pp. 299–320.

    Article  Google Scholar 

  4. Asadov, Yu.Q., Jafarov, K.M., and Gasymov, G.B., Structural Transformations in Cu2−x S and Cu2−x InS Crystals, Phase Transitions, 1986, vol. 7, pp. 281–303.

    Article  CAS  Google Scholar 

  5. Belov, N.V. and Butuzov, V.A., Structure of High Chalcocite, Cu2S, Dokl. Akad. Nauk SSSR, 1964, vol. 54, no. 8, pp. 717–720.

    Google Scholar 

  6. Frueh, A.J., The Crystal Structure of Stromeyerite AgCuS, a Possible Defect Structure, Z. Kristallogr., 1955, vol. 106, pp. 299–307.

    CAS  Google Scholar 

  7. Bragg, W. and Claringbull, G.F., Crystal Structures of Minerals, vol. 4 of The Crystalline State, Bragg, W., Ed., London: Bell, 1965.

    Google Scholar 

  8. Frueh, A.J., Cramanske, G.K., and Knight, C.H., The Crystallography of Eucairite, AgCuS, Z. Kristallogr., 1957, vol. 108, pp. 389–396.

    Article  CAS  Google Scholar 

  9. Blachnik, R., Lasocka, M., and Walbreeht, U., The System Copper-Tellurium, J. Solid State Chem., 1983, vol. 48, pp. 431–438.

    Article  CAS  Google Scholar 

  10. Nowotny, H., Die Kristallostruktur von Cu2Te, Z. Metallkd., 1946, vol. 37, pp. 40–42.

    Google Scholar 

  11. Mendelevich, A.Yu., Krestovnikov, A.N., and Glazov, V.M., Analysis of Phase Equilibria in Pseudobinary Group I Chalcogenide Systems in the Regular Solution Approximation, Zh. Fiz. Khim., 1969, vol. 43, no. 12, p. 3067.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Physics, Academy of Sciences of Azerbaijan, pr. Javida 33, Baku, AZ1143, Azerbaijan

    Yu. G. Asadov, Yu. I. Alyev & A. G. Babaev

Authors
  1. Yu. G. Asadov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yu. I. Alyev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. G. Babaev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Yu. G. Asadov.

Additional information

Original Russian Text © Yu.G. Asadov, Yu.I. Alyev, A.G. Babaev, 2008, published in Neorganicheskie Materialy, 2008, Vol. 44, No. 4, pp. 400–407.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Asadov, Y.G., Alyev, Y.I. & Babaev, A.G. Effect of selenium or tellurium substitution for half of the sulfur atoms in AgCuS on its structure and the temperatures of its polymorphic transformations. Inorg Mater 44, 337–344 (2008). https://doi.org/10.1134/S0020168508040031

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0020168508040031

Keywords

Search

Navigation