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Effect of SO2 impurity on the optical transmission of As2S3 glass

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Abstract

To assess the effect of sulfur dioxide impurity on the optical properties and absorption spectrum of glassy arsenic sulfide, we have prepared As2S3 glass samples containing 0.01 to 0.12 wt % SO2 and have measured their transmission spectra in the range 500–5000 cm−1. The extinction coefficient of sulfur dioxide in glassy arsenic sulfide, evaluated from the intensity of the 1158-cm−1 absorption band, is 10.0 ± 0.7 cm−1/wt%.

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References

  1. Devyatykh, G.G., Churbanov, M.F., Scripachev, I.V., et al., Recent Developments in As-S Glass Fibers, Proc. XI Int. Symp. on Non-Oxide and New Optical Glasses, Sheffield, 1999, pp. 179–183.

  2. Borisevich, V.G., Plotnichenko, V.G., Skripachev, I.V., and Churbanov, M.F., Extinction Coefficient of SH Groups in Glassy Arsenic Sulfide, Vysokochist. Veshchestva, 1990, no. 4, pp. 198–202.

  3. Shoji Tsuchihashi and Yoji Kawamoto, Properties and Structure of Glasses in the System As-S, J. Non-Cryst. Solids, 1971, vol. 5, no. 4, pp. 286–305.

    Article  CAS  Google Scholar 

  4. Herzberg, G., Molecular Spectra and Molecular Structure: II. Infrared and Raman Spectra of Polyatomic Molecules, Princeton: Van Nostrand Reinhold, 1945.

    Google Scholar 

  5. Ležal, D. and Konnák, K., The Characterization of the Infrared Absorption Spectra of the Vitreous, Cubic, and Monoclinic Modification of As2O3, J. Non-Cryst. Solids, 1995, vols. 192–193, pp. 187–190.

    Google Scholar 

  6. Shiryaev, V.S., Smetanin, S.V., Ovchinnikov, D.K., et al., Effects of Oxygen and Carbon Impurities on the Optical Transmission of As2Se3 Glass, Neorg. Mater., 2005, vol. 41, no. 3, pp. 369–376 [Inorg. Mater. (Engl. Transl.), vol. 41, no. 3, pp. 308–314].

    Article  CAS  Google Scholar 

  7. Bychkova, T.I., Vinogradova, G.Z., Voitsekhovskii, V.V., and Plotnichenko, V.G., As2O3-Related Absorption in Glassy Selenium, Vysokochist. Veshchestva, 1990, no. 4, pp. 203–207.

  8. Dianov, E.M., Petrov, M.Yu., Plotnichenko, V.G., and Sysoev, V.K., Evaluation of Minimal Optical Losses in Chalcogenide Glasses, Kvantovaya Elektron. (Moscow), 1982, vol. 9, no. 4, pp. 798–800.

    CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of Chemistry of High-Purity Substances, Russian Academy of Sciences, ul. Tropinina 49, Nizhni Novgorod, 603950, Russia

    G. E. Snopatin, M. Yu. Matveeva, G. G. Butsyn & M. F. Churbanov

  2. Fiber Optics Research Center, Prokhorov General Physics Institute, Russian Academy of Sciences, ul. Vavilova 38, Moscow, 119991, Russia

    E. B. Kryukova & V. G. Plotnichenko

Authors
  1. G. E. Snopatin
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  2. M. Yu. Matveeva
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  3. G. G. Butsyn
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  4. M. F. Churbanov
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  5. E. B. Kryukova
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  6. V. G. Plotnichenko
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Original Russian Text © G.E. Snopatin, M.Yu. Matveeva, G.G. Butsyn, M.F. Churbanov, E.B. Kryukova, V.G. Plotnichenko, 2006, published in Neorganicheskie Materialy, 2006, Vol. 42, No. 12, pp. 1516–1520.

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Snopatin, G.E., Matveeva, M.Y., Butsyn, G.G. et al. Effect of SO2 impurity on the optical transmission of As2S3 glass. Inorg Mater 42, 1388–1392 (2006). https://doi.org/10.1134/S0020168506120181

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  • DOI: https://doi.org/10.1134/S0020168506120181

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