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Scintillating properties of Pr-doped YAlO3 single crystals grown by the micro-pulling-down method

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Pr-doped YAlO3 (0.1, 0.5, 1, 2, 3, 4, 5, and 6 mol % Pr6O11) single crystals were grown by the micro-pulling-down method and their optical and luminescence properties were investigated in the range 80–300 K. Dominant 5d–4f double-peak emission at 254 and 282 nm was observed both in radio-and photoluminescence, and was accompanied by weak 4f–4f luminescence at 495 and 620 nm. The 5d–4f emission shows almost no temperature dependence below 300 K, and achieved radioluminescence intensity is more than 15 times higher than that of Bi4Ge3O12.

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References

  1. Moses, W.W., Current Trends in Scintillator Detectors and Materials, Nucl. Instrum. Methods. Phys. Res., Sect. A, 2002, vol. 487, nos. 1–2, pp. 123–128.

    Article  CAS  Google Scholar 

  2. Weber, M.J., Optical Spectra of Ce3+ and Ce3+-Sensitized Fluorescence in YAlO3, J. Appl. Phys., 1973, vol. 44, no. 7, pp. 3205–3208.

    Article  CAS  Google Scholar 

  3. Takagi, K. and Fukuzawa, T., Cerium-Activated Gd2SiO5 Single Crystal Scintillator, Appl. Phys. Lett., 1983, vol. 42, no. 1, pp. 43–45.

    Article  CAS  Google Scholar 

  4. Melcher, C.L. and Schweitzer, J.S., A Promising New Scintillator: Cerium-Doped Lutetium Oxyorthosilicate, Nucl. Instrum. Methods. Phys. Res., Sect. A, 1992, vol. 314, no. 1, pp. 212–214.

    Article  Google Scholar 

  5. Cooke, D.W., McClellan, K.J., Bennett, B.L., et al., Crystal Growth and Optical Characterization of Cerium-Doped Lu1.8Y0.2SiO5, J. Appl. Phys., 2000, vol. 88, no. 12, pp. 7360–7362.

    Article  CAS  Google Scholar 

  6. Drozdowski, W., Lukasiewicz, T., Wojtowicz, A.J., et al., Thermoluminescence and Scintillation of Praseodymium-Activated Y3Al5O12 and LuAlO3 Crystals, J. Cryst. Growth, 2005, vol. 275, nos. 1–2, pp. e709–e714.

    Article  CAS  Google Scholar 

  7. Dorenbos, P., The 5d Level Positions of the Trivalent Lanthanides in Inorganic Compounds, J. Lumin., 2000, vol. 91, nos. 3–4, pp. 155–176.

    Article  CAS  Google Scholar 

  8. Ogino, H., Yoshikawa, A., Nikl, M., et al., Growth and Scintillation Properties of Pr-Doped Lu3Al5O12 Crystals, J. Cryst. Growth, 2006, vol. 287, no. 2, pp. 335–338.

    Article  CAS  Google Scholar 

  9. Novoselov, A., Ogino, H., Yoshikawa, A., et al., Study on Crystal Growth and Luminescence Properties of Pr-Doped RE2SiO5 (RE = Y, Lu), J. Cryst. Growth, 2006, vol. 287, no. 2, pp. 309–312.

    Article  CAS  Google Scholar 

  10. Novoselov, A., Yoshikawa, A., and Fukuda, T., The Micro-pulling-Down Method: Fast and Economic Solution for Materials Screening, Curr. Top. Cryst. Growth Res., 2004, vol. 7, pp. 87–111.

    CAS  Google Scholar 

  11. Cockayne, B., Lent, B., Abell, J.S., and Harris, I.R., Cracking in Yttrium Orthoaluminate Single Crystals, J. Mater. Sci., 1973, vol. 8, pp. 871–875.

    Article  CAS  Google Scholar 

  12. Shannon, R.D., Revised Effective Ionic Radii and Systematic Studies of Interatomic Distances in Halides and Chalcogenides, Acta Crystallogr., Sect. A: Cryst. Phys., Diffr., Theor. Gen. Crystallogr., 1976, vol. 32, no. 5, pp. 751–767.

    Article  Google Scholar 

  13. Epelbaum, B.M., Schierning, G., and Winnacker, A., Modification of the Micro-pulling-Down Method for High Temperature Solution Growth of Miniature Bulk Crystals, J. Cryst. Growth, 2005, vol. 275, nos. 1–2, pp. e867–e870.

    Article  CAS  Google Scholar 

  14. Novoselov, A., Ogino, H., Yoshikawa, A., et al., Crystal Growth, Optical and Luminescence Properties of Pr-Doped Y2SiO5 Single Crystals, Opt. Mater., 2006, doi:10.1016/j.optmat.2006.04.017.

  15. Pedrini, C., Bouttet, D., Dujardin, C., et al., Fast Fluorescence and Scintillation of Pr-Doped Yttrium Aluminum Perovskite, Opt. Mater., 1994, vol. 3, no. 2, pp. 81–88.

    Article  CAS  Google Scholar 

  16. Li-Ji Lyu and Hamilton, D.S., Radiative and Nonradiative Relaxation Measurements in Ce3+ Doped Crystals, J. Lumin., 1991, vols. 48–49, no. 1, pp. 251–254.

    Google Scholar 

  17. Nikl, M., Yoshikawa, A., Vedda, A., and Fukuda, T., Development of Novel Scintillator Crystals, J. Cryst. Growth, 2006, vol. 292, no. 2, pp. 416–421.

    Article  CAS  Google Scholar 

  18. Drozdowski, W., Wojtowicz, A.J., Wisniewski, D., et al., Scintillation Properties of Pr-Activated LuAlO3, Opt. Mater., 2006, vol. 28, nos. 1–2, pp. 102–105.

    Article  CAS  Google Scholar 

  19. Zorenko, Yu.V., Voloshinovskii, A.S., Striganyuk, G.B., and Gorbenko, V.I., Exciton Luminescence of YAlO3 Single Crystals and Single-Crystal Films, Opt. Spectrosc., 2005, vol. 98, no. 4, pp. 555–559.

    Article  CAS  Google Scholar 

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Zhuravleva, M., Novoselov, A., Yoshikawa, A. et al. Scintillating properties of Pr-doped YAlO3 single crystals grown by the micro-pulling-down method. Inorg Mater 43, 753–757 (2007). https://doi.org/10.1134/S0020168507070163

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  • DOI: https://doi.org/10.1134/S0020168507070163

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