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Thermodynamic study of the BiCl3-MCl (M = Li, Na, K, Cs) systems in the ideal associated solution model

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Abstract

The thermal stability of the congruently melting compounds LiCl · BiCl3, LiCl · 4BiCl3, NaCl · BiCl3, 3KCl · BiCl3, and 3CsCl · BiCl3 is assessed from the curvature of the liquidus at their melting points, and the applicability of the ideal associated solution model to the BiCl3-LiCl, BiCl3-NaCl, BiCl3-KCl, and BiCl3-CsCl systems is analyzed.

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Authors and Affiliations

  1. Khetagurov State University, ul. Vatutina 46, Vladikavkaz, 362040, North Ossetia, Russia

    K. B. Dzeranova & A. S. Trunin

Authors
  1. K. B. Dzeranova
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  2. A. S. Trunin
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Correspondence to K. B. Dzeranova.

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Original Russian Text © K.B. Dzeranova, A.S. Trunin, 2007, published in Neorganicheskie Materialy, 2007, Vol. 43, No. 9, pp. 1131–1134.

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Dzeranova, K.B., Trunin, A.S. Thermodynamic study of the BiCl3-MCl (M = Li, Na, K, Cs) systems in the ideal associated solution model. Inorg Mater 43, 1015–1017 (2007). https://doi.org/10.1134/S002016850709018X

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  • DOI: https://doi.org/10.1134/S002016850709018X

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