Skip to main content
SpringerLink
Log in

Low-temperature heat capacity and thermodynamic properties of InSe

  • Published:
Inorganic Materials Aims and scope

Abstract

The heat capacity of InSe has been measured at temperatures from 11.14 to 325.26 K using an adiabatic calorimeter. The results differ significantly from earlier data (by ∼2.2% at 200 K). The smoothed heat capacity data have been used to evaluate temperature-dependent thermodynamic functions (entropy, enthalpy increment, and reduced Gibbs energy) of indium selenide. Its thermodynamic properties under standard conditions are C 0p (198.15 K) = 49.43 ± 0.10 J/(K mol), S 0(298.15 K) = 82.20 ± 0.16 J/(K mol), H 0(298.15 K) − H0(0) = 10.94 ± 0.02 kJ/mol, and Φ0(298.15 K) = 45.50 ± 0.09 J/(K mol). The Debye characteristic temperature of InSe evaluated from the heat capacity data is 275 ± 15 K.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Mamedov, K.K., Kerimov, I.G., Kostryukov, V.N., and Mekhtiev, M.I., Heat Capacity and Entropy of Indium Monoselenide, Zh. Fiz. Khim., 1967, vol. 41, no. 6, pp. 1300–1302.

    CAS  Google Scholar 

  2. Dmitriev, A.I., Lashkarev, V.G., Baida, A.A., et al., Heat Capacity of the n-InSe Single Crystal Layered Semiconductor, J. Appl. Phys., 2002, vol. 92, no. 9, pp. 5110–5112.

    Article  CAS  Google Scholar 

  3. Shebershneva, O.V., A Fractal Model for Low-Temperature Heat Capacity of Inorganic Solids, Cand. Sci. (Chem.) Dissertation, Moscow: Kurnakov Inst. of General and Inorganic Chemistry, Russ. Acad. Sci., 1996.

    Google Scholar 

  4. Powder Diffraction File, Swarthmore: Joint Committee on Powder Diffraction Standards, card no. 34-1431.

  5. http://www.physics.nist.gov/PhysRefData/Compositions.

  6. Gorbunov, V.E., Gurevich, V.M., and Gavrichev, K.S., Adiabatic Microcalorimeter with an Aneroid-Type Cryostat, Zh. Fiz. Khim., 1982, vol. 56, no. 1, pp. 235–237.

    CAS  Google Scholar 

  7. Iorish, V.S. and Tolmach, P.I., Procedure and Program for Spline Fitting Low-Temperature Heat Capacity Data, Zh. Fiz. Khim., 1986, vol. 60, no. 10, pp. 2583–2587.

    CAS  Google Scholar 

  8. Abbasov Almuk Suleiman Ogly, Physicochemical Properties of Compound Semiconductors in the Systems AI-BVI, AIII-BVI, and AIII-BV (AI = Cu, Ag; AIII = Ga, In, Gd; BV = P, As, Sb; BVI = S, Se, Te), Extended Abstract of Cand. Sci. (Phys.-Math.) Dissertation, Baku, 1989.

Download references

Author information

Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    A. V. Tyurin & K. S. Gavrichev

  2. Moscow State University, Vorob’evy gory 1, Moscow, 119899, Russia

    V. P. Zlomanov

Authors
  1. A. V. Tyurin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. K. S. Gavrichev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. P. Zlomanov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. V. Tyurin.

Additional information

Original Russian Text © A.V. Tyurin, K.S. Gavrichev, V.P. Zlomanov, 2007, published in Neorganicheskie Materialy, 2007, Vol. 43, No. 9, pp. 1031–1035.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Tyurin, A.V., Gavrichev, K.S. & Zlomanov, V.P. Low-temperature heat capacity and thermodynamic properties of InSe. Inorg Mater 43, 921–925 (2007). https://doi.org/10.1134/S0020168507090014

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0020168507090014

Keywords

Search

Navigation