Abstract
Saponites with Ni were hydrothermally synthesized at a given pH using inorganic salts as raw materials. Then, mesoporous molecular sieves with Ni were synthesized hydrothermally using the synthesized saponites as precursors and cetyltrimethyl ammonium bromide as a template. The prepared mesoporous molecular sieves with Ni still had mesoporous structure after calcination at 850°C for 3 h or hydrothermal treatment at 100°C for 10 days.
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Beck, J.S., Vartuli, J.C., Roth, W.J., et al., A New Family of Mesoporous Molecular Sieves Prepared with Liquid Crystal Templates, J. Am. Chem. Soc., 1992, vol. 114, no. 27, pp. 10834–10843.
Ryoo, R., Kim, J.M., Ko, C.H., and Shin, C.H., Disordered Molecular Sieve with Branched Mesoporous Channel Network, J. Phys. Chem., 1996, vol. 100, no. 45, pp. 17 718–17 721.
Kim, J.M., Jun, S., and Ryoo, R., Improvement of Hydrothermal Stability of Mesoporous Silica Using Salts: Reinvestigation for Time-Dependent Effects, J. Phys. Chem. B, 1999, vol. 103, no. 30, pp. 6200–6205.
Zhao, D.Y., Feng, J.L., Huo, Q.S., et al., Triblock Copolymer Syntheses of Mesoporous Silica with Periodic 50 to 300 Angstrom Pores, Science, 1998, vol. 279, no. 5350, pp. 548–552.
Tanav, P.V. and Pinnavaia, T.J., A Neutral Templateing Route to Mesoporous Molecular Sieves, Science, 1995, vol. 267, no. 5199, pp. 865–868.
Huang, L.M., Guo, W.P., Deng, P., et al., Investigation of Synthesizing MCM-41/ZSM-5 Composites, J. Phys. Chem. B, 2000, vol. 104, no. 13, pp. 2817–2823.
Matsumoto, A., Sasaki, T., Nishimiya, N., and Tsutsum, K., Thermal Stability and Hydrophobicity of Mesoporous Silica FSM-16, Coll. Surf. A, 2002, vol. 203, nos. 1–3, pp. 185–193.
Liu, Y., Zhang, W., and Pinnavaia, T.J., Steam-Stable Aluminosilicate Mesostructures Assembled from Zeolite Y Seeds, J. Am. Chem. Soc., 2000, vol. 122, no. 36, pp. 8791–8792.
Zhang, Z., Hua, Y., Xiao, F.S., et al., Mesoporous Aluminosilicates with Ordered Hexagonal Structure, Strong Acidity, and Extraordinary Hydrothermal Stability at High Temperatures, J. Am. Chem. Soc., 2001, vol. 123, no. 21, pp. 5014–5021.
Barrett, E.P., Joyner, L.G., and Halenda, P.P., The Determination of Pore Volume and Area Distributions in Porous Substances: I. Computation from Nitrogen Isotherms, J. Am. Chem. Soc., 1951, vol. 73, no. 1, pp. 373–380.
Liu, Z.Y., Synthesis, Modified, Characterization, and Catalytic Performance of Cross Linked Substance and the Layer Silicate by Isomorphous Substitution, Doctoral Dissertation (in Chinese), Changchun: Jilin University, 1989.
Selvaraj, M., Panduragan, A., Seshadri, K.S., et al., Synthesis, Characterization, and Catalytic Application of MCM-41 Mesoporous Molecular Sieves Containing Zn and Al, Appl. Catal., A, 2003, vol. 242, no. 2, pp. 347–364.
Wojcieszak, R., Monteverdi, S., Mercy, M., et al., Nickel Containing MCM-41 and AlMCM-41 Mesoporous Molecular Sieves Characteristics and in the Hydrogenation of Benzene, Appl Catal., A, 2004, vol. 268, nos. 1–2, pp. 241–253.
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Jiang, T.S., Zhao, Q. & Yin, H.B. Synthesis and characterization of Ni-mesoporous molecular sieves with high stability. Inorg Mater 43, 30–34 (2007). https://doi.org/10.1134/S0020168507010086
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DOI: https://doi.org/10.1134/S0020168507010086