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Calcium bismuth borates in the CaO-Bi2O3-B2O3 system

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Abstract

The 600°C (subsolidus) section of the CaO-Bi2O3-B2O3 phase diagram has been studied by x-ray diffraction and differential thermal analysis. A new calcium bismuth borate of composition CaBi2B4O10 has been identified, and the existence of CaBi2B2O7 has been confirmed. According to T-x phase diagram data, these compounds form peritectically at 700±5 and 783±5°C, respectively.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    A. V. Egorysheva, V. D. Volodin & V. M. Skorikov

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  1. A. V. Egorysheva
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  2. V. D. Volodin
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  3. V. M. Skorikov
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Correspondence to A. V. Egorysheva.

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Original Russian Text © A.V. Egorysheva, V.D. Volodin, V.M. Skorikov, 2008, published in Neorganicheskie Materialy, 2008, Vol. 44, No. 1, pp. 76–81.

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Egorysheva, A.V., Volodin, V.D. & Skorikov, V.M. Calcium bismuth borates in the CaO-Bi2O3-B2O3 system. Inorg Mater 44, 70–75 (2008). https://doi.org/10.1134/S0020168508010123

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  • DOI: https://doi.org/10.1134/S0020168508010123

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