Abstract
We have studied the kinetics of molybdenum trioxide desorption from the alumina surface after mechanical activation of Al2O3 + MoO3 mixtures. Mechanical activation has been shown to considerably inhibit MoO3 thermal desorption. The apparent rate constant and activation energy of the process have been evaluated.
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Kainarskii, I.S., Degtyareva, E.V., and Orlova, I.G., Korundovye ogneupory i keramika (Alumina Refractories and Ceramics), Moscow: Metallurgiya, 1981.
Lukin, E.S., Popova, N.A., and Zdvizhkova, N.I., High-Strength Alumina-Zirconia Ceramics, Steklo Keram., 1993, nos. 9–10, pp. 25–30.
Kosenko, N.F. and Smirnova, M.A., Principles of Mechanochemical Processing of Alumina Materials with Application to the Manufacturing of Refractories, Mezhdunarodnaya nauchnaya konferentisiya “Energoresursosberegayushchie tekhnologii i oborudovanie, ekologicheski bezopasnye proizvodstva” (Int. Sci. Conf. on Energy-Saving Technologies and Equipment and Environmentally Friendly Processes), Ivanovo, 2004, p. 67.
Remy, H., Lehrbuch der anorganische Chemie, Leipzig: Akademie, 1960.
Kosenko, N.F., Smirnova, M.A., and Ermakova, I.A., Strength of Bonding between Molybdena and Alumina, IVserossiiskaya shkola-konferentsiya “Molodye uchenye—novoi Rossi. Fundamental’nye issledovaniya v oblasti khimii i innovatsionnaya deyatel’nost’” (I All-Russia Conf. Young Scientists for New Russia: Basic Research and Innovations in Chemistry), Ivanovo, 2005, pp. 185–186.
Kosenko, N.F., Smirnova, M.A., and Denisova, O.P., Kinetics of Mechanically Activated P2O5 Incorporation into Al2O3, Neorg. Mater., 2005, vol. 41, no. 3, pp. 321–323 [Inorg. Mater. (Engl. Transl.), vol. 41, no. 3, pp. 261–263].
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Original Russian Text © N.F. Kosenko, M.A. Smirnova, I.A. Ermakova, 2007, published in Neorganicheskie Materialy, 2007, Vol. 43, No. 5, pp. 584–587.
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Kosenko, N.F., Smirnova, M.A. & Ermakova, I.A. Kinetics of MoO3 thermal desorption from the surface of mechanically activated alumina. Inorg Mater 43, 512–514 (2007). https://doi.org/10.1134/S0020168507050135
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DOI: https://doi.org/10.1134/S0020168507050135