Abstract
The phase equilibria in the ternary system La2O3-Nb2O5-Nb have been studied at subsolidus temperatures in vacuum (6.65 × 10−3 Pa), and the temperature stability limits of LaNb7O12 have been determined in vacuum and during heating in air.
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Gordienko, S.P., Fenochka, B.V., and Fesenko, V.V., Redkozemel’nye metally i ikh tugoplavkie soedineniya. Spravochnik (Rare-Earth Metals and Refractory Rare-Earth Compounds: A Handbook), Kiev: Naukova Dumka, 1971.
Leger, J.M., Yacoubi, N., and Loriers, J., Synthesis of Rare Earth Monooxides, J. Solid State Chem., 1981, vol. 36, pp. 261–270.
Levinskii, Yu.V., p-T-x-diagrammy sostoyaniya dvoinykh metallicheskikh sistem (p-T-x Phase Diagrams of Binary Metallic Systems), Moscow: Metallurgiya, 1990, vol. 2.
Gshneidner, K.A., Jr., Rare Earth Alloys, Princeton, NJ: Van Nostrand, 1961.
Arsen’ev, P.A., Glushkova, V.B., Evdokimov, A.A., et al., Rare-Earth Compounds: Zirconates, Hafnates, Niobates, Tantalates, and Antimonates, in Khimiya redkikh elementov (Chemistry of Rare Elements), Moscow: Nauka, 1985.
Xu, J., Emge, T., and Greenblatt, M., Synthesis, Crystal Structure, and Physical Properties of a New Reduced Lanthanum Niobium Oxide: LaNb7O12, J. Solid State Chem., 1996, vol. 123, pp. 21–29.
Köhler, J., Tischtau, R., and Simon, A., Oxoniobates with 13 and 15 Electrons in [Nb6O12] Clusters: The Structures of KNb8O14 and LaNb8O14, J. Chem. Soc., Dalton Trans., 1991, pp. 829–832.
Niepel, L. and Malinovsky, M., Triangulation of Phase Diagrams, Chem. Zvesti, 1978, vol. 32, no. 6, pp. 810–820.
Hofmann, R. and Gruehn, R., Zur Darstellung und sTruktur neuer Niobate LnNb7O19 (Ln = La, Ce), Z. Anorg. Allg. Chem., 1991, vol. 602, pp. 105–117.
Köhler, J., Svensson, G., and Simon, A., Oxoniobates Containing Metal Clusters, Angew. Chem., Int. Ed. Engl., 1992, vol. 31, pp. 1437–1456.
Berg, L.G., Vvedenie v termographiyu (Introduction to Thermal Analysis), Moscow: Nauka, 1969.
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Original Russian Text © O.G. Reznitskikh, N.I. Lobachevskaya, V.G. Zubkov, N.D. Koryakin, V.D. Zhuravlev, V.G. Bamburov, 2007, published in Neorganicheskie Materialy, 2007, Vol. 43, No. 1, pp. 80–84.
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Reznitskikh, O.G., Lobachevskaya, N.I., Zubkov, V.G. et al. Phase equilibria in the La2O3-Nb2O5-Nb system and thermal stability of LaNb7O12 . Inorg Mater 43, 73–77 (2007). https://doi.org/10.1134/S0020168507010153
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DOI: https://doi.org/10.1134/S0020168507010153